Title:
Chemoton theory
Personal Author:
Series:
Mathematical and computational chemistry
Publication Information:
New York, NY : Kluwer Academic/Plenum Publishers, 2003
Physical Description:
2v.
ISBN:
9780306477850
9780306477836
9780306477843
Subject Term:
Available:*
Library | Item Barcode | Call Number | Material Type | Item Category 1 | Status |
---|---|---|---|---|---|
Searching... | 30000010099251 | QH325 G36 2003 v.1 | Open Access Book | Great Book | Searching... |
Searching... | 30000010099247 | QH325 G36 2003 v.2 | Open Access Book | Great Book | Searching... |
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Summary
Summary
Dr. Gànti has introduced Chemoton Theory to explain the origin of life. Theoretical Foundations of Fluid Machineries is a discussion of the theoretical foundations of fluid automata. It introduces quantitative methods - cycle stoichiometry and stoichiokinetics - in order to describe fluid automata with the methods of algebra, as well as their construction, starting from elementary chemical reactions up to the complex, program-directed, proliferating fluid automata, the chemotons.
Chemoton Theory outlines the development of a theoretical biology, based on exact quantitative considerations and the consequences of its application on biotechnology and on the artificial synthesis of living systems.
Table of Contents
I. Introduction | p. 1 |
II. Constructional Elements of Fluid Machines | p. 9 |
Reaction Chains | p. 9 |
Chemical reactions as sections of forced trajectories | p. 9 |
Coupling of chemical reactions | p. 12 |
Branchings | p. 18 |
AND-type branching | p. 18 |
OR-type branchings | p. 21 |
The Chemical Cycle | p. 22 |
Characterization of the chemical cycle | p. 22 |
Cycle stoichiometry | p. 25 |
Operation rules | p. 25 |
Examples for the application of the rules | p. 27 |
Generalization of cycle stoichiometry | p. 30 |
Kinetics of cycles | p. 31 |
An example for chemical cycles | p. 32 |
The catalytic nature of chemical cycles | p. 35 |
Enzyme reactions | p. 39 |
General considerations | p. 41 |
Self-Reproducing Chemical Cycles | p. 43 |
Simple self-reproducing cycle | p. 44 |
Kinetics of self-reproducing cycles | p. 53 |
Examples of self-reproducing cycles | p. 53 |
Self-consuming cycles | p. 56 |
Storage and Replication of Information | p. 56 |
Template processes | p. 57 |
Example for calculating template polymerization | p. 61 |
Kinetics of template polymerization | p. 63 |
General remarks | p. 67 |
Compartmentalization | p. 68 |
Stoichiometry | p. 69 |
Formal kinetics of membrane growth | p. 70 |
III. Design of Simple Fluid Machines | p. 73 |
Coupling of Simple Parts | p. 73 |
Coupling of chemical cycles with reaction chains | p. 73 |
Coupling of cycles with one another | p. 76 |
Second-generation cycles | p. 84 |
Industrial applications | p. 91 |
Coupling of Self-Reproducing Constituents | p. 97 |
Coupling of simple parts into self-reproducing systems | p. 97 |
The coupling of a self-reproducing cycle with a reaction chain | p. 101 |
Oscillating reaction systems | p. 103 |
Coupling of self-reproducing cycles and template polymerization: fluid program control | p. 109 |
Industrial applications | p. 114 |
IV. Proliferating Fluid Automata | p. 121 |
The Forms of Genesis | p. 121 |
Definitions | p. 122 |
Examples | p. 124 |
Proliferating Microspheres | p. 127 |
Coupling, Stoichiometry | p. 128 |
Operation: growth and division | p. 130 |
Kinetics | p. 134 |
Proliferating "Fluid Clockworks" | p. 137 |
Microspheres with OR-branching | p. 137 |
Microsphere with an oscillating chemical system | p. 139 |
Proliferating "fluid clockworks" | p. 141 |
Chemotons | p. 144 |
Chemoton coupling | p. 147 |
Stoichiometry | p. 148 |
Qualitative survey of operation | p. 150 |
Kinetics | p. 152 |
Computer study of operation | p. 155 |
Chemoton variants | p. 159 |
V. Outlines of Self-Organizing Fluid Computers | p. 163 |
Introductory Remarks | p. 163 |
Constituents of Fluid Computers | p. 165 |
Connection to the electric field | p. 165 |
The I-switch | p. 170 |
The F-switch | p. 176 |
The C-switch | p. 177 |
A possible way to realize the C-switch | p. 180 |
Chemotons of limited proliferation | p. 183 |
The Basic Network | p. 188 |
Design of the basic network | p. 188 |
Operation of the basic network | p. 191 |
Energy supply of the basic network | p. 193 |
Shape recognition by light sensitivity | p. 194 |
Shape recognition by touching | p. 198 |
Coupling of the basic network to other sensors | p. 199 |
General remarks | p. 201 |
Cogitator Networks | p. 202 |
G-elements | p. 202 |
Networks consisting of C- and G-elements | p. 203 |
Basic cogitator network | p. 206 |
Secondary wiring | p. 207 |
Associative network | p. 209 |
The "dream" of the associative network | p. 210 |
Design of Cogitators | p. 211 |
Abstractor subunit | p. 211 |
Decoder subunit | p. 214 |
Simple cogitator | p. 218 |
The problem solving ability of the cogitator | p. 220 |
Cogitators with Time Coder | p. 222 |
T-elements | p. 222 |
Simple fluid clockwork | p. 225 |
Complex fluid clockwork | p. 227 |
Cogitator with clockwork | p. 228 |
Activity, Sleeping and Death | p. 229 |
Activity | p. 229 |
Selective control of operation | p. 230 |
Sleeping and dreaming | p. 233 |
Toward Fluid Robots | p. 237 |
The cogitator as a robot brain | p. 237 |
Fluid robots | p. 239 |
References | p. 241 |
Index | p. 245 |
VI. About the World of Living in General | p. 251 |
What is Life? | p. 251 |
The ambiguity of the concept of life | p. 251 |
Views concerning the essence of life | p. 254 |
The standpoints of some outstanding philosophers | p. 259 |
The Most General Properties of Living Beings | p. 268 |
Empirical facts providing the basis for the theory | p. 268 |
Conclusions | p. 273 |
Life Criteria | p. 278 |
Alive, capable of living, dead, nonliving | p. 278 |
The levels of life | p. 280 |
Life criteria | p. 282 |
Chemotons as Living Systems | p. 289 |
Chemotons satisfy life criteria | p. 289 |
Chemotons are minimum systems of life | p. 293 |
VII. Chemical Evolution | p. 297 |
Setting of Objectives | p. 297 |
The Date of the Genesis of Life | p. 298 |
The Genesis of Earth | p. 300 |
The Primitive Atmosphere | p. 308 |
Chemical Evolution | p. 311 |
Introduction | p. 311 |
Energy source | p. 312 |
Initial compounds | p. 314 |
Low-molecular-weight products | p. 315 |
Abiotic formation of proteinoids | p. 324 |
Abiogenic formation of nucleic acids | p. 325 |
Formation of microscopic structures | p. 328 |
VIII. Biogenesis | p. 331 |
Models of Biogenesis | p. 331 |
Experimental models | p. 331 |
Qualitative theoretical models | p. 332 |
Quantitative theoretical models | p. 334 |
Metabolic Network of a Prebiotic Chemoton | p. 338 |
General aspects | p. 338 |
Autocatalytic subsystems | p. 340 |
Connective subsystems | p. 346 |
Additional pathways | p. 351 |
A qualitative survey of the operation of the network | p. 354 |
Quantitative Description of Prebiotic Chemotons | p. 356 |
Strategy | p. 356 |
Membrane synthesis | p. 359 |
Template synthesis | p. 361 |
Combination of the two subsystems | p. 371 |
Synthesis of precursors | p. 373 |
Self-reproducing metabolic network | p. 377 |
Overall equation of the prebiotic chemoton | p. 378 |
IX. Prebiotic Evolution | p. 383 |
Introduction | p. 383 |
Beginnings of Prebiotic Evolution | p. 384 |
Conditions of biogenesis on Earth | p. 384 |
Spontaneous genesis of proliferating systems | p. 388 |
Spontaneous genesis of chemotons | p. 389 |
External conditions of early evolution | p. 391 |
The early evolution of chemotons | p. 394 |
Appearance of Enzyme Activity | p. 396 |
The problem of primitive catalysis | p. 396 |
Evolution of RNAs | p. 400 |
Development of enzyme RNAs | p. 403 |
The Origin of Coenzymes | p. 409 |
General considerations | p. 409 |
Coenzymes are the remnants of eRNAs | p. 410 |
The Origin of Genes and the Code | p. 414 |
The origin of genes | p. 414 |
The origin of RNA polymerases | p. 416 |
The appearance of DNA | p. 419 |
The origin of code | p. 422 |
Summary | p. 424 |
X. Exobiological Outlook | p. 427 |
Introductory Remarks | p. 427 |
Possibility of the Existence of Non-terrestrial Types of Life | p. 429 |
Non-carbon-based life | p. 429 |
Carbon-based life with a non-terrestrial type of metabolism | p. 434 |
Life of non-terrestrial origin with a terrestrial metabolism | p. 436 |
Exobiological Studies in the Solar System | p. 437 |
Dry celestial bodies | p. 437 |
Mars | p. 440 |
Galilean moons | p. 449 |
Giant planets | p. 452 |
XI. Outlines of a Quantitative Biology | p. 453 |
Introduction | p. 453 |
Some Genetic Considerations | p. 455 |
Self-(re)production without genetic subsystem | p. 455 |
Reproduction by a "technological recipe" | p. 458 |
Hereditary properties acquired by adaptation | p. 461 |
General structure of the genetic material | p. 464 |
Quantitative Treatment of a Prokaryotic Cell | p. 470 |
Possibilities and limitations | p. 470 |
Stoichiometry of the minimum model of prokaryotes | p. 472 |
The Stoichiometric Principles of Evolution | p. 479 |
Csanyi's general theory of evolution | p. 479 |
Stoichiometric principles of the evolution of prokaryotes | p. 483 |
Evolution to eukaryotes | p. 486 |
Evolution of eukaryotes | p. 491 |
Applications in Biotechnology | p. 493 |
Limits of the prospective development of biotechnology | p. 493 |
One-step chemical syntheses | p. 496 |
Chemical syntheses by reaction networks | p. 498 |
Synthesis of Living Systems | p. 500 |
The objective of synthesis | p. 500 |
Neobiogenesis | p. 502 |
Possibility of an exact proof | p. 506 |
References | p. 509 |
Index | p. 539 |