Recoverable and recyclable catalysts

Title:

Publication Information:

UK : Wiley, 2009

Physical Description:

xviii, 471 p. : ill. ; 26 cm.

ISBN:

9780470681954

Subject Term:

Catalysts -- Recycling

Catalysis

Added Author:

Benaglia, Maurizio

Available:*

Library	Item Barcode	Call Number	Material Type	Item Category 1	Status
Searching... PSZ JB	30000010226193	QD505 R42 2009	Open Access Book	Book	Searching... Unknown

There is continued pressure on chemical and pharmaceutical industries to reduce chemical waste and improve the selectivity and efficiency of synthetic processes. The need to implement green chemistry principles is a driving force towards the development of recoverable and recyclable catalysts.

The design and synthesis of recoverable catalysts is a highly challenging interdisciplinary field combining chemistry, materials science engineering with economic and environmental objectives. Drawing on international research and highlighting recent developments, this book serves as a practical guide for both experts and newcomers to the field.

Topics covered include:

An introduction to the principles of catalyst recovery and recycling Catalysts on insoluble and soluble support materials Thermomorphic catalysts, self-supported catalysts and perfluorous catalytic systems The development of reusable organic catalysts Continuous flow and membrane reactors

Each chapter combines principles with practical information on the synthesis of catalysts and strategies for catalyst recovery. The book concludes with a comparison of different catalytic systems, using case studies to illustrate the key features of each approach.

Recoverable and Recyclable Catalysts is a valuable reference source for academic researchers and professionals from a range of pharmaceutical and chemical industries, particularly those working in catalysis, organic synthesis and sustainable chemistry.

Author Notes

Maurizio Benaglia is Associate Professor at the Department of Organic and Industrial Chemistry, University of Milan, Italy. He is author of over ninety publications in international scientific journals, including five review articles. His current research focuses on stereoselective reactions, synthesis of chiral supramolecular systems, synthesis of supported organometallic and metal-free catalysts, and design and synthesis of new chiral catalysts, and environmentally pure catalysts.

Preface

Acknowledgements

Contributors

1 The Experimental Assay of Catalyst Recovery: General ConceptsJohn A. Gladysz

1.1 Introduction

1.2 Catalyst Precursor vs Catalyst

1.3 Catalyst vs Catalyst Resting State

1.4 Catalyst Inventory: Loss Mechanisms

1.5 Evaluation of Catalyst Recovery

1.6 Prospective

References

2 Surface-functionalized Nanoporous Catalysts for Renewable ChemistryBrian G. Trewyn and Hung-Ting Chen and Victor S.-Y. Lin

2.1 Introduction

2.2 Immobilization Strategies of Heterogeneous Catalysts

2.3 Efficient Heterogeneous Catalysts with Enhanced Reactivity and Selectivity with Functionality

2.4 Other Heterogeneous Catalyst Systems on Nonsilica Supports

2.5 Conclusion

References

3 Insoluble Resin-supported CatalystsGang Zhao and Zhuo Chai

3.1 Introduction

3.2 Transition Metal Catalyzed C_C Bond Formation Reactions

3.3 Oxidation

3.4 Reduction

3.5 Organocatalyzed Reactions

3.6 Annulation Reactions

3.7 Miscellaneous

3.8 Conclusion

References

4 Catalysts Bound to Soluble PolymersTamilselvi Chinnusamy and Petra Hilgers and Oliver Reiser

4.1 Introduction

4.2 Soluble Supports - General Considerations

4.3 Recent Developments of Soluble Polymer-supported Catalysts

4.4 Recent Examples for Reactions Promoted by Catalysts Bound to Soluble Polymers

4.5 Conclusion

List of Abbreviations

References

5 Polymeric, Recoverable Catalytic SystemsQiao-Sheng Hu

5.1 Introduction

5.2 Polymeric Catalyst Systems

5.3 Summary

Acknowledgements

References

6 Thermomorphic CatalystsDavid E. Bergbreiter

6.1 Introduction

6.2 Thermomorphic Catalyst Separation Strategies

6.3 Hydrogenation Reactions Under Thermomorphic Conditions

6.4 Hydroformylation Reactions Under Thermomorphic Conditions

6.5 Hydroaminations Under Thermomorphic Conditions

6.6 Pd-catalyzed Reactions Under Thermomorphic Conditions

6.7 Polymerization Reactions Under Thermomorphic Conditions

6.8 Organocatalysis Under Thermomorphic Conditions

6.9 Cu(I)-catalyzed 1,3-Dipolar Cycloadditions Under Thermomorphic Conditions

6.10 Thermomorphic Hydrosilylation Catalysts

6.11 Thermomorphic Catalytic Oxidations

6.12 Conclusions

References

7 Self-supported Asymmetric CatalystsWenbin Lin and David J. Mihalcik

7.1 Introduction

7.2 Self-supported Asymmetric Catalysts Formed by Linking Catalytically Active Subunits via Metal-Ligand Coordination

7.3 Self-supported Asymmetric Catalysts Formed by Post-synthetic Modifications of Coordination Polymers

7.4 Self-supported Asymmetric Catalysts Formed by Linking Multitopic Chiral Ligands with Catalytic Metal Centers

7.5 Conclusions and Outlook

Acknowledgments

References

8 Fluorous Chiral Catalyst ImmobilizationTibor Soós

8.1 Introduction

8.2 Fluorous Chemistry and its Basic Recovery Concepts

8.3 Application of Fluorous Chiral Catalysts

8.4 Summary

References

9 Biphasic Catalysis: Catalysis in Supercritical CO2 and in WaterSimon L. Desset and David J. Cole-Hamilton

9.1 Introduction

9.2 Biphasic Catalysis

9.3 Aqueous Biphasic Catalysis

9.4 Supercritical Carbon Dioxide

9.5 Conclusion

References

10 Asymmetric Catalysis in Ionic LiquidsLijin Xu and Jianliang Xiao

10.1 Introduction

10.2 Metal-catalyzed Asymmetric Reactions in ILs

10.3 Asymmetric Organocatalytic Reactions in ILs

10.4 Concluding Remarks

References

11 Recoverable Organic CatalystsMaurizio Benaglia

11.1 Introduction

11.2 Achiral Organic Catalysts

11.3 Chiral Organic Catalysts

11.4 Catalysts Derived from Amino Acids

11.5 General Considerations on Recyclable Organocatalysts

11.6 Outlook and Perspectives

References

12 Organic Polymer-microencapsulated Metal CatalystsJun Ou and Patrick H. Toy

12.1 Introduction

12.2 Non-cross-linked Polymer-microencapsulated Catalysts

12.3 Cross-linked Polymer-microencapsulated Catalysts

12.4 Summary Table

12.5 Conclusions

References

13 Organic Synthesis with Mini Flow Reactors Using Immobilised CatalystsSascha Ceylan and Andreas Kirschning

13.1 Introduction

13.2 Catalysis in Mini Flow Reactors with Immobilised Catalysts

13.3 Miscellaneous Enabling Techniques for Mini Flow Systems

13.4 Perspectives and Outlook

References

14 Homogeneous Catalysis Using Microreactor TechnologyJohan C. Brandt and Thomas Wirth

14.1 Introduction

14.2 Acid-catalysed Reactions

14.3 Liquid-liquid Biphasic Systems

14.4 Photocatalysis

14.5 Asymmetric Catalytic Reactions

14.6 Unusual Reaction Conditions

References

15 Catalyst Immobilization Strategy: Some General Considerations and a Comparison of the Main Features of Different SupportsFranco Cozzi

15.1 Introduction

15.2 General Considerations on Catalyst Immobilization

15.3 Comparison of Different Supports Employed for the Immobilization of Proline

15.4 Comparison of Different Supports Employed for the Immobilization of Bis(oxazolines)

15.5 Conclusions

References

Index

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On Order

Summary

Summary

Author Notes

Table of Contents