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Cover image for Applied surface thermodynamics
Title:
Applied surface thermodynamics
Series:
Surfactant science series ; 151
Edition:
2nd ed.
Publication Information:
Boca Raton, FL : Taylor & Francis, 2011
Physical Description:
xxii, 743 p. : ill. ; 25 cm.
ISBN:
9780849396878

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30000010237028 QC173.4.S94 A67 2011 Open Access Book Book
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Summary

Summary

Surface thermodynamics forms the foundation of any meaningful study of capillarity and wetting phenomena. The second edition of Applied Surface Thermodynamics offers a comprehensive state-of-the-art treatment of this critical topic. It provides students and researchers with fundamental knowledge and practical guidelines in solving real-world problems related to the measurement and interpretation of interfacial properties.

Containing 40 percent new material and reorganized content, this second edition begins by presenting a generalized Gibbs theory of capillarity, including discussions of highly curved interfaces. Concentrating on drop-shape techniques, the book discusses liquid-fluid interfacial tension and its measurement. Next, the authors focus on contact angles with chapters on experimental procedures, thermodynamic models, and the interpretation of contact angles in terms of solid surface tension. The book discusses theoretical approaches to determining solid surface tension as well as interfacial tensions of particles and their manifestations. It concludes by discussing drop size dependence of contact angles and line tension.

What's New in the Second Edition:

Recent progress in Axisymmetric Drop Shape Analysis (ADSA) Image processing methods for drop shape analysis Advanced applications and generalizations of ADSA Recent studies of contact angle hysteresis Contact angles on inert fluoropolymers Update on line tension and the drop size dependence of contact angles

Exploring a range of different aspects of surface science and its applications, the book logically progresses so that knowledge of previous chapters enhances the understanding of subsequent material, yet each chapter is freestanding so that experienced researchers can quickly refer to topics of particular interest.


Author Notes

A. W. Neumann is a Professor Emeritus in the Department of Mechanical and Industrial Engineering at the University of Toronto. He received his PhD in chemical physics from the University of Mainz in 1962.

Robert David is a Postdoctoral Fellow in the Departments of Mechanical and Industrial Engineering and Cell and Systems Biology at the University of Toronto. He received his PhD in Mechanical Engineering from MIT in 2006.

Yi Zuo is an Assistant Professor in the Department of Mechanical Engineering at the University of Hawaii at Manoa. He received his PhD in Mechanical and Industrial Engineering from the University of Toronto in 2006.


Table of Contents

John Gaydos and Yehuda Rotenberg and Pu Chen and Ladislav Boruvka and A. Wilhelm NeumannJohn Gaydos and A. Wilhelm NeumannMina Hoorfar and A. Wilhelm NeumannYi Zuo and A. Wilhelm NeumannYi Zuo and Julia Maldonado-Valderrama and Miguel Cabrerizo-Vílchez and Arash Bateni and M. Guadalupe Cabezas and Robert David and A. Wilhelm NeumannHossein TavanaHossein TavanaHossein Tavana and A. Wilhelm NeumannRobert David and Jan Spelt and Junfeng Zhang and Daniel KwokElio Moy and Robert David and A. Wilhelm NeumannYi Zuo and Dongqing Li and A. Wilhelm NeumannDongqing Li and Yi Zuo and A. Wilhelm NeumannRobert David and A. Wilhelm Neumann
Prefacep. xv
Editorsp. xix
Contributorsp. xxi
Chapter 1 Outline of the Generalized Theory of Capillarityp. 1
Chapter 2 Thermodynamics of Simple Axisymmetric Capillary Systemsp. 49
Chapter 3 Axisymmetric Drop Shape Analysis (ADSA)p. 107
Chapter 4 Image Analysis for Axisymmetric Drop Shape Analysisp. 175
Chapter 5 Generalization and Advanced Application of Axisymmetric Drop Shape Analysisp. 205
Chapter 6 Contact Angle Measurements: General Procedures and Approachesp. 283
Chapter 7 Thermodynamic Status of Contact Anglesp. 329
Chapter 8 Interpretation of Contact Anglesp. 423
Chapter 9 Contact Angles and Solid Surface Tensionsp. 491
Chapter 10 Theoretical Approaches for Estimating Solid-Liquid Interfacial Tensionsp. 555
Chapter 11 Wettability and Surface Tension of Particlesp. 599
Chapter 12 Behavior of Particles at Solidification Frontsp. 633
Chapter 13 Line Tension and the Drop Size Dependence of Contact Anglesp. 701
Indexp. 735
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