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Library | Item Barcode | Call Number | Material Type | Item Category 1 | Status |
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Searching... | 30000010321840 | QC762 E44 2013 | Open Access Book | Book | Searching... |
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Summary
Summary
Specialist Periodical Reports provide systematic and critical review coverage in major areas of chemical research. Compiled by teams of leading authorities in the relevant subject, the series creates a unique service for the active research chemist with regular critical in-depth accounts of progress in particular areas of chemistry. Subject coverage of all volumes is very similar and publication is on an annual or biennial basis. As EPR continues to find new applications in virtually all areas of modern science, including physics, chemistry, biology and materials science, this series caters not only for experts in the field, but also those wishing to gain a general overview of EPR applications in a given area.
Author Notes
Professor Bruce Gilbert is emeritus Professor at the University of York and Chairs the Specialist Periodical Report editorial board. Dr Victor Chechik is at the University of York. Dr Damien Murphy is at the Cardiff University.
Table of Contents
Preface | p. v |
EPR characterization of diamagnetic and magnetic organic soft materials using nitroxide spin probe techniques | p. 1 |
1 Introduction | p. 1 |
2 Non-LC nitroxide spin probes in diamagnetic LC hosts | p. 2 |
3 LC nitroxide spin probes in diamagnetic LC hosts | p. 4 |
4 Magnetic properties of second-generation of rod-like LC nitroxide radical materials | p. 7 |
5 Conclusions | p. 19 |
References | p. 20 |
Inorganic and organometallic radicals of main group elements | p. 22 |
1 Introduction | p. 22 |
2 New and improved methods | p. 23 |
3 Small open-shell inorganic molecules | p. 24 |
4 Group 2 elements | p. 27 |
5 Boron | p. 28 |
6 Aluminium → Indium | p. 32 |
7 Carbon | p. 32 |
8 Silicon → Lead | p. 33 |
9 Phosphorus radicals | p. 37 |
10 Arsenic → Bismuth | p. 41 |
11 Nitrogen chalcogenides | p. 42 |
Acknowledgments | p. 50 |
References | p. 50 |
State mixing, electron spin relaxation, and chain dynamics in transient flexible 1,n-biradicals | p. 58 |
Introduction | p. 58 |
Conclusions | p. 76 |
References | p. 77 |
EPR approaches to disorder in proteins | p. 79 |
1 Areas in which protein disorder is relevant | p. 79 |
2 Methods | p. 82 |
3 Examples from the recent literature | p. 88 |
4 Case studies | p. 90 |
5 Conclusions | p. 95 |
Abbreviations | p. 95 |
References | p. 95 |
Resolving protein-semiquinone interactions by two-dimensional ESEEM spectroscopy | p. 103 |
1 Introduction | p. 103 |
2 Quinone processing sites in proteins | p. 105 |
3 Spectroscopic background | p. 117 |
4 Interactions of SQ with protons in model systems and proteins | p. 125 |
5 14 N and 15 N ID and 2D ESEEM spectra | p. 141 |
6 13 C and 17 O labeling in the study of SQ conformation 158 and spin density distribution | p. 158 |
7 Exploring the spectroscopic data in structural models of SQ-protein interactions | p. 161 |
8 Conclusion | p. 169 |
Acknowledgements | p. 169 |
References | p. 169 |
Electron paramagnetic resonance oxygen imaging in vivo | p. 180 |
1 Introduction | p. 180 |
2 Principles of EPR | p. 181 |
3 Principles of oximetry | p. 182 |
4 Spin probes | p. 183 |
5 EPR imaging equipment for in vivo oximetry | p. 187 |
6 Principles of imaging | p. 187 |
7 Biomedical applications of oxygen imaging | p. 196 |
8 Problems of oximetry | p. 198 |
Conclusion | p. 202 |
References | p. 203 |
High-frequency and -field electron paramagnetic resonance of transition metal ion (d block) coordination complexes | p. 209 |
1 Introduction | p. 209 |
2 Background on HFEPR instrumentation | p. 210 |
3 Background on HFEPR theory | p. 213 |
4 HFEPR studies of mononuclear transition metal (d Block) coordination complexes | p. 215 |
5 HFEPR studies of dinuclear transition metal (d block) coordination complexes | p. 230 |
6 HFEPR studies of polynuclear metal clusters | p. 239 |
7 Conclusions | p. 250 |
References | p. 250 |
Supplementary material | p. 262 |
References and notes | p. 262 |
Molecular interpretation of EPR parameters û computational spectroscopy approaches | p. 264 |
1 Introduction | p. 264 |
2 Spin Hamiltonian | p. 265 |
3 Overview of current electronic structure methods | p. 266 |
4 Calculation of SH parameters ù the machinery | p. 275 |
5 Benchmarking studies and applications | p. 287 |
References | p. 305 |