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Cover image for Fundamentals in air pollution : from processes to modelling
Title:
Fundamentals in air pollution : from processes to modelling
Personal Author:
Publication Information:
Dordrecht ; New York : Springer, c2010
Physical Description:
x, 299 p. : ill. ; 24 cm.
ISBN:
9789048129690

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30000010256922 TD881 S664 2010 Open Access Book Book
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Summary

Summary

This book is a translation of the French book "Pollution atmosph rique. Des p- cessus la mod lisation", published by Springer France (2007). The content is mainly derived from a course devoted to air pollution I taught at cole nationale des ponts et chauss es (ENPC; one of the foremost French high schools, at ParisTech Institute of Technology and University Paris-Est) during the decade 1997-2006. This book has of course been deeply in uenced by my research activity at CEREA, the Teaching and Research Center for Atmospheric Envir- ment, a joint laboratory between ENPC and the Research and Development Di- sion of Electricit de France (EDF R&D), that I created and then headed from 2002 to 2007. I want to thank many of my colleagues for discussions, help and review. Thanks to Vivien Mallet for his careful review, his availability and his pieces of advice (both for the content and the form of this book). Thanks to Marc Bocquet, Karine Sartelet- Kata, Ir ne Korsakissok for their help in reviewing chapters. I want also to thank a few colleagues for having provided me illustrations from their research work. Thanks to Bastien Albriet, Marc Bocquet, douard Debry, Ir ne Korsakissok, H- sein Malakooti, Denis Qu lo, Yelva Roustan, Karine Sartelet, Christian Seigneur and Marilyne Tombette. Thanks also to the American family, C line and Julien, for their review of the introduction.


Reviews 1

Choice Review

Do not be confused by the word "fundamentals" in this book's title. It is far from being a qualitative treatment of air pollution intended for nonmajors. Sportisse (INRIA, France) begins with introductory background information and follows with chapters titled "Atmospheric Radiative Transfer," "Atmospheric Boundary Layer," and "Gas-phase Atmospheric Chemistry." Further chapters cover atmospheric particulates, aerosol dynamics, and the use of numerical simulation and chemistry transport models. Within this framework, the author briefly discusses traditional topics such as acid rain, ozone depletion, chlorofluorocarbon emissions, photochemical smog, and radioactive emissions from the nuclear accident at Chernobyl. It is assumed that readers are familiar with integral calculus and partial differentials, so the book is probably best for graduate students and advanced undergraduates who have strong mathematics backgrounds. Otherwise, the writing is very clear, and most readers will probably not notice that the book was translated (from French). The work includes about 70 challenging exercises (with solutions) that make it especially useful for self-study by professionals from other fields who wish to review this topic. Valuable for libraries that support programs in environmental chemistry, geophysics, meteorology, and air pollution engineering. Summing Up: Highly recommended. Upper-division undergraduates through professionals/practitioners. H. E. Pence SUNY College at Oneonta


Table of Contents

Introductionp. 1
Greenhouse Effect, Ozone Hole and Air Qualityp. 1
Brief Historyp. 1
Accidents, Impacts and Regulatory Contextp. 4
A Multiplayer Gamep. 8
Role of Scientific Expertisep. 10
Atmospheric Dilemmap. 12
Book Objectives and Organizationp. 14
Bibliographyp. 16
1 Primer for the Atmospheric Compositionp. 17
1.1 Atmospheric Chemical Compositionp. 17
1.1.1 Trace Speciesp. 17
1.1.2 Gases, Aerosols and Water Dropsp. 20
1.1.3 A Few Speciesp. 21
1.1.4 Primary and Secondary Speciesp. 21
1.2 Atmospheric Vertical Structurep. 22
1.2.1 Atmospheric Layersp. 22
1.2.2 Atmospheric Pressurep. 25
1.2.3 Vertical Distribution of Speciesp. 27
1.3 Timescalesp. 30
1.3.1 Timescales of Atmospheric Transportp. 30
1.3.2 Atmospheric Residence Time for a Trace Speciesp. 27
Problems Related to Chap. 1p. 36
2 Atmospheric Radiative Transferp. 46
2.1 Primer for Radiative Transferp. 46
2.1.1 Definitionsp. 46
2.1.2 Energy Transitionsp. 46
2.1.3 Emissionsp. 50
2.1.4 Absorptionp. 52
2.1.5 Scatteringp. 55
2.1.6 Radiative Transfer Equationp. 59
2.1.7 Additional Facts for Aerosolsp. 60
2.1.8 Albedop. 62
2.2 Applications to the Earth's Atmospherep. 63
2.2.1 Solar and Terrestrial Radiationp. 63
2.2.2 Radiative Budget for the Earth/Atmosphere Systemp. 68
2.2.3 Greenhouse Effectp. 71
2.2.4 Aerosols, Clouds and Greenhouse Effectp. 77
2.2.5 Atmospheric Pollution and Visibilityp. 84
Problems Related to Chap. 2p. 87
3 Atmospheric Boundary Layerp. 93
3.1 Meteorological Scalesp. 94
3.2 Atmospheric Boundary Layerp. 96
3.2.1 Backgroundp. 96
3.2.2 Classificationp. 97
3.3 Thermal Stratification and Stabilityp. 98
3.3.1 A Few Useful Conceptsp. 99
3.3.2 Stabilityp. 101
3.3.3 Moist Airp. 103
3.3.4 Daily Variation of the ABL Stabilityp. 105
3.4 ABL Turbulencep. 106
3.4.1 Backgroundp. 107
3.4.2 Scale Range and Averagingp. 108
3.4.3 Turbulent Kinetic Energyp. 110
3.4.4 Mixing Height and Turbulence Indicatorsp. 111
3.5 Fundamentals of Atmospheric Dynamicsp. 113
3.5.1 Primer for Fluid Mechanicsp. 113
3.5.2 ABL Flowp. 117
3.6 A Few Facts for the Urban Climatep. 325
3.6.1 Thermal Forcing and Urban Breezep. 125
3.6.2 Energy Budgetp. 126
3.6.3 Urban Heat Islandp. 127
3.6.4 Urban Boundary Layerp. 129
Problems Related to Chap. 3p. 130
4 Gas-Phase Atmospheric Chemistryp. 133
4.1 Primer for Atmospheric Chemistryp. 134
4.1.1 Background for Chemical Kineticsp. 134
4.1.2 Photochemical Reactionsp. 138
4.1.3 Atmosphere as an Oxidizing Reactorp. 142
4.1.4 Chemical Lifetimep. 144
4.1.5 Validity of Chemical Mechanismsp. 149
4.2 Stratospheric Chemistry of Ozonep. 150
4.2.1 Destruction and Production of Stratospheric Ozonep. 150
4.2.2 Ozone Destruction Catalyzed by Bromide and Chloride Compoundsp. 154
4.2.3 Antarctic Ozone Holep. 156
4.3 Tropospheric Chemistry of Ozonep. 159
4.3.1 Basic Facts for Combustionp. 159
4.3.2 Photostationary State of Tropospheric Ozonep. 162
4.3.3 Oxidation Chains of VOCsp. 163
4.3.4 NO x -Limited Versus VOC-Limited Chemical Regimesp. 165
4.3.5 Emission Reduction Strategies for Ozone Precursorsp. 167
4.3.6 Example of Photochemical Pollution at the Regional Scale: Case of Île-de-France Regionp. 170
4.3.7 Transcontinental Transportp. 171
4.4 Brief Introduction to Indoor Air Qualityp. 172
Problems Related to Chap. 4p. 174
5 Aerosols, Clouds and Rainsp. 179
5.1 Aerosols and Particlesp. 180
5.1.1 General Factsp. 180
5.1.2 Residence Time and Vertical Distributionp. 186
5.1.3 Aerosol Dynamicsp. 188
5.1.4 Parameterizationsp. 193
5.2 Aerosols and Cloudsp. 202
5.2.1 Primer for Cloudsp. 202
5.2.2 Saturation Vapor Pressure of Water, Relative Humidity and Dew Pointp. 203
5.2.3 Condensation Nucleip. 204
5.2.4 Mass Transfer Between the Gaseous Phase and Cloud Dropsp. 210
5.3 Acid Rains and Scavengingp. 212
5.3.1 Acid Rainsp. 213
5.3.2 Wet Scavengingp. 218
Problems Related to Chap. 5p. 222
6 Toward Numerical Simulationp. 231
6.1 Reactive Dispersion Equationp. 232
6.1.1 Dilution and Off-Line Couplingp. 232
6.1.2 Advection-Diffusion-Reaction Equationsp. 232
6.1.3 Averaged Models and Closure Schemesp. 234
6.1.4 Boundary Conditionsp. 238
6.1.5 Model Hierarchyp. 239
6.2 Fundamentals of Numerical Analysis for Chemistry-Transport Modelsp. 245
6.2.1 Operator Splitting Methodsp. 245
6.2.2 Time Integration of Chemical Kineticsp. 249
6.2.3 Advection Schemesp. 254
6.3 Numerical Simulation of the General Dynamic Equation for Aerosols (GDE)p. 260
6.3.1 Size Distribution Representationp. 260
6.3.2 Coagulationp. 263
6.3.3 Condensation and Evaporationp. 263
6.4 State-of-the-Art Modeling Systemp. 265
6.4.1 Forward Simulationp. 265
6.4.2 Uncertaintiesp. 265
6.4.3 Advanced Methodsp. 266
6.4.4 Model-to-Data Comparisonsp. 274
6.4.5 Applicationsp. 275
6.5 Next-Generation Modelsp. 278
Problems Related to Chap. 6p. 279
Appendix 1 Units, Constants and Basic Datap. 283
Referencesp. 285
Indexp. 293
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