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Summary
Summary
Industry relies heavily on the combustion process. The already high demand for energy, primarily from combustion, is expected to continue to rapidly increase. Yet, the information is scattered and incomplete, with very little attention paid to the overall combustion system. Designed for practicing engineers, Heat Transfer in Industrial Combustion eclipses the extant literature with an emphasis on the aspects of heat transfer that directly apply to industry.
From a practical point of view, the editor organizes relevant papers into a single, coherent resource. The book encompasses heat transfer, thermodynamics, and fluid mechanics, including the little-covered subjects of the use of oxygen to enhance combustion and flame impingement. Maximizing applications and minimizing theory, it covers modes of heat transfer, computer modeling, heat transfer from flame impingement, from burners, low temperature, high temperature, and advanced applications, and more.
The theoretical focus of most literature has created a clear need for a practical treatment of the heat transfer as it applies to industrial combustion systems. With detailed coverage and extensive references, Heat Transfer in Industrial Combustion fills this void.
Features
Author Notes
Charles E. Baukal, Jr., Ph.D., P.E., is the Director of the John Zink Company LLC R and D Test Center in Tulsa, OK. He has 20 years of experience in the fields of heat transfer and industrial combustion and has authored more than 50 publications in those fields, including editing the book Oxygen-Enhanced Combustion (CRC Press, Boca Raton, FL, 1998). He has a Ph.D. in mechanical engineering from the University of Pennsylvania, is a licensed Professional Engineer in the state of Pennsylvania, has been an adjunct instructor at several colleges, and has eight U.S. patents.
Table of Contents
Chapter 1 Introduction | |
1.1 Importance of Heat Transfer in Industrial Combustion | p. 1 |
1.1.1 Energy Consumption | p. 1 |
1.1.2 Research Needs | p. 1 |
1.2 Literature Discussion | p. 6 |
1.2.1 Heat Transfer | p. 6 |
1.2.2 Combustion | p. 7 |
1.2.3 Heat Transfer and Combustion | p. 7 |
1.3 Combustion System Components | p. 8 |
1.3.1 Burners | p. 8 |
1.3.1.1 Competing Priorities | p. 9 |
1.3.1.2 Design Factors | p. 10 |
1.3.1.3 General Burner Types | p. 13 |
1.3.2 Combustors | p. 18 |
1.3.2.1 Design Considerations | p. 18 |
1.3.2.2 General Classifications | p. 19 |
1.3.3 Heat Load | p. 21 |
1.3.3.1 Process Tubes | p. 21 |
1.3.3.2 Moving Substrate | p. 21 |
1.3.3.3 Opaque Materials | p. 22 |
1.3.3.4 Transparent Materials | p. 22 |
1.3.4 Heat Recovery Devices | p. 23 |
1.3.4.1 Recuperators | p. 23 |
1.3.4.2 Regenerators | p. 23 |
References | p. 24 |
Chapter 2 Some Fundamentals of Combustion | |
2.1 Combustion Chemistry | p. 29 |
2.1.1 Fuel Properties | p. 29 |
2.1.2 Oxidizer Composition | p. 30 |
2.1.3 Mixture Ratio | p. 30 |
2.1.4 Operating Regimes | p. 33 |
2.2 Combustion Properties | p. 34 |
2.2.1 Combustion Products | p. 34 |
2.2.1.1 Oxidizer Composition | p. 34 |
2.2.1.2 Mixture Ratio | p. 37 |
2.2.1.3 Air and Fuel Preheat Temperature | p. 38 |
2.2.1.4 Fuel Composition | p. 40 |
2.2.2 Flame Temperature | p. 40 |
2.2.2.1 Oxidizer and Fuel Composition | p. 40 |
2.2.2.2 Mixture Ratio | p. 41 |
2.2.2.3 Oxidizer and Fuel Preheat Temperature | p. 43 |
2.2.3 Available Heat | p. 43 |
2.2.4 Flue Gas Volume | p. 46 |
2.3 Exhaust Product Transport Properties | p. 48 |
2.3.1 Density | p. 49 |
2.3.2 Specific Heat | p. 51 |
2.3.3 Thermal Conductivity | p. 53 |
2.3.4 Viscosity | p. 55 |
2.3.5 Prandtl Number | p. 58 |
2.3.6 Lewis Number | p. 60 |
References | p. 64 |
Chapter 3 Heat Transfer Modes | |
3.1 Introduction | p. 65 |
3.2 Convection | p. 65 |
3.2.1 Forced Convection | p. 66 |
3.2.1.1 Forced Convection from Flames | p. 66 |
3.2.1.2 Forced Convection from Outside Combustor Wall | p. 68 |
3.2.1.3 Forced Convection from Hot Gases to Tubes | p. 68 |
3.2.2 Natural Convection | p. 68 |
3.2.2.1 Natural Convection from Flames | p. 68 |
3.2.2.2 Natural Convection from Outside Combustor Wall | p. 69 |
3.3 Radiation | p. 69 |
3.3.1 Surface Radiation | p. 72 |
3.3.2 Nonluminous Radiation | p. 82 |
3.3.2.1 Theory | p. 82 |
3.3.2.2 Combustion Studies | p. 90 |
3.3.3 Luminous Radiation | p. 102 |
3.3.3.1 Theory | p. 102 |
3.3.3.2 Combustion Studies | p. 105 |
3.4 Conduction | p. 109 |
3.4.1 Steady-State Conduction | p. 110 |
3.4.2 Transient Conduction | p. 113 |
3.5 Phase Change | p. 114 |
3.5.1 Melting | p. 114 |
3.5.2 Boiling | p. 114 |
3.5.2.1 Internal Boiling | p. 116 |
3.5.2.2 External Boiling | p. 116 |
3.5.3 Condensation | p. 117 |
References | p. 117 |
Chapter 4 Heat Sources and Sinks | |
4.1 Heat Sources | p. 123 |
4.1.1 Combustibles | p. 123 |
4.1.1.1 Fuel Combustion | p. 123 |
4.1.1.2 Volatile Combustion | p. 123 |
4.1.2 Thermochemical Heat Release | p. 124 |
4.1.2.1 Equilibrium TCHR | p. 126 |
4.1.2.2 Catalytic TCHR | p. 127 |
4.1.2.3 Mixed TCHR | p. 127 |
4.2 Heat Sinks | p. 127 |
4.2.1 Load | p. 128 |
4.2.1.1 Tubes | p. 128 |
4.2.1.2 Substrate | p. 129 |
4.2.1.3 Granular Solid | p. 129 |
4.2.1.4 Molten Liquid | p. 131 |
4.2.1.5 Surface Conditions | p. 132 |
4.2.2 Wall Losses | p. 140 |
4.2.3 Openings | p. 143 |
4.2.3.1 Radiation | p. 143 |
4.2.3.2 Gas Flow Through Openings | p. 143 |
4.2.4 Material Transport | p. 145 |
References | p. 145 |
Chapter 5 Computer Modeling | |
5.1 Combustion Modeling | p. 149 |
5.2 Modeling Approaches | p. 150 |
5.2.1 Fluid Dynamics | p. 151 |
5.2.1.1 Moment Averaging | p. 151 |
5.2.1.2 Vortex Methods | p. 152 |
5.2.1.3 Spectral Methods | p. 152 |
5.2.1.4 Direct Numerical Simulation | p. 153 |
5.2.2 Geometry | p. 153 |
5.2.2.1 Zero-Dimensional Modeling | p. 153 |
5.2.2.2 One-Dimensional Modeling | p. 153 |
5.2.2.3 Multi-dimensional Modeling | p. 154 |
5.2.3 Reaction Chemistry | p. 154 |
5.2.3.1 Nonreacting Flows | p. 155 |
5.2.3.2 Simplified Chemistry | p. 155 |
5.2.3.3 Complex Chemistry | p. 156 |
5.2.4 Radiation | p. 156 |
5.2.4.1 Nonradiating | p. 156 |
5.2.4.2 Participating Media | p. 157 |
5.2.5 Time Dependence | p. 158 |
5.2.5.1 Steady State | p. 158 |
5.2.5.2 Transient | p. 158 |
5.3 Simplified Models | p. 159 |
5.4 Computational Fluid Dynamic Modeling | p. 159 |
5.4.1 Increasing Popularity of CFD | p. 159 |
5.4.2 Potential Problems of CFD | p. 161 |
5.4.3 Equations | p. 162 |
5.4.3.1 Fluid Dynamics | p. 162 |
5.4.3.2 Heat Transfer | p. 164 |
5.4.3.3 Chemistry | p. 169 |
5.4.3.4 Multiple Phases | p. 170 |
5.4.4 Boundary and Initial Conditions | p. 171 |
5.4.4.1 Inlets and Outlets | p. 172 |
5.4.4.2 Surfaces | p. 172 |
5.4.4.3 Symmetry | p. 172 |
5.4.5 Discretization | p. 173 |
5.4.5.1 Finite Difference Technique | p. 173 |
5.4.5.2 Finite Volume Technique | p. 174 |
5.4.5.3 Finite Element Technique | p. 175 |
5.4.5.4 Mixed | p. 175 |
5.4.5.5 None | p. 175 |
5.4.6 Solution Methods | p. 175 |
5.4.7 Model Validation | p. 176 |
5.4.8 Industrial Combustion Examples | p. 177 |
5.4.8.1 Modeling Burners | p. 177 |
5.4.8.2 Modeling Combustors | p. 178 |
References | p. 181 |
Chapter 6 Experimental Techniques | |
6.1 Introduction | p. 195 |
6.2 Heat Flux | p. 195 |
6.2.1 Total Heat Flux | p. 195 |
6.2.1.1 Steady-State Uncooled Solids | p. 196 |
6.2.1.2 Steady-State Cooled Solids | p. 196 |
6.2.1.3 Steady-State Cooled Gages | p. 197 |
6.2.1.4 Transient Uncooled Targets | p. 198 |
6.2.1.5 Transient Uncooled Gages | p. 198 |
6.2.2 Radiant Heat Flux | p. 200 |
6.2.2.1 Heat Flux Gage | p. 200 |
6.2.2.2 Ellipsoidal Radiometer | p. 203 |
6.2.2.3 Spectral Radiometer | p. 204 |
6.2.2.4 Other Techniques | p. 204 |
6.2.3 Convective Heat Flux | p. 206 |
6.3 Temperature | p. 207 |
6.3.1 Gas Temperature | p. 207 |
6.3.1.1 Suction Pyrometer | p. 207 |
6.3.1.2 Optical Techniques | p. 209 |
6.3.1.3 Fine Wire Thermocouples | p. 209 |
6.3.1.4 Line Reversal | p. 213 |
6.3.2 Surface Temperature | p. 213 |
6.3.2.1 Embedded Thermocouple | p. 213 |
6.3.2.2 Infrared Detectors | p. 214 |
6.4 Gas Flow | p. 216 |
6.4.1 Gas Velocity | p. 216 |
6.4.1.1 Pitot Tubes | p. 216 |
6.4.1.2 Laser Doppler Velocimetry | p. 218 |
6.4.1.3 Other Techniques | p. 219 |
6.4.2 Static Pressure Distribution | p. 219 |
6.4.2.1 Stagnation Velocity Gradient | p. 219 |
6.4.2.2 Stagnation Zone | p. 220 |
6.5 Gas Species | p. 221 |
6.6 Other Measurements | p. 221 |
6.7 Physical Modeling | p. 223 |
References | p. 223 |
Chapter 7 Flame Impingement | |
7.1 Introduction | p. 231 |
7.2 Experimental Conditions | p. 233 |
7.2.1 Configurations | p. 234 |
7.2.1.1 Flame Normal to a Cylinder in Crossflow | p. 235 |
7.2.1.2 Flame Normal to a Hemispherically Nosed Cylinder | p. 236 |
7.2.1.3 Flame Normal to a Plane Surface | p. 236 |
7.2.1.4 Flame Parallel to a Plane Surface | p. 238 |
7.2.2 Operating Conditions | p. 238 |
7.2.2.1 Oxidizers | p. 238 |
7.2.2.2 Fuels | p. 240 |
7.2.2.3 Equivalence Ratios | p. 240 |
7.2.2.4 Firing Rates | p. 243 |
7.2.2.5 Reynolds Number | p. 243 |
7.2.2.6 Burners | p. 243 |
7.2.2.7 Nozzle Diameter | p. 246 |
7.2.2.8 Location | p. 246 |
7.2.3 Stagnation Targets | p. 246 |
7.2.3.1 Size | p. 247 |
7.2.3.2 Target Materials | p. 248 |
7.2.3.3 Surface Preparation | p. 248 |
7.2.3.4 Surface Temperatures | p. 250 |
7.2.4 Measurements | p. 250 |
7.3 Semianalytical Heat Transfer Solutions | p. 250 |
7.3.1 Equation Parameters | p. 257 |
7.3.1.1 Thermophysical Properties | p. 258 |
7.3.1.2 Stagnation Velocity Gradient | p. 261 |
7.3.2 Equations | p. 263 |
7.3.2.1 Sibulkin Results | p. 263 |
7.3.2.2 Fay and Riddell Results | p. 263 |
7.3.2.3 Rosner Results | p. 264 |
7.3.3 Comparisons With Experiments | p. 264 |
7.3.3.1 Forced Convection (Negligible TCHR) | p. 264 |
7.3.3.2 Forced Convection with TCHR | p. 266 |
7.3.4 Sample Calculations | p. 268 |
7.3.4.1 Laminar Flames Without TCHR | p. 268 |
7.3.4.2 Turbulent Flames Without TCHR | p. 269 |
7.3.4.2 Laminar Flames with TCHR | p. 270 |
7.3.5 Summary | p. 270 |
7.4 Empirical Heat Transfer Correlations | p. 271 |
7.4.1 Thermophysical Properties | p. 272 |
7.4.2 Flames Impinging Normal to a Cylinder | p. 272 |
7.4.2.1 Local Convection Heat Transfer | p. 273 |
7.4.2.2 Average Convection Heat Transfer | p. 273 |
7.4.2.3 Average Convection Heat Transfer with TCHR | p. 274 |
7.4.2.4 Average Radiation Heat Transfer | p. 274 |
7.4.2.5 Maximum Convection and Radiation Heat Transfer | p. 275 |
7.4.3 Flames Impining Normal to a Hemi-Nosed Cylinder | p. 275 |
7.4.3.1 Local Convection Heat Transfer | p. 275 |
7.4.3.2 Local Convection Heat Transfer with TCHR | p. 276 |
7.4.4 Flames Impinging Normal to a Plane Surface | p. 276 |
7.4.4.1 Local Convection Heat Transfer | p. 276 |
7.4.4.2 Local Convection Heat Transfer with TCHR | p. 279 |
7.4.4.3 Average Convection Heat Transfer | p. 279 |
7.4.5 Flames Parallel to a Plane Surface | p. 280 |
7.4.5.1 Local Convection Heat Transfer With TCHR | p. 280 |
7.4.5.2 Local Convection and Radiation Heat Transfer | p. 281 |
References | p. 281 |
Chapter 8 Heat Transfer from Burners | |
8.1 Introduction | p. 285 |
8.2 Open-Flame Burners | p. 285 |
8.2.1 Momentum Effects | p. 285 |
8.2.2 Flame Luminosity | p. 285 |
8.2.3 Firing Rate Effects | p. 287 |
8.2.4 Flame Shape Effects | p. 292 |
8.3 Radiant Burners | p. 296 |
8.3.1 Perforated Ceramic or Wire Mesh Radiant Burners | p. 300 |
8.3.2 Flame Impingement Radiant Burners | p. 301 |
8.3.3 Porous Refractory Radiant Burners | p. 302 |
8.3.4 Advanced Ceramic Radiant Burners | p. 307 |
8.3.5 Radiant Wall Burners | p. 311 |
8.3.6 Radiant Tube Burners | p. 311 |
8.4 Effects on Heat Transfer | p. 316 |
8.4.1 Fuel Effects | p. 316 |
8.4.1.1 Solid Fuels | p. 316 |
8.4.1.2 Liquid Fuels | p. 316 |
8.4.1.3 Gaseous Fuels | p. 316 |
8.4.1.4 Fuel Temperature | p. 317 |
8.4.2 Oxidizer Effects | p. 318 |
8.4.2.1 Oxidizer Composition | p. 318 |
8.4.2.2 Oxidizer Temperature | p. 318 |
8.4.3 Staging Effects | p. 320 |
8.4.3.1 Fuel Staging | p. 321 |
8.4.3.2 Oxidizer Staging | p. 322 |
8.4.4 Burner Orientation | p. 322 |
8.4.4.1 Hearth-Fired Burners | p. 323 |
8.4.4.2 Wall-Fired Burners | p. 324 |
8.4.4.3 Roof-Fired Burners | p. 325 |
8.4.4.4 Side-Fired Burners | p. 326 |
8.4.5 Heat Recuperation | p. 326 |
8.4.5.1 Regenerative Burners | p. 327 |
8.4.5.2 Recuperative Burners | p. 329 |
8.4.5.3 Furnace or Flue Gas Recirculation | p. 331 |
8.4.6 Pulse Combustion | p. 331 |
8.5 In-Flame Treatment | p. 335 |
References | p. 337 |
Chapter 9 Heat Transfer in Furnaces | |
9.1 Introduction | p. 345 |
9.2 Furnaces | p. 346 |
9.2.1 Firing Method | p. 347 |
9.2.1.1 Direct Firing | p. 347 |
9.2.1.2 Indirect Firing | p. 347 |
9.2.1.3 Heat Distribution | p. 349 |
9.2.2 Load Processing Method | p. 351 |
9.2.2.1 Batch Processing | p. 351 |
9.2.2.2 Continuous Processing | p. 351 |
9.2.2.3 Hybrid Processing | p. 352 |
9.2.3 Heat Transfer Medium | p. 352 |
9.2.3.1 Gaseous Medium | p. 352 |
9.2.3.2 Vacuum | p. 353 |
9.2.3.3 Liquid Medium | p. 353 |
9.2.3.4 Solid Medium | p. 354 |
9.2.4 Geometry | p. 354 |
9.2.4.1 Rotary Geometry | p. 355 |
9.2.4.2 Rectangular Geometry | p. 358 |
9.2.4.3 Ladle Geometry | p. 358 |
9.2.4.4 Vertical Cylindrical Geometry | p. 360 |
9.2.5 Furnace Types | p. 360 |
9.2.5.1 Reverberatory Furnace | p. 360 |
9.2.5.2 Shaft Kiln | p. 362 |
9.2.5.3 Rotary Furnace | p. 362 |
9.3 Heat Recovery | p. 363 |
9.3.1 Recuperators | p. 364 |
9.3.2 Regenerators | p. 364 |
9.3.3 Gas Recirculation | p. 366 |
9.3.3.1 Flue Gas Recirculation | p. 366 |
9.3.3.2 Furnace Gas Recirculation | p. 366 |
References | p. 367 |
Chapter 10 Lower Temperature Applications | |
10.1 Introduction | p. 369 |
10.2 Ovens and Dryers | p. 369 |
10.2.1 Predryer | p. 369 |
10.2.2 Dryer | p. 372 |
10.3 Fired Heaters | p. 375 |
10.3.1 Reformer | p. 376 |
10.3.2 Process Heater | p. 378 |
10.4 Heat Treating | p. 384 |
10.4.1 Standard Atmosphere | p. 387 |
10.4.2 Special Atmosphere | p. 387 |
References | p. 391 |
Chapter 11 Higher Temperature Applications | |
11.1 Introduction | p. 395 |
11.1.1 Furnaces | p. 395 |
11.1.2 Industries | p. 395 |
11.2 Metals Industry | p. 396 |
11.2.1 Ferrous Metal Production | p. 396 |
11.2.1.1 Electric Arc Furnace | p. 396 |
11.2.1.2 Smelting | p. 399 |
11.2.1.3 Ladle Preheating | p. 399 |
11.2.1.4 Reheating Furnace | p. 402 |
11.2.1.5 Forging | p. 407 |
11.2.2 Aluminum Metal Production | p. 408 |
11.3 Minerals Industry | p. 410 |
11.3.1 Glass | p. 411 |
11.3.1.1 Types of Traditional Glass-Melting Furnaces | p. 412 |
11.3.1.2 Unit Melter | p. 412 |
11.3.1.3 Recuperative Melter | p. 412 |
11.3.1.4 Regenerative or Siemens Furnace | p. 412 |
11.3.1.5 Oxygen-Enhanced Combustion for Glass Production | p. 414 |
11.3.1.6 Advanced Techniques for Glass Production | p. 416 |
11.3.2 Cement and Lime | p. 417 |
11.3.3 Bricks, Refractories, and Ceramics | p. 419 |
11.4 Waste Incineration | p. 419 |
11.4.1 Types of Incinerators | p. 422 |
11.4.1.1 Municipal Waste Incinerators | p. 422 |
11.4.1.2 Sludge Incinerators | p. 423 |
11.4.1.3 Mobile Incinerators | p. 424 |
11.4.1.4 Transportable Incinerators | p. 425 |
11.4.1.5 Fixed Hazardous Waste Incinerators | p. 425 |
11.4.2 Heat Transfer in Waste Incineration | p. 426 |
References | p. 428 |
Chapter 12 Advanced Combustion Systems | |
12.1 Introduction | p. 433 |
12.2 Oxygen-Enhanced Combustion | p. 433 |
12.2.1 Typical Use Methods | p. 434 |
12.2.1.1 Air Enrichment | p. 434 |
12.2.1.2 O[subscript 2] Lancing | p. 435 |
12.2.1.3 Oxy/Fuel | p. 435 |
12.2.1.4 Air-Oxy/Fuel | p. 436 |
12.2.2 Operating Regimes | p. 437 |
12.2.3 Heat Transfer Benefits | p. 437 |
12.2.3.1 Increased Productivity | p. 437 |
12.2.3.2 Higher Thermal Efficiencies | p. 438 |
12.2.3.3. Higher Heat Transfer Efficiency | p. 438 |
12.2.3.4 Increased Flexibility | p. 438 |
12.2.4 Potential Heat Transfer Problems | p. 439 |
12.2.4.1 Refractory Damage | p. 439 |
12.2.4.2 Nonuniform Heating | p. 440 |
12.2.5 Industrial Heating Applications | p. 440 |
12.2.5.1 Metals | p. 440 |
12.2.5.2 Minerals | p. 440 |
12.2.5.3 Incineration | p. 441 |
12.2.5.4 Other | p. 441 |
12.3 Submerged Combustion | p. 441 |
12.3.1 Metals Production | p. 441 |
12.3.2 Minerals Production | p. 443 |
12.3.3 Liquid Heating | p. 444 |
12.4 Miscellaneous | p. 444 |
12.4.1 Surface Combustor-Heater | p. 445 |
12.4.2 Direct-Fired Cylinder Dryer | p. 445 |
References | p. 446 |
Appendices | |
Appendix A Reference Sources for Further Information | p. 449 |
Appendix B Common Conversions | p. 451 |
Appendix C Methods of Expressing Mixture Ratios for CH[subscript 4], C[subscript 3]H[subscript 8], and H[subscript 2] | p. 453 |
Appendix D Properties for CH[subscript 4], C[subscript 3]H[subscript 8], and H[subscript 2] Flames | p. 459 |
Appendix E Fluid Dynamics Equations | p. 497 |
Appendix F Material Properties | p. 501 |
Author Index | p. 521 |
Subject Index | p. 535 |