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Cover image for Introduction to hydrogen technology
Title:
Introduction to hydrogen technology
Publication Information:
New York : John Wiley, 2009
Physical Description:
x, 307 p. : ill. (some col.) ; 26 cm.
ISBN:
9780471779858
Added Author:

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Item Category 1
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30000010205211 TP245.H9 I57 2009 Open Access Book Book
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30000010285366 TP245.H9 I57 2009 Open Access Book Book
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Summary

Summary

Introduction to Hydrogen Technology explains the basic chemistry that underlies promising, innovative new technologies such as hydrogen fuel cells. Incorporating information on the latest developments and current research on alternative energy sources, this book: Covers chemistry fundamentals relating to hydrogen technology, including reversible reactions and chemical equilibrium, acid-base chemistry, thermodynamics, reaction kinetics, electrochemistry, organic reactions involving hydrogen, polymer chemistry, photochemistry, and plasma chemistry Discusses various types of hydrogen fuel cells and diverse fuel cell applications Addresses the production techniques and the infrastructure necessary to support hydrogen-based energy sources
This is a hands-on resource for scientists and researchers working with hydrogen-based technologies and an excellent reference for students in engineering, science, environmental science, and applied science and technology. This book also will be useful for the general public interested in sustainable energy.


Author Notes

Roman J. Press is a former distinguished researcher at the Rochester Institute of Technology (RIT), where his work involved hydrogen applications and the use of renewable energy. He holds twenty-six patents and has authored numerous publications. His industrial experience includes work at General Motors, Delphi, and Quantum Technologies
K. S. V. Santhanam is a Professor in RIT's Department of Chemistry and the Director of the Center for Materials Science and Engineering, a member of RIT's Task Force on Nanotechnology, and an affiliated faculty member of the Golisano Institute for Sustainability. He is an elected corresponding member of Sachsische Akademie der Wissenschaften zu Leipzig, and a member of the American Chemical Society, Materials Research Society, and the Electrochemical Society
Massoud J. Miri is a Professor in the Department of Chemistry and the Center for Materials Science and Engineering at RIT. He is a member of the American Chemical Society (including its Division of Polymer Chemistry, POLYED Committee, and Division of Polymeric Materials Science and Engineering), and a member of the Sigma Xi Research Society
Alla V. Bailey is a faculty member in the Department of Chemistry at RIT; formerly the principal researcher at Plastpolymer company in St. Petersburg, Russia. She holds forty patents, has authored numerous scientific publications, including three books, and holds the highest scientific degree in Europe, D.Sci
Gerald A. Takacs is Professor of Chemistry, a member of the materials science and engineering graduate faculty, an extended faculty member in microsystems engineering, and an affiliated faculty member of the Golisano Institute for Sustainability


Table of Contents

Prefacep. ix
1 Available Energy Resourcesp. 1
1.1 Civilization and the Search for Sustainable Energyp. 1
1.2 The Planet's Energy Resources and Energy Consumptionp. 4
1.3 The Greenhouse Effect and Its Influence on Quality of Life and the Ecospherep. 6
1.4 Nonrenewable Energy Resourcesp. 10
1.5 Renewable Energy Sourcesp. 18
1.6 Energy Storagep. 34
1.7 Energy Ethicsp. 36
2 Chemistry Backgroundp. 39
2.1 Reversible Reactions and Chemical Equilibriump. 39
2.2 Acid-Base Chemistryp. 46
2.3 Chemical Thermodynamicsp. 57
2.4 Chemical Kineticsp. 74
2.5 Electrochemistry (Oxidation-Reduction Reactions)p. 95
2.6 Organic Chemistryp. 99
2.7 Polymer Chemistryp. 125
2.8 Photochemistryp. 150
2.9 Plasma Chemistryp. 162
3 Hydrogen Propertiesp. 173
3.1 Occurrence of Hydrogen, Properties and Usep. 173
3.2 Hydrogen as an Energy Carrierp. 181
3.3 Hydrogen Storagep. 183
4 Hydrogen Technologyp. 195
4.1 Production of Hydrogenp. 195
4.2 Hydrogen Infrastructurep. 210
4.3 Hydrogen Safetyp. 214
4.4 Hydrogen Technology Assessmentp. 217
5 Fuel Cell Essentialsp. 225
5.1 Introductionp. 225
5.2 Definition of Fuelp. 227
5.3 What Is a Fuel Value?p. 227
5.4 Why Do We Want to Use Hydrogen as Fuel?p. 228
5.5 Classification of Fuel Cellsp. 229
5.6 Open Circuit Voltages of Fuel Cellsp. 230
5.7 Thermodynamic Estimate of Fuel Cell Voltagep. 235
5.8 Efficiency of a Fuel Cellp. 237
5.9 Efficiency and Temperaturep. 238
5.10 Influence of Electrode Material on Current Outputp. 238
5.11 Pressure Dependence of Fuel Cell Voltagep. 239
5.12 Thermodynamic Prediction of Heat Generated in a Fuel Cellp. 243
5.13 Fuel Cell Managementp. 244
5.14 Rate of Consumption of Hydrogen and Oxygenp. 250
5.15 Rate of Production of Waterp. 250
5.16 Fuel Cross-over Problemp. 250
5.17 Polymer Membranes for PEMFCp. 251
5.18 Parts of PEMFC and Fabricationp. 255
5.19 Alkaline Fuel Cells (AFC)p. 259
5.20 Molten Carbonate Fuel Cell (MCFC)p. 261
5.21 Solid Oxide Fuel Cell (SOFC)p. 265
5.22 Flow Chart for Fuel Cell Developmentp. 270
5.23 Relative Merits of Fuel Cellsp. 272
5.24 Fuel Cells for Special Applicationsp. 273
5.25 Fuel Cell Reformersp. 275
5.26 Fuel Cell System Architecturep. 276
Appendix 5.1 Redox Reactions in DMFCp. 285
6 Fuel Cells Applicationsp. 287
6.1 Stationary Power Productionp. 287
6.2 Fuel Cell Transportationp. 288
6.3 Micro-power Systemsp. 294
6.4 Mobile and Residential Power Systemsp. 296
6.5 Fuel Cells for Space and Military Applicationsp. 296
6.6 Conclusionp. 297
Indexp. 299
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