Cover image for Green chemistry and engineering
Title:
Green chemistry and engineering
Personal Author:
Edition:
1st ed.
Publication Information:
Amsterdam : Academic Press, 2007
Physical Description:
vii, 326 p. : ill. ; 23 cm.
ISBN:
9780123725325

Available:*

Library
Item Barcode
Call Number
Material Type
Item Category 1
Status
Searching...
30000010241792 TP155.2.E58 D63 2007 Open Access Book Gift Book
Searching...
Searching...
30000003483769 TP155.2.E58 D63 2007 Open Access Book Book
Searching...

On Order

Summary

Summary

Chemical processes provide a diverse array of valuable products and materials used in applications ranging from health care to transportation and food processing. Yet these same chemical processes that provide products and materials essential to modern economies, also generate substantial quantities of wastes and emissions. Green Chemistry is the utilization of a set of principles that reduces or eliminate the use or generation of hazardous substances in design. Due to extravagant costs needed to managing these wastes, tens of billions of dollars a year, there is a need to propose a way to create less waste. Emission and treatment standards continue to become more stringent, which causes these costs to continue to escalate.

Green Chemistry and Engineering describes both the science (theory) and engineering (application) principles of Green Chemistry that lead to the generation of less waste. It explores the use of milder manufacturing conditions resulting from the use of smarter organic synthetic techniques and the maintenance of atom efficiency that can temper the effects of chemical processes. By implementing these techniques means less waste, which will save industry millions of dollars over time.


Table of Contents

Prefacep. xi
About the Authors...p. xv
1 Introductionp. 1
Definition of Green Chemistryp. 3
Twelve Principles of Green Chemistryp. 3
Initiatives Taken Up by Countries Around the Worldp. 6
The Green Chemistry Expert Systemp. 7
How Green Chemistry Is Being Addressedp. 9
Cross Interactions from Green Chemistryp. 9
The Patent Scenep. 11
The Measure of Greennessp. 11
Safety and Risk Indicesp. 15
Mass and Energy Indicesp. 16
The Hierarchical Approachp. 17
The Sustainable Process Indexp. 21
Conclusionsp. 22
Referencesp. 23
2 Newer Synthetic Methodsp. 27
Introductionp. 27
Use of Microwaves for Synthesisp. 32
Electro-Organic Methodsp. 33
Elegant and Cost-Effective Synthetic Designp. 33
Conclusionsp. 37
Referencesp. 39
Appendix 2.1

p. 40

Referencesp. 42
Appendix 2.2

p. 44

Referencesp. 50
3 Catalysis and Green Chemistryp. 53
Catalysis and Green Chemistryp. 54
Conclusionsp. 66
Referencesp. 66
4 Biocatalysis: Green Chemistryp. 69
Introductionp. 69
Advantages Within Industrial Applicationsp. 70
Challenges to Make Biocatalysis Industrially Viablep. 71
Process Designp. 82
Future Trendsp. 83
Referencesp. 89
5 Alternate Solventsp. 93
Safer Solventsp. 94
Green Solventsp. 97
Water as Solventp. 98
Solvent-Free Conditionsp. 99
Ionic Liquidsp. 99
Conclusionsp. 103
Referencesp. 104
6 Process and Operationsp. 105
Industry Perceptionp. 107
Reactionsp. 112
Reactor Designsp. 113
Micro Mixersp. 117
Unit Operationsp. 121
Reactions with Separation Operationsp. 135
Other New Reactor Designsp. 161
Process Integrationp. 162
Conclusionsp. 167
Referencesp. 168
7 Alternate Energy Sourcesp. 171
Greenhouse Gasesp. 172
Renewable Energyp. 187
Future Sources of Renewable Energyp. 190
Conclusionsp. 190
Referencesp. 191
8 Inherent Safetyp. 193
Conflicts Due to Inherently Safe Designsp. 228
Conclusionsp. 242
Referencesp. 243
9 Industrial Examplesp. 245
The Pharmaceutical Industries and Green Chemistryp. 252
The Polymer Industryp. 264
Pesticides, Antifoulants, and Herbicidesp. 270
Solvents and Green Chemistryp. 274
The Food and Flavor Industryp. 277
The Maleic Anhydride Manufacturing Processp. 280
Chelantsp. 281
The Surfactant Industryp. 283
Industries in Need of Support to Go Greenp. 284
The Semiconductor Manufacture Industryp. 284
The Dye Industryp. 285
The Textile Industryp. 286
The Tannery Industryp. 288
The Sugar and Distillery Industriesp. 288
The Paper and Pulp Industryp. 289
The Pharmaceutical Industryp. 291
Conclusionsp. 293
Referencesp. 294
10 Conclusions and Future Trendsp. 297
Energyp. 297
Process Intensificationp. 299
Biotechnology: The Solution to All Problemsp. 302
Future Predictionsp. 308
Conclusionsp. 310
Referencesp. 311
Indexp. 313