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Searching... | 30000010106523 | QD471 H35 2006 | Open Access Book | Proceedings, Conference, Workshop etc. | Searching... |
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Summary
Summary
With an enormous velocity, olefin polymerization has expanded to one of the most significant fields in polymers since the first industrial use about 50 years ago. In 2005, 100 million tons of polyolefins were produced - the biggest part was catalyzed by metallorganic compounds. The Hamburg Macromolecular Symposium 2005 with the title "Olefin Polymerization" involved topics such as new catalysts and cocatalysts, kinetics, mechanism and polymer reaction engineering, synthesis of special polymers, and characterization of polyolefins. The conference combined scientists from different disciplines to discuss latest research results of polymers and to offer each other the possibility of cooperation. This is reflected in this volume, which contains invited lectures and selected posters presented at the symposium.
Table of Contents
PrefaceW. Kaminsky | |
Topic A New Catalysts and Cocatalysts | |
Ansa-Metallocenes by Intramolecular Ring Closure Reactions - Syntheses and Applications | p. 1 |
Metallocene Catalysts for Olefin Oligomerization | p. 14 |
Syndiospecific Polymerization Catalysts for Styrene Based on Rare Earth Metal Half-Sandwich Complexes | p. 23 |
Novel Initiators for Thermally and UV-Triggered ROMP | p. 30 |
Single-Site Organochromium Catalysts: Synthesis, Characterisation by Paramagnetic NMR and Olefin Polymerisation | p. 38 |
Activation of Metallacyclopropenes, five-membered Metallacyclocumulenes and Metallacyclopentynes of Zirconium with [superscript i]BU[subscript 2] AlH | p. 48 |
[superscript 19]F NMR Investigations of the Reaction of B(C[subscript 6]F[subscript 5])[subscript 3] with Different Tri(alkyl)aluminum Compounds | p. 54 |
Topic B Kinetics, Mechanism, and Polymer Reaction Engineering | |
Methylalumoxane (MAO)-Derived MeMAO[superscript -] Anions in Zirconocene-Based Polymerization Catalyst Systems - A UV-Vis Spectroscopic Study | p. 63 |
Solvent-Ligated Transition Metal Complexes as Initiators for the Polymerization of Isobutene | p. 69 |
Microkinetic Videomicroscopic Analysis of the Olefin-Copolymerization with Heterogeneous Catalysts | p. 78 |
Metal Complexes for the Vinyl Addition Polymerization of Norbornene: New Compound Classes and Activation Mechanism with B(C[subscript 6]F[subscript 5])[subscript 3]/A1Et[subscript 3] | p. 88 |
Anion Influence in Metallocene-based Olefin Polymerisation Catalysts | p. 100 |
Living Olefin Polymerisation and Block Copolymer Synthesis in the Presence of a Single-site Catalyst Containing a Phenoxyimine Ligand | p. 111 |
Synthesis of Very Small Polymer Particles by Catalytic Polymerization in Aqueous Systems | p. 117 |
Tandem Copolymerization: An Effective Control of the Level of Branching and Molecular Weight Distribution | p. 124 |
Using the Transfer Function of an Isoperibolic Reaction Calorimeter for Thermo-kinetic Analysis | p. 134 |
Topic C Synthesis of Special Polymers | |
New Polyolefin Nanocomposites and Catalyst Supports Based on Organophilic Boehmites | p. 145 |
Control of Ultrahigh Molecular Weight Polypropene Microstructures via Asymmetric "Dual-Side" Catalysts | p. 151 |
Ethylene/1,3-Cyclohexadiene Copolymerization by Means of Methylaluminoxane Activated Half-Sandwich Complexes | p. 156 |
Direct Copolymerization of Propene and Ethene-based Macromers to Produce Long Chain Branched Syndiotactic Polypropene | p. 161 |
New Materials Designed by Coordination Polymerization of w-undecenyl Macromonomers | p. 168 |
Coordination Homopolymerization of w-undecenyl Poly(styrene-block-isoprene) Macromonomers in the Presence of CGC-Ti/MAO Complexes | p. 177 |
PP/PMMA Block Copolymers by Combination of ATRP and Metallocene Catalysis | p. 186 |
Synthesis of Copolymers with Sterically Hindered and Polar Monomers | p. 193 |
Polymerization of Polar Monomers Using Cyclopentadienyl Complexes of the Alkaline Earth Metals | p. 203 |
Topic D Characterization of Polyolefins | |
Rheological Characterization of Long-chain Branched Polyethylenes and Comparison with Classical Analytical Methods | p. 209 |
The Rheology of Linear and Long-chain Branched Polymer Melts | p. 219 |
Characterization of Branched Polyolefins by High Temperature GPC Utilizing Function Specific Detectors | p. 228 |
Sorption Studies of Propylene in Polypropylene Polymerized with Novel Ziegler-Natta-Catalysts in Liquid and Gas Phase | p. 235 |
The Study of Cavitation in HDPE Using Time Resolved Synchrotron X-ray Scattering During Tensile Deformation | p. 241 |
Morphology Evolution in the Early Stages of Olefin Polymerization | p. 249 |