Cover image for Olefin polymerization : selected contributions from the conference in Hamburg (Germany), October 10-12, 2005
Title:
Olefin polymerization : selected contributions from the conference in Hamburg (Germany), October 10-12, 2005
Series:
Macromolecular symposia ; 236
Publication Information:
Weinheim, Germany : Wiley-VCH Verlag, 2006
ISBN:
9783527317424

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30000010106523 QD471 H35 2006 Open Access Book Proceedings, Conference, Workshop etc.
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Summary

Summary

With an enormous velocity, olefin polymerization has expanded to one of the most significant fields in polymers since the first industrial use about 50 years ago. In 2005, 100 million tons of polyolefins were produced - the biggest part was catalyzed by metallorganic compounds. The Hamburg Macromolecular Symposium 2005 with the title "Olefin Polymerization" involved topics such as new catalysts and cocatalysts, kinetics, mechanism and polymer reaction engineering, synthesis of special polymers, and characterization of polyolefins. The conference combined scientists from different disciplines to discuss latest research results of polymers and to offer each other the possibility of cooperation. This is reflected in this volume, which contains invited lectures and selected posters presented at the symposium.


Table of Contents

Gerhard ErkerChristoph Janiak and Frederik BlankJulia Hitzbleck and Klaus Beckerle and Jun Okuda and Tobias Halbach and Rolf MulhauptYan Zhang and Dongren Wang and Peter Lonnecke and Thomas Scherzer and Michael R. BuchmeiserMarkus EndersVladimir V. Burlakov and Marc A. Bach and Marcus Klahn and Perdita Arndt and Wolfgang Baumann and Anke Spannenberg and Uwe RosenthalChristoph Janiak and Paul-Gerhard LassahnUlrich Wieser and Frank Schaper and Hans-Herbert BrintzingerOskar Nuyken and Mario Vierle and Fritz E. Kuhn and Yanmei ZhangDaniela Ferrari and Stefan Knoke and Bernd Tesche and Gerhard FinkChristoph Janiak and Paul-Gerhard Lassahn and Vasile LozanPolly A. Wilson and Mark H. Hannant and Joseph A. Wright and Roderick D. Cannon and Manfred BochmannMarc-Stephan Weiser and Rolf MulhauptStefan Mecking and Vincent Monteil and Johannes Huber and Ludmila Kolb and Peter WehrmannMarco Frediani and Christian Piel and Walter Kaminsky and Claudio Bianchini and Luca RosiArnd-Luder Gaulke and Werner Pauer and Hans-Ulrich MoritzRainer Xalter and Tobias S. Halbach and Rolf MulhauptC. Cobzaru and B. RiegerDirk E. Heiser and Frederic Pelascini and Dominic Kramer and Jennifer Scott and Sandro Gambarotta and Jennifer McCahill and Douglas W. Stephan and Jun Okuda and Rolf MulhauptS. Rulhoff and W. KaminskyFrederic Peruch and Edgar Catari and Said Zahraoui and Francois Isel and Pierre Joseph LutzEdgar Catari and Frederic Peruch and Francois Isel and Pierre Joseph LutzAlbrecht Dix and Saija Ptacek and Sven Poser and Manfred ArnoldMatthias Donner and Mercia Fernandes and Walter KaminskyAlexandra Steffens and Herbert SchumannFlorian J. Stadler and Christian Piel and Walter Kaminsky and Helmut MunstedtManfred H. WagnerK. Tribe and G. Saunders and R. MeissnerM. Patzlaff and A. Wittebrock and K.-H. ReichertK. Schneider and S. Trabelsi and N.E. Zafeiropoulos and R. Davies and Chr. Riekel and M. StammXuejing Zheng and Joachim Loos
PrefaceW. Kaminsky
Topic A New Catalysts and Cocatalysts
Ansa-Metallocenes by Intramolecular Ring Closure Reactions - Syntheses and Applicationsp. 1
Metallocene Catalysts for Olefin Oligomerizationp. 14
Syndiospecific Polymerization Catalysts for Styrene Based on Rare Earth Metal Half-Sandwich Complexesp. 23
Novel Initiators for Thermally and UV-Triggered ROMPp. 30
Single-Site Organochromium Catalysts: Synthesis, Characterisation by Paramagnetic NMR and Olefin Polymerisationp. 38
Activation of Metallacyclopropenes, five-membered Metallacyclocumulenes and Metallacyclopentynes of Zirconium with [superscript i]BU[subscript 2] AlHp. 48
[superscript 19]F NMR Investigations of the Reaction of B(C[subscript 6]F[subscript 5])[subscript 3] with Different Tri(alkyl)aluminum Compoundsp. 54
Topic B Kinetics, Mechanism, and Polymer Reaction Engineering
Methylalumoxane (MAO)-Derived MeMAO[superscript -] Anions in Zirconocene-Based Polymerization Catalyst Systems - A UV-Vis Spectroscopic Studyp. 63
Solvent-Ligated Transition Metal Complexes as Initiators for the Polymerization of Isobutenep. 69
Microkinetic Videomicroscopic Analysis of the Olefin-Copolymerization with Heterogeneous Catalystsp. 78
Metal Complexes for the Vinyl Addition Polymerization of Norbornene: New Compound Classes and Activation Mechanism with B(C[subscript 6]F[subscript 5])[subscript 3]/A1Et[subscript 3]p. 88
Anion Influence in Metallocene-based Olefin Polymerisation Catalystsp. 100
Living Olefin Polymerisation and Block Copolymer Synthesis in the Presence of a Single-site Catalyst Containing a Phenoxyimine Ligandp. 111
Synthesis of Very Small Polymer Particles by Catalytic Polymerization in Aqueous Systemsp. 117
Tandem Copolymerization: An Effective Control of the Level of Branching and Molecular Weight Distributionp. 124
Using the Transfer Function of an Isoperibolic Reaction Calorimeter for Thermo-kinetic Analysisp. 134
Topic C Synthesis of Special Polymers
New Polyolefin Nanocomposites and Catalyst Supports Based on Organophilic Boehmitesp. 145
Control of Ultrahigh Molecular Weight Polypropene Microstructures via Asymmetric "Dual-Side" Catalystsp. 151
Ethylene/1,3-Cyclohexadiene Copolymerization by Means of Methylaluminoxane Activated Half-Sandwich Complexesp. 156
Direct Copolymerization of Propene and Ethene-based Macromers to Produce Long Chain Branched Syndiotactic Polypropenep. 161
New Materials Designed by Coordination Polymerization of w-undecenyl Macromonomersp. 168
Coordination Homopolymerization of w-undecenyl Poly(styrene-block-isoprene) Macromonomers in the Presence of CGC-Ti/MAO Complexesp. 177
PP/PMMA Block Copolymers by Combination of ATRP and Metallocene Catalysisp. 186
Synthesis of Copolymers with Sterically Hindered and Polar Monomersp. 193
Polymerization of Polar Monomers Using Cyclopentadienyl Complexes of the Alkaline Earth Metalsp. 203
Topic D Characterization of Polyolefins
Rheological Characterization of Long-chain Branched Polyethylenes and Comparison with Classical Analytical Methodsp. 209
The Rheology of Linear and Long-chain Branched Polymer Meltsp. 219
Characterization of Branched Polyolefins by High Temperature GPC Utilizing Function Specific Detectorsp. 228
Sorption Studies of Propylene in Polypropylene Polymerized with Novel Ziegler-Natta-Catalysts in Liquid and Gas Phasep. 235
The Study of Cavitation in HDPE Using Time Resolved Synchrotron X-ray Scattering During Tensile Deformationp. 241
Morphology Evolution in the Early Stages of Olefin Polymerizationp. 249