Cover image for Polymer nanocomposites: synthesis, characterization, and modeling
Title:
Polymer nanocomposites: synthesis, characterization, and modeling
Series:
ACS symposium series ; 804
Publication Information:
Washington, WA : An American Chemical Society Publication, 2002
Physical Description:
x, 242 p. : ill. ; 24 cm.
ISBN:
9780841237681

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30000010200098 TA418.9.N35 P66 2002 Open Access Book Book
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Summary

Summary

Research during the last ten years, spurred by the development of new analytical techniques, has led to the general recognition that aspects of the nanoscale morphology (1-100nm) are critical in the manifestation of physical properties. Nanoscale fillers, synthesis approaches, processing techniques, and morphological characterization are important facets of the polymer industry. Polymer Nanocomposites: Synthesis, Characterization, and Modeling highlights the unique chemical and physical aspects associated with polymer based nanocomposite materials. Two nonexclusive themes are present throughout the book: 1) techniques to manipulate inorganic morphology in the presence of polymers on the nanometer length scale and 2) physical understanding and implications to properties of the surface absorbed and nanoscopically confined polymers. The volume discusses the development of high performance materials as well as possible future directions for research in the field.


Author Notes

Ramanan Krishnamoorti is at University of Houston.


Table of Contents

Richard A. Vaia and Ramanan KrishnamoortiJon CollisterSumanda Bandyopadhyay and Alex J. Hsieh and Emmanuel P. GiannelisR. T. Paine and E. A. Pruss and G. L. Wood and C. Schwierkowski and R. F. Hill and C. Chapelle and W. J. KroenkeQingye Zhou and Yo Nakamura and Seiji Inaoka and Mi-kyoung Park and Yingfan Wang and Xiaowu Fan and Jimmy Mays and Rigoberto AdvinculaValeriy V. Ginzburg and Anna C. BalazsRex P. HjelmRobert Y. Lochhead and Cheri McConnell BoykinRichard A. Vaia and Derek LincolnRick D. Davis and William L. Jarrett and Lon J. MathiasDerek L. Ho and Robert M. Briber and Charles J. GlinkaR. Limary and P. F. GreenCynthia A. Mitchell and Ramanan KrishnamoortiVincent Ferreiro and Gudrun Schmidt and Charles Han and Alamgir KarimE. Manias and V. KuppaR. K. Bharadwaj and R. A. Vaia and B. L. Farmer
Prefacep. ix
1. Polymer Nanocomposites: Introductionp. 1
2. Commercialization of Polymer Nanocompositesp. 7
3. PMMA Nanocomposites Synthesized by Emulsion Polymerizationp. 15
4. Boron Nitride Fillers for Organic Polymer Compositesp. 27
5. Surface-Initiated Anionic Polymerization: Tethered Polymer Brushes on Silicate Flat Surfacesp. 39
6. Predicting the Phase Behavior of Polymer--Clay Nanocomposites: The Role of End-Functionalized Chainsp. 57
7. Carbon Black Structure and Associations in Filled Rubbersp. 71
8. An Investigative Study of Polymer Adsorption to Smectite Clay: Polyelectrolytes and Sodium Montmorillonitep. 85
9. Mesoscopic Structure of Polymer--Inorganic Nanocompositesp. 99
10. Solution and Solid-State NMR Spectroscopy of Nylon 6--Montmorillonite Clay Nanocompositesp. 117
11. Studies of Organically Modified Clays by Scattering Techniquesp. 127
12. Thin Film Organically Modified Layered Silicate--Polymer Hybrid Materialsp. 141
13. Influence of Layered-Silicates on the Rheological Properties of Diblock Copolymer Nanocompsitesp. 159
14. Dispersion and Nucleating Effects of Clay Fillers in Nanocomposite Polymer Filmsp. 177
15. Molecular Simulations of Ultra-Confined Polymers: Polystyrene Intercalated in Layered-Silicatesp. 193
16. A Coarse-Grained Simulation Study of Polymer Melt Intercalation in Layered Nanostructuresp. 209
Author Indexp. 227
Subject Indexp. 229