Cover image for Thermodynamic properties of complex fluid mixtures
Title:
Thermodynamic properties of complex fluid mixtures
Series:
Research report ;0070-3982
Publication Information:
Weinheim : Wiley-VCH ; Bonn, Federal Republic of Germany : DFG, 2004
ISBN:
9783527277704
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30000010068058 QD549.2.C66 T43 2004 Open Access Book Book
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30000010081792 QD549.2 .C66 T43 2004 Open Access Book Book
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Summary

Summary

A priority programme of the Deutsche Forschungsgemeinschaft (DFG) was conducted to investigate the thermophysical and thermochemical fundamentals relevant for process design in the chemical and petrochemical industry as well as for biotechnological and environmental process sciences. The priority programme comprised 27 projects in which researchers form various disciplines like applied thermodynamics, industrial chemistry, physical chemistry, process sciences, or biotechnology collaborated to solve some of the major problems of modern thermodynamics. The research results are exclusively documented in this book and cover topics like phase equilibrium in chemical reactive mixtures, in aqueous solutions of electrolytes, aqueous two-phase systems and polymer solutions, high pressure fluid phase equilibria, and microemulsion systems. The results contribute to a better understanding of important phase equilibrium phenomena and help to improve process models.


Table of Contents

I Chemical Reactive Systems
1 Experimental and Theoretical Investigations at the System CH3OH + H2SO4 + H2O.Matthias Behmann and Sae-Hoon Kim and Hans-Jürgen Kob and Klaus Lucas
2 Measurement of Binary Phase Equilibria of Esterification Systems.Marko Tischmeyer and Wolfgang Arlt
3 Solubility of Carbon Dioxide in Aqueous Alkanolamine Solutions in the Temperature Range 313 to 353 K and Pressures up to 2.7 MPa.Dirk Silkenbaumer and Bernd Rumpf and Rudiger N. Lichtenthaler
4 The Influence of NO2 on Complex Phase and Reaction Equilibria in Wet Flue Gas Cleaning Processes.Mohammad A. Siddiqi and Jens Petersen and Klaus Lucas
5 An Infrared Spectroscopic Investigation of the Species Distribution in the System NH3 + CO2 + H2O.Ute Lichtfers and Bernd Rumpf
II Associating Mixtures
6 VLLE for Mixtures of Water and Alcohols: Measurements and Correlations.Frank Gremer and Gerhard Herres and Dieter Gorenflo
7 Phase Equilibria in Ternary Systems Containing Phenols, Hydrocarbons, and Water.Jurgen Schmelzer and Klaus Taubert and Antje Martin and Rene Meinhardt and Jochen Kempe
8 Influence of Additives on Hydrophobic Association in Polynary Aqueous Mixtures. An NMR Relaxation and Self-Diffusion Study.Manfred Holz and Manghaiko Mayele
III Aqueous Solutions of Strong Electrolytes
9 Phase Equilibria of Aqueous Solutions Containing Volatile Electrolytes.Jurgen Zipprian and Nils Elm and Karlheinz Schaber
10 Experimental Determination and Prediction of Phase Equilibria in Systems Containing Strong ElectrolytesMagnus Topphoff and Christian Rose and Jorn Kiepe and Jurgen Gmehling
11 Ion Coordination and Thermodynamic Modeling of Molten Salt Hydrate Mixtures.Wolfgang Voigt and Kay Hettrich and Dewen Zeng
12 Effects of Salts on Excess Enthalpies of Binary Liquid Mixtures.Peter Ulbig and Thorsten Friese and Katrin Wagner
13 Hydrate Equilibria in Aqueous Solutions Containing Inhibitors.Armin M. Rock and Lothar R, Oellrich
IV Phase Equilibrium of Aqueous Two-Phase Systems
14 Experimental and Theoretical Investigations on the Precipitation of Polyelectrolytes from Aqueous Solutions by Neutral PolymersThomas Grunfelder and Gerd Maurer
15 Experimental and Theoretical Studies on Partitioning of Native and Unfolded Enzymes in Aqueous Two-Phase SystemsMaria-Regina Kula and Christian Ramsch
16 Experimental and Theoretical Investigation on the Partitioning of Proteins in Aqueous Two-Phase SystemsJochen Brenneisen and Gerd Maurer
V Phase Equilibrium of Polymer Systems
17 Phase Behavior of Quaternary Polymer SolutionsClaudia Barth-Wiedmann and Matthias Wunsch and Bernhard Anton Wolf
18 Calculation of the High Pressure Phase Equilibrium of Mixtures of Ethlene, Poly(ethylene-co-vinylacetate) Copolymers and Vinyl Acetate with a Cubic Equation of StateC. Browarzik and D. Browarzik and H. Kehlen
19 Modeling of Copolymer Phase Equilibria Using the Perturbed-Chain SAFT Equation of StateFeelly Tumakaka and Gabriele Sadowski
20 Cloud Point Pressures of Ethene + Acrylate + Poly(ethene-co-acrylate)SystemsMichael Buback and Markus Busch
21 Gas Expanded Polymer SolutionsBernd Bungert and Wolfgang Arlt
22 Calculation of the Stability and of the Phase Equilibrium on the System Methylcyclohexane + Polystyrene Based on an Equation of StateDieter Browarzik and Mario Kowalewski
VI High-Pressure Phase Equilibria
23 Phase Equilibrium (Solid-Liquid-Gas) in Binary Systems of Poly(ethylene glycols), Poly(ethylene glycol) dimethyl ether with Carbon Dioxide, Propane, and NitrogenEckhard Weidner and Veronika Wiesmet
24 Measurements and Modeling of High-Pressure Fluid Phase Equilibrium of Systems Containing Benzene Derivatives and CO2.Gerd Brunner and Oliver Pfohl and Stanimir Petkov
VII Phase Equilibrium in Microemulsion Systems
25 The Potential of Surfactants Modified Supercritical Fluids for Dissolving Different Classes of SubstancesUta Lewin-KIretzschmar and Peter Harting
26 Liquid-Liquid Phase Equilibria in Microemulsion Forming Systems Based on Carbohydrate Surfactants.Sabine Enders and Dirk Häntzschel and Heike Kahl and Konrad Quitzsch
27 Interactions of Polyelectrolytes and Zwitterionic Surfactants in Aqueous SolutionHeinz Hoffmann and Holger Lauer and Klaus Redlich