Cover image for The chemists's companion : a handbook of practical data, techniques, and references
Title:
The chemists's companion : a handbook of practical data, techniques, and references
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Publication Information:
New York : John Wiley, 1972
ISBN:
9780471315902
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30000002542235 QD65.G6 1972 r Reference Book 1:BOOKREF
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Summary

Summary

Here in one source is a wide variety of practical, everydayinformation often required by chemists but seldom found together,if at all, in the standard handbooks, data collections, manuals,and other usual sources. Discussing physical, chemical, andmechanical properties of substances and systems, the authors answersuch questions as:
* How do I test for and destroy peroxides in different solventsand what is the best way to purify such solvents?
* What are the structure, physical properties, and recentreferences to the use of common-name solvents and solvent aids suchas the "Skellysolves," "Cellosolves," "Crownanes," and"Glymes"?
* What is the utility of a particular molecular sieve, orpermeation gel, or epoxy cement, or liquid crystal, and where do Ibuy them and find references to their application?
The book is divided into nine chapters and covers properties ofatoms and molecules, spectroscopy, photochemistry, chromatography,kinetics and thermodynamics, various experimental techniques, andmathematical and numerical information, including the definitions,values, and usage rules of the newly adopted International Systemof Units (SI Units). A section on statistical treatment of datawhich provides an actual least-squares computer program is alsoincluded. In the spectroscopy chapter, very extensive andup-to-date collections of spectral correlation data are presentedfor ir, uv-vis, optical rotation, nmr, and mass spectra, along withdata on esr and nqr spectroscopy. Also included is a variety ofhard-to-classify but frequently sought information, such as namesand addresses of microanalysis companies and chemistry publishers,descriptions and commercial sources of atomic and molecular models,and safety data for hazardous chemicals. More than 500 keyreferences are also included, most of which are recent. There areimportant hints and definitions associated with the art as well asthe state of the art for the appropriate subjects. Also foundthroughout the book are about 250 suppliers and directions forobtaining special booklets or other material.

Containing a wealth of useful information, The Chemist'sCompanion will be an indispensable guide for students andprofessional chemists in nearly all the chemical disciplines. Inaddition, it will provide for the teacher and student an unusualadjunct for use in a broad cross-section of chemistry courses.


Author Notes

About the Authors ARNOLD J. GORDON is Associate Director of Scientific Affairs at Pfizer Pharmaceuticals. He was previously a member of the chemistry faculty of the Catholic University of America. Dr. Gordon received a B.S. degree in Chemical Engineering from Northeastern University and a Ph.D. degree in Organic Chemistry from New York University. He is the author of more than 25 articles published in journals and books in such diverse areas as stereochemistry, synthesis, new drug development, organic semiconductors and chemical education. R. A. FORD is Assistant Professor at Montgomery College in Takoma Park, Maryland. He was previously Assistant Professor at Catholic University. Dr. Ford received a Ph.D. degree at Wayne State University.


Table of Contents

Properties of Molecular Systems
I Properties of Solvents and Common Liquids
II Azeotropic Data
III Empirical Boiling Point-Pressure Relationships
IV Properties of Selected Gases
V Properties of Representative Fused Salt Systems
VI Structure and Properties of Naturally Occurring -Amino Acids
VII Properties and Applications of Liquid Crystals
VIII Prototropic Tautomerism
IX Acids and Bases?
Properties of Atoms and Bonds
I Properties of the Elements
II Table of Isotopes
III Selected Bond Lengths
IV Effective van der Waals Radii
V Bond Angles and Hybridization
VI Selected Bond Strengths
VII Force Constants
VIII Torsion and Inversion Barriers
IX Bond and Group Dipole Moments
X Aromaticity?
Kinetics and Energetics
I Activation Parameters and Kinetics of Selected Reactions
II Linear Free Energy Relationships
III Conformational Free Energy Values
IV Free Energy-Composition Chart?
Spectroscopy
I The Electromagnetic Spectrum
II Solvents and Other Media for Spectral Measurements
III Optical Materials for Spectroscopy and Photochemistry
IV Vibration Spectra
V Electronic Absorption and Emission Spectra: UV and Vis
VI Optical Activity and Optical Rotation
VII Mass Spectrometry
VIII Nuclear Magnetic Resonance Spectroscopy
IX Electron Spin Resonance Spectroscopy
X Nuclear Quadrupole Resonance Spectroscopy
XI Bibliography of Spectral Data Compilations?
Photochemistry
I Electronic Energy State Diagram
II Excited State Energy Transfer: Sensitizers and Quenchers
III Photochemistry Light Sources and Equipment
IV Chemical Actinometry: Quantum Yield
V Suppliers
VI References?
Chromatography
I Fundamental Types of Chromatography and Basic Definitions
II Adsorption Chromatography
III Paper Chromatography
IV Column and Thin Layer Partition Chromatography
V Ion-Exchange Chromatography
VI Gel Filtration and Gel Permeation Chromatography
VII Automated Liquid Chromatography
VIII Electrophoresis
IX Vapor Phase Chromatography
X Chromatography Supply Directory
XI References?
Experimental Techniques
I Properties of Laboratory Materials
II Standard Glassware Cleaning Solutions
III Purification of Common Solvents
IV Detection of Peroxides and Their Removal
V Chemical Methods for Deoxygenating Gases and Liquids
VI Simple Chemical Methods for Detecting Specific Gases
VII Simple Preparations of Some Dry Gases
VIII Common Solvents for Crystallization
IX Solvents for Extraction of Aqueous Solutions
X Drying Agents
XI Solvents and Baths for Heating and Cooling
XII Molecular Weight Determination?
Mathematical and Numerical Information
I Approved International Units System and General Constants
II Useful Conversion Factors
III Wavelength-Wavenumber Conversion Table
IV Multiples of Element and Group Weights
V Molecular Symmetry: Definitions and Common Systems
VI Character Tables for Common Symmetry Groups
VII Computer Programs
VIII Statistical Treatment of Data?
Miscellaneous
I Important Chemistry Reference Sources: A Bibliography
II Atomic and Molecular Models
III Addresses of Publishers that Deal With Chemistry