Cover image for Laser control and manipulation of molecules
Title:
Laser control and manipulation of molecules
Series:
ACS symposium series ; 821
Publication Information:
Washington, D.C. : American Chemical Society, 2002
ISBN:
9780841237865

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30000010046259 QD461 L38 2002 Open Access Book Book
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Summary

Summary

This book details advances in the studies of chemical dynamics and photochemistry using emerging laser technologies. It examines both theoretical and experimental advances in this field and includes such topics as efficient selectivity in chemical reactions, new pulse shaping techniques, and new tool for realistic control and manipulation of molecules.


Author Notes

A. D. Bandrauk is at Universite de Sherbrooke. Y. Fujimura is at Tohoku University.


Table of Contents

Herschel RabitzSuhail P. Shah and Vandana Kurkal and Stuart A. RiceK. Hoki and Y. FujimuraRichard Billotto and Ani Khachatrian and Langchi Zhu and Robert J. Gordon and Helene Lefebvre-Brion and Tamar SeidmanVadim V. Lozovoy and Matthew Comstock and Marcos DantusJunichi Shimamura and Kenji Mishima and Koichi YamashitaKuninobu Nagaya and Yoshiaki Teranishi and Hiroki NakamuraR. R Jones and S. N. Pisharody and R. van LeeuwenSeogjoo Jang and Jianshu CaoTakashi NakajimaY. Sato and H. Chiba and M. Nakamura and K. OhmoriTakayoshi Kobayashi and Akira Shirakawa and Takao FujiNiels H. Damrauer and Gustav GerberNoel P. Moore and Getahun M. Menkir and Alexei N. Markevitch and Paul Graham and Robert J. LevisA. D. Bandrauk and J. Levesque and S. ChelkowskiT. Tung Nguyen-Dang and H. Abou-Rachid and N. A. Nguyen and N. Mireault and O. AtabekKaoru YamanouchiHirohiko Kono and Shiro KosekiLong Cai and Bretislav FriedrichA. M. Lyyra and F. C. Spano and J. Qi and T. KirovaHirofumi Sakai and Jakob Juul Larsen and C. P. Safvan and Ida Wendt-Larsen and Henrik Stapelfeldt and Tsuneto KanaiD. Mathur and S. Banerjee and G. Ravindra Kumar
Prefacep. xi
Coherent Optimal Control
1. Controlling Molecular Motion: The Molecule Knows Bestp. 2
2. Variations on the Theme of Stimulated Raman Adiabatic Passage: Control of Chemical Reactionsp. 16
3. Laser Control of Selective Preparation of Preoriented Enantiomers from their Racematep. 32
4. Experimental and Theoretical Studies of the Channel Phase in the Coherent Control of Molecular Processesp. 47
5. Four-Wave Mixing and Coherent Controlp. 61
6. Control of Chemical Reactions by Using Chirped Laser Pulsesp. 81
7. Selective Excitation among Closely Lying Multilevelsp. 98
8. Laser Manipulation of Differential Autoionization Yields: Pump--Dump Control through Coupled Channelsp. 118
9. Optimal Quantum Control in Dissipative Environments: General Formalism and Perturbative Limitsp. 132
10. Manifestation fo Coherence on Laser Pulse Propagation: Propagation Dynamics of Phase-Controlled Lasersp. 144
11. Double-Pulse Manipulation of Vibrational Wavepackets in HgAr van der Waal Complexp. 155
12. Real-Time Spectroscopy of Molecular Vibration Using sub-5-fs Pulsesp. 171
Intense Fields
13. Quantum Control by Adaptive Femtosecond Pulse Shaping: Application to CH[subscript 2] BrCl in the Gas Phase and [Ru(dpb)[subscript 3 superscript 2+] in the Solution Phasep. 190
14. The Mechanisms of Strong-Field Control of Chemical Reactivity Using Tailored Laser Pulsesp. 207
15. Laser-Phase Control of Dissociative Ionization of Molecules: Exact Non-Born-Oppenheimer Simulations for H[subscript 2 superscript +]p. 221
16. Molecular Restructuring in Intense IR Laser Fieldsp. 236
17. Ultrafast Dynamics of Molecules in Intense Laser-Light Fields: New Research Directionsp. 251
18. Intense-Laser-Induced Electron Transfer and Structure Deformation of Moleculesp. 267
Alignment and Manipulation
19. Manipulating Molecules via Combined Electrostatic and Pulsed Nonresonant Laser Fieldsp. 286
20. Prospects for All-Optical Alignment and Quantum State Control of Nonpolar Moleculesp. 304
21. Alignment of Neutral Molecules by a Strong Nonresonant Linearly Polarized Laser Fieldp. 320
22. Propensity of Molecules to Spatially Align in Linearly Polarized, Intense Light Fieldsp. 336
Author Indexp. 351
Subject Indexp. 352