Cover image for Influence of the solvents on some radical reactions
Title:
Influence of the solvents on some radical reactions
Publication Information:
Hauppauge, N.Y. : Nova Science Publishers, c2009
Physical Description:
130 p. ; 23 cm.
ISBN:
9781608766352
General Note:
Includes index

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Material Type
Item Category 1
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30000010251857 QD544 I54 2009 Open Access Book Book
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Summary

Summary

This book is based on results of a series of experimental investigations it was proved that the nature of medium has an essential influence both on the rate and the chemical mechanism of homolutical reactions. This influence can be quantitatively connected with the physical-chemical characteristics of medium based on the principle of linearity of free energies with the use of multiparametric equations.


Table of Contents

Preface
Complications Existing at Consideration of Factors Influencing on Kinetics of Radical Reactions
The Medium Influence on Thermolysis of Diacyl -- & Dialkylperoxides
Decomposition of Peracids Esters
Decomposition of the Hydroperoxides & Reactions of the Phenoxy Radicals
Effects of the Solvents in the Oxidation Reactions
The Medium Influence on Some Others Homolytic Reactions
Conclusions
Appendix
Index