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Summary
Summary
This textbook introduces the physical concepts required for a comprehensive understanding of p-n junction devices, light emitting diodes and solar cells.
Semiconductor devices have made a major impact on the way we work and live. Today semiconductor
p-n junction diode devices are experiencing substantial growth: solar cells are used on an unprecedented scale in the renewable energy industry; and light emitting diodes (LEDs) are revolutionizing energy efficient lighting. These two emerging industries based on p-n junctions make a significant contribution to the reduction in fossil fuel consumption.
This book covers the two most important applications of semiconductor diodes - solar cells and LEDs - together with quantitative coverage of the physics of the p-n junction. The reader will gain a thorough understanding of p-n junctions as the text begins with semiconductor and junction device fundamentals and extends to the practical implementation of semiconductors in both photovoltaic and LED devices. Treatment of a range of important semiconductor materials and device structures is also presented in a readable manner.
Topics are divided into the following six chapters:
* Semiconductor Physics
* The PN Junction Diode
* Photon Emission and Absorption
* The Solar Cell
* Light Emitting Diodes
* Organic Semiconductors, OLEDs and Solar Cells
Containing student problems at the end of each chapter and worked example problems throughout, this textbook is intended for senior level undergraduate students doing courses in electrical engineering, physics and materials science. Researchers working on solar cells and LED devices, and those in the electronics industry would also benefit from the background information the book provides.
Author Notes
ADRIAN KITAI , Departments of Engineering Physics and Materials Science and Engineering, McMaster University, Hamilton, Ontario, Canada
Table of Contents
Introduction | p. xi |
Acknowledgements | p. xv |
1 Semiconductor Physics | p. 1 |
1.1 Introduction | p. 2 |
1.2 The Band Theory of Solids | p. 2 |
1.3 The Kronig-Penney Model | p. 3 |
1.4 The Bragg Model | p. 8 |
1.5 Effective Mass | p. 8 |
1.6 Number of States in a Band | p. 10 |
1.7 Band Filling | p. 12 |
1.8 Fermi Energy and Holes | p. 14 |
1.9 Carrier Concentration | p. 15 |
1.10 Semiconductor Materials | p. 25 |
1.11 Semiconductor Band Diagrams | p. 26 |
1.12 Direct Gap and Indirect Gap Semiconductors | p. 29 |
1.13 Extrinsic Semiconductors | p. 35 |
1.14 Carrier Transport in Semiconductors | p. 40 |
1.15 Equilibrium and Non-Equilibrium Dynamics | p. 43 |
1.16 Carrier Diffusion and the Einstein Relation | p. 45 |
1.17 Quasi-Fermi Energies | p. 48 |
1.18 The Diffusion Equation | p. 50 |
1.19 Traps and Carrier Lifetimes | p. 53 |
1.20 Alloy Semiconductors | p. 56 |
1.21 Summary | p. 59 |
Suggestions for Further Reading | p. 61 |
Problems | p. 63 61 Problems |
2 The PN Junction Diode | p. 69 |
2.1 Introduction | p. 70 |
2.2 Diode Current | p. 72 |
2.3 Contact Potential | p. 75 |
2.4 The Depletion Approximation | p. 78 |
2.5 The Diode Equation | p. 85 |
2.6 Reverse Breakdown and the Zener Diode | p. 97 |
2.7 Tunnel Diodes | p. 100 |
2.8 Generation/Recombination Currents | p. 101 |
2.9 Ohmic Contacts, Schottky Barriers and Schottky Diodes | p. 104 |
2.10 Heterojunctions | p. 113 |
2.11 Alternating Current (AC) and Transient Behaviour | p. 115 |
2.12 Summary | p. 117 |
Suggestions for Further Reading | p. 118 |
Problems | p. 119 |
3 Photon Emission and Absorption | p. 123 |
3.1 Introduction to Luminescence and Absorption | p. 124 |
3.2 Physics of Light Emission | p. 125 |
3.3 Simple Harmonic Radiator | p. 128 |
3.4 Quantum Description | p. 129 |
3.5 The Exciton | p. 132 |
3.6 Two-Electron Atoms | p. 135 |
3.7 Molecular Excitons | p. 141 |
3.8 Band-to-Band Transitions | p. 144 |
3.9 Photometric Units | p. 148 |
3.10 Summary | p. 152 |
Suggestions for Further Reading | p. 153 |
Problems | p. 155 |
4 The Solar Cell | p. 159 |
4.1 Introduction | p. 160 |
4.2 Light Absorption | p. 162 |
4.3 Solar Radiation | p. 164 |
4.4 Solar Cell Design and Analysis | p. 164 |
4.5 Thin Solar Cells | p. 172 |
4.6 Solar Cell Generation as a Function of Depth | p. 176 |
4.7 Solar Cell Efficiency | p. 179 |
4.8 Silicon Solar Cell Technology: Wafer Preparation | p. 184 |
4.9 Silicon Solar Cell Technology: Solar Cell Finishing | p. 187 |
4.10 Silicon Solar Cell Technology: Advanced Production Methods | p. 191 |
4.11 Thin Film Solar Cells: Amorphous Silicon | p. 192 |
4.12 Telluride/Selenide/Sulphide Thin-Film Solar Cells | p. 199 |
4.13 High-Efficiency Multijunction Solar Cells | p. 200 |
4.14 Concentrating Solar Systems | p. 203 |
4.15 Summary | p. 204 |
Suggestions for Further Reading | p. 205 |
Problems | p. 207 |
5 Light Emitting Diodes | p. 215 |
5.1 Introduction | p. 216 |
5.2 LED Operation and Device Structures | p. 217 |
5.3 Emission Spectrum | p. 220 |
5.4 Non-Radiative Recombination | p. 221 |
5.5 Optical Outcoupling | p. 223 |
5.6 GaAs LEDs | p. 225 |
5.7 GaAsi P LEDs | p. 226 |
5.8 Double Heterojunction AIxGa1-xAs LEDs | p. 228 |
5.9 AlGalnPLEDs | p. 234 |
5.10 Ga1-x InxTNLEDs | p. 236 |
5.11 LED Structures for Enhanced Outcoupling and Power Output | p. 244 |
5.12 Summary | p. 247 |
Suggestions for Further Reading | p. 248 |
Problems | p. 249 |
6 Organic Semiconductors, OLEDs and Solar Cells | p. 253 |
6.1 Introduction to Organic Electronics | p. 254 |
6.2 Conjugated Systems | p. 255 |
6.3 Polymer OLEDs | p. 260 |
6.4 Small-Molecule OLEDs | p. 266 |
6.5 Anode Materials | p. 270 |
6.6 Cathode Materials | p. 270 |
6.7 Hole Injection Layer | p. 271 |
6.8 Electron Injection Layer | p. 272 |
6.9 Hole Transport Layer' | p. 272 |
6.10 Electron Transport Layer | p. 275 |
6.11 Light Emitting Material Processes | p. 276 |
6.12 Host Materials | p. 278 |
6.13 Fluorescent Dopants | p. 279 |
6.14 Phosphorescent Dopants | p. 283 |
6.15 Organic Solar Cells | p. 283 |
6.16 Organic Solar Cell Materials | p. 289 |
6.17 Summary | p. 292 |
Suggestions for Further Reading | p. 294 |
Problems | p. 296 |
Appendix 1 Physical Constants | p. 303 |
Appendix 2 Properties of Semiconductor Materials | p. 305 |
Appendix 3 The Boltzmann Distribution Function | p. 307 |
Index | p. 311 |