Cover image for Principles of solar cells, LEDs, and diodes : the role of the PN junction
Title:
Principles of solar cells, LEDs, and diodes : the role of the PN junction
Personal Author:
Publication Information:
Chichester, West Sussex, U.K. : Wiley, 2011
Physical Description:
xiii, 318 p. : ill. ; 24 cm.
ISBN:
9781444318333
Abstract:
"The book will cover the two most important applications of semiconductor diodes - solar cells and LEDs - together with quantitative coverage of the physics of the PN junction at the senior undergraduate level. It will include: Review of semiconductor physics Introduction to PN diodesThe solar cell Physics of efficient conversion of sunlight into electrical energy Semiconductor solar cell materials and device physics Advanced solar cell materials and devices The light emitting diode Physics of efficient conversion of electrical energy into light Semiconductor light emitting diode materials and device physics Advanced light emitting diode materials and devices"-- Provided by publisher.

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30000010280709 TK7871.86 K58 2011 Open Access Book Book
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Summary

Summary

This textbook introduces the physical concepts required for a comprehensive understanding of p-n junction devices, light emitting diodes and solar cells.

Semiconductor devices have made a major impact on the way we work and live. Today semiconductor
p-n junction diode devices are experiencing substantial growth: solar cells are used on an unprecedented scale in the renewable energy industry; and light emitting diodes (LEDs) are revolutionizing energy efficient lighting. These two emerging industries based on p-n junctions make a significant contribution to the reduction in fossil fuel consumption.

This book covers the two most important applications of semiconductor diodes - solar cells and LEDs - together with quantitative coverage of the physics of the p-n junction. The reader will gain a thorough understanding of p-n junctions as the text begins with semiconductor and junction device fundamentals and extends to the practical implementation of semiconductors in both photovoltaic and LED devices. Treatment of a range of important semiconductor materials and device structures is also presented in a readable manner.

Topics are divided into the following six chapters:

* Semiconductor Physics
* The PN Junction Diode
* Photon Emission and Absorption
* The Solar Cell
* Light Emitting Diodes
* Organic Semiconductors, OLEDs and Solar Cells

Containing student problems at the end of each chapter and worked example problems throughout, this textbook is intended for senior level undergraduate students doing courses in electrical engineering, physics and materials science. Researchers working on solar cells and LED devices, and those in the electronics industry would also benefit from the background information the book provides.


Author Notes

ADRIAN KITAI , Departments of Engineering Physics and Materials Science and Engineering, McMaster University, Hamilton, Ontario, Canada


Table of Contents

Introductionp. xi
Acknowledgementsp. xv
1 Semiconductor Physicsp. 1
1.1 Introductionp. 2
1.2 The Band Theory of Solidsp. 2
1.3 The Kronig-Penney Modelp. 3
1.4 The Bragg Modelp. 8
1.5 Effective Massp. 8
1.6 Number of States in a Bandp. 10
1.7 Band Fillingp. 12
1.8 Fermi Energy and Holesp. 14
1.9 Carrier Concentrationp. 15
1.10 Semiconductor Materialsp. 25
1.11 Semiconductor Band Diagramsp. 26
1.12 Direct Gap and Indirect Gap Semiconductorsp. 29
1.13 Extrinsic Semiconductorsp. 35
1.14 Carrier Transport in Semiconductorsp. 40
1.15 Equilibrium and Non-Equilibrium Dynamicsp. 43
1.16 Carrier Diffusion and the Einstein Relationp. 45
1.17 Quasi-Fermi Energiesp. 48
1.18 The Diffusion Equationp. 50
1.19 Traps and Carrier Lifetimesp. 53
1.20 Alloy Semiconductorsp. 56
1.21 Summaryp. 59
Suggestions for Further Readingp. 61
Problemsp. 63 61 Problems
2 The PN Junction Diodep. 69
2.1 Introductionp. 70
2.2 Diode Currentp. 72
2.3 Contact Potentialp. 75
2.4 The Depletion Approximationp. 78
2.5 The Diode Equationp. 85
2.6 Reverse Breakdown and the Zener Diodep. 97
2.7 Tunnel Diodesp. 100
2.8 Generation/Recombination Currentsp. 101
2.9 Ohmic Contacts, Schottky Barriers and Schottky Diodesp. 104
2.10 Heterojunctionsp. 113
2.11 Alternating Current (AC) and Transient Behaviourp. 115
2.12 Summaryp. 117
Suggestions for Further Readingp. 118
Problemsp. 119
3 Photon Emission and Absorptionp. 123
3.1 Introduction to Luminescence and Absorptionp. 124
3.2 Physics of Light Emissionp. 125
3.3 Simple Harmonic Radiatorp. 128
3.4 Quantum Descriptionp. 129
3.5 The Excitonp. 132
3.6 Two-Electron Atomsp. 135
3.7 Molecular Excitonsp. 141
3.8 Band-to-Band Transitionsp. 144
3.9 Photometric Unitsp. 148
3.10 Summaryp. 152
Suggestions for Further Readingp. 153
Problemsp. 155
4 The Solar Cellp. 159
4.1 Introductionp. 160
4.2 Light Absorptionp. 162
4.3 Solar Radiationp. 164
4.4 Solar Cell Design and Analysisp. 164
4.5 Thin Solar Cellsp. 172
4.6 Solar Cell Generation as a Function of Depthp. 176
4.7 Solar Cell Efficiencyp. 179
4.8 Silicon Solar Cell Technology: Wafer Preparationp. 184
4.9 Silicon Solar Cell Technology: Solar Cell Finishingp. 187
4.10 Silicon Solar Cell Technology: Advanced Production Methodsp. 191
4.11 Thin Film Solar Cells: Amorphous Siliconp. 192
4.12 Telluride/Selenide/Sulphide Thin-Film Solar Cellsp. 199
4.13 High-Efficiency Multijunction Solar Cellsp. 200
4.14 Concentrating Solar Systemsp. 203
4.15 Summaryp. 204
Suggestions for Further Readingp. 205
Problemsp. 207
5 Light Emitting Diodesp. 215
5.1 Introductionp. 216
5.2 LED Operation and Device Structuresp. 217
5.3 Emission Spectrump. 220
5.4 Non-Radiative Recombinationp. 221
5.5 Optical Outcouplingp. 223
5.6 GaAs LEDsp. 225
5.7 GaAsi P LEDsp. 226
5.8 Double Heterojunction AIxGa1-xAs LEDsp. 228
5.9 AlGalnPLEDsp. 234
5.10 Ga1-x InxTNLEDsp. 236
5.11 LED Structures for Enhanced Outcoupling and Power Outputp. 244
5.12 Summaryp. 247
Suggestions for Further Readingp. 248
Problemsp. 249
6 Organic Semiconductors, OLEDs and Solar Cellsp. 253
6.1 Introduction to Organic Electronicsp. 254
6.2 Conjugated Systemsp. 255
6.3 Polymer OLEDsp. 260
6.4 Small-Molecule OLEDsp. 266
6.5 Anode Materialsp. 270
6.6 Cathode Materialsp. 270
6.7 Hole Injection Layerp. 271
6.8 Electron Injection Layerp. 272
6.9 Hole Transport Layer'p. 272
6.10 Electron Transport Layerp. 275
6.11 Light Emitting Material Processesp. 276
6.12 Host Materialsp. 278
6.13 Fluorescent Dopantsp. 279
6.14 Phosphorescent Dopantsp. 283
6.15 Organic Solar Cellsp. 283
6.16 Organic Solar Cell Materialsp. 289
6.17 Summaryp. 292
Suggestions for Further Readingp. 294
Problemsp. 296
Appendix 1 Physical Constantsp. 303
Appendix 2 Properties of Semiconductor Materialsp. 305
Appendix 3 The Boltzmann Distribution Functionp. 307
Indexp. 311