Cover image for Macromolecular nanostructured materials
Title:
Macromolecular nanostructured materials
Series:
Springer series in materials science, 78
Publication Information:
Tokyo : Springer, 2004
Physical Description:
xvi, 335 p. : ill. ; 24 cm.
ISBN:
9783540223276

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30000010164599 TA418.9.N35 M32 2004 Open Access Book Book
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Summary

Summary

This volume contains information on the most recent advances in the rapid development of nanostructured materials. The authors are world leaders in this area and a group of young scientists who have devoted themselves to the develop ment of macromolecular nanostructured materials. The first development phase of this field was characterized by the construction of nanostructured materials. We have now entered the second phase, the aim of which has been the creation of a functional device for various applications. Polymeric materials have already estab lished a nanosized structure for these infinitesimal purposes. However, these poly mers are used via a top-down processing approach from the mass. The goal of cre ating new nanostructured materials is to produce instead a device which can be self-assembled and used in a bottom-up processing approach. Although the top down processing approach has given rise to the problem of how to dispose of scraps generated by industrial and daily usage, the bottom-up processing approach will involve a specific reaction after usage, thereby eliminating this disposal prob lem. The collected articles present important concepts for the precise synthesis of nanostructured materials. These small molecules are designed according to the molecular recognition results for their functions, such as molecular electronics, mesoscopic assemblies using organic building blocks or polymers with well defined shape, size and a deeply buried functional group, and novel magnets con sisting of organic radicals, sol-gel hybrids applicable for hardeners of fluids or liq uid crystals."


Table of Contents

An Integrated Systems-oriented Approach to Molecular Electronics
Supramolecular Polymers Containing Cyclodextrin
Cucurbituril: A Versatile "Bead" for Polyrotaxane Synthesis
Nanometer-size Multispin Macromolecules and Their Magnetic Force Microscopic Images
Synthesis and Characterization of New Highly Soluble Organic Polyimides
"Inorganic" Combinatorial Chemistry Utilizing Sol-Gel Transcription of Gelatinous Organic Superstructures
Development of Organogelators Based on Supramolecular Chemistry
Synthesis and Self-Association of Stimuli-responsive Block Copolymers by Living Cationic Polymerization
Spherical, Fibrous Rock- and Sheet-like Noncovalent Polymers
Macromolecular Conjugated Complexes
Polymer-capped Bimetallic Nanoclusters as Active and Selective Catalysts
Organic-Inorganic Hybrid Materials Based on Silsesquioxanes
Protonation-induced Intramolecular Electron Transfer in the Ferrocene-Quinone Conjugated System
Oligomers of Non-natural Metal Complex Amino Acids
Macromolecular Metal Complexes in Biological Systems
Direct Observation of Supramolecular Structures of Biorelated Materials by Atomic Force Microscopy
Analysis of the Nanostructure of Calcium Carbonate Composite in Biominerals of Pinctada Fucata
A Novel Triple Helix Consisting of One Polynucleotide and Two Polysaccharide Chains
Physicochemical Properties of Spider Silk: An Approach to Nanostructure