Cover image for Materials for conservation : organic consolidants, adhesives and coatings
Title:
Materials for conservation : organic consolidants, adhesives and coatings
Edition:
2nd ed.
Publication Information:
Amsterdam ; Boston : Butterworth-Heinemann, 2010
Physical Description:
xiv, 489 p. : ill. ; 23 cm.
ISBN:
9780750669054

9781138128101
General Note:
Original ed. published in 1986
Abstract:
"The first section explains the physical and chemical properties which are important in the conservation process, i.e. application, aging, reversal. The topics covered include molecular weight, glass transition temperature, solubility and solvents, polymerisation and degradation reactions, adhesion, and uses. The second section provides detailed consideration of the individual materials, current and obsolete, used in conservation, drawing out the factors relevant to their effects on objects. The conservation uses of each material are summarised and referenced to allow further study"--P. [4] of cover

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30000010281138 TP156.C57 H67 2010 Open Access Book Book
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Summary

Summary

Materials in Conservation is the definitive introduction to the properties of materials used in conservation. The continual struggle of conservators to ameliorate the deterioration of objects has led to increasing use of synthetic polymers. These materials are part of the sophisticated technology that has been developed to augment and often replace traditional materials and methods. Conservators therefore have a wider range of techniques available. However, they must be able to appreciate the potentials and pitfalls of any proposed technique.

The first section explains physical and chemical properties which are important in the conservation process, i.e. application, ageing, reversal. The topics covered include molecular weight, glass transition temperature, solubility and solvents, polymerisation and degradation reactions. The second section provides a detailed consideration of the individual materials, current and obsolete, used in conservation, drawing out the factors relevant to their effects on objects. The conservation uses of each material are summarised and referenced to allow further study. In five appendices, the properties of the polymers, solvents and their interactions are tabulated, with a list of suppliers and conversion table of physical units. IUPAC and SI nomenclature is used throughout the book.

In this second edition, this classic text is revised and updated to include modern materials such as cyclododecane, and current ideas on adhesion, consolidation and reversibility, making Materials in Conservation the definitive source of vital information in the field.

This handy reference book should be on the bench of every conservator and available wherever objects, from steam engines to dried plants, are preserved.


Author Notes

Velson Horie is a Collection Care and Conservation Consultant. For 28 years he was Keeper of Conservation at The Manchester Museum, The University of Manchester, then was the Research Project Manager at the British Library coordinating an international and interdisciplinary study on the natural ageing of books. Teaching experience includes university lectures, a distance learning course on Chemistry for Conservators and professional updating courses on polymers. He has published extensively on conservation.

www.horie.co.uk nbsp;


Table of Contents

Prefacep. ix
Acknowledgementsp. xii
Disclaimerp. xiii
About the Authorp. xiv
Part I Background Information
1 Introduction
1.1 Use of Resins in Conservationp. 3
1.2 Setting Processesp. 4
1.3 Reversibilityp. 5
1.4 Historyp. 8
1.5 Information Sourcesp. 9
Referencesp. 11
2 Polymer Science
2.1 Film-Forming Materialsp. 15
2.2 Molecular Weight and Sizep. 19
2.3 Glass Transition Temperaturep. 22
2.4 Mechanical Propertiesp. 27
2.5 Optical Propertiesp. 32
2.6 Polymerizationp. 33
2.7 Deterioration of Polymersp. 37
2.8 Testing of Polymersp. 44
2.9 Identification of Polymersp. 58
Referencesp. 59
3 Solvents
3.1 Chemical Type and Purityp. 67
3.2 Solubility Parametersp. 69
3.3 Evaporation Ratep. 75
3.4 Hazardsp. 76
3.5 Solvent-Solute Interactionp. 81
Referencesp. 92
4 Adhesion
4.1 Introductionp. 97
4.2 Wetting the Surfacep. 97
4.3 Effects of Setting Properties on Adhesionp. 100
4.4 Strength of Adhesion Bondsp. 101
4.5 Failure of Jointsp. 103
Referencesp. 104
5 Uses and Requirements of Applied Polymers - A Summary
5.1 Stabilityp. 105
5.2 Reversibilityp. 105
5.3 Glass Transition Temperaturep. 105
5.4 Settingp. 105
5.5 Strengthp. 106
5.6 Applicationp. 106
5.7 Consolidationp. 106
5.8 Adhesionp. 111
5.9 Coatingsp. 117
5.10 Mouldingp. 118
5.11 Specifying a Product for Conservationp. 118
Referencesp. 121
Part II Survey of Polymers
6 Hydrocarbons
6.1 Polyethene (PE) and Paraffin Waxp. 125
6.2 Rubberp. 130
Referencesp. 132
7 Vinyl Acetate-Derived Polymers
7.1 Poly(Vinyl Acetate) (PVAC)p. 137
7.2 Poly(Vinyl Alcohol) (PVAL)p. 142
7.3 Poly(Vinyl Acetals)p. 145
Referencesp. 148
8 Acrylic Polymers
8.1 Backgroundp. 153
8.2 Conservationp. 159
Referencesp. 172
9 Miscellaneous Synthetic Thermoplastics
9.1 Poly(Vinyl Chloride) (PVC)p. 179
9.2 Poly(Vinylidene Chloride) (PVDC)p. 181
9.3 Polystyrene (PS)p. 181
9.4 Poly(Vinyl Pyrrolidone) (PVP)p. 182
9.5 Poly(p-Xylylene) (PPX)p. 182
9.6 Low-Molecular-Weight Resinsp. 183
9.7 Polyethersp. 188
9.8 Nylonsp. 194
9.9 Poly(2-Ethyl-2-Oxazoline)p. 196
Referencesp. 196
10 Polymers Derived from Cellulose
10.1 Cellulose Ethersp. 206
10.2 Cellulose Estersp. 212
Referencesp. 216
11 Natural Water-Soluble Polymers
11.1 Polysaccharidesp. 221
11.2 Proteinsp. 228
Referencesp. 235
12 Natural Resins
12.1 Terpenesp. 241
12.2 Monoterpenoidsp. 241
12.3 Diterpenoidsp. 248
12.4 Triterpenoidsp. 253
12.5 Shellacp. 258
12.6 Beeswaxp. 260
12.7 Carnauba Waxp. 261
12.8 Oils and Alkydsp. 261
Referencesp. 266
13 Cross-Linking Polymers
13.1 Silicon-Containing Polymersp. 271
13.2 Polyester Resinsp. 283
13.3 Polyurethane Polymersp. 286
13.4 Epoxy Resinsp. 289
13.5 Formaldehyde Resinsp. 297
Referencesp. 301
14 Fillers and Colourants
14.1 Fillersp. 307
14.2 Colourantsp. 307
Referencesp. 309
Appendices
Appendix 1 Polymer Propertiesp. 311
Appendix 2.1 Solvent Propertiesp. 323
Appendix 2.2 Hydrocarbon Solventsp. 369
Appendix 2.3 Hazards and Warnings (European Union Labelling)p. 373
Appendix 2.4 Hazards and Warnings (Globally Harmonized System Labelling)p. 377
Appendix 3 Polymer Solubility Chartsp. 379
Appendix 4 Glossaryp. 423
Author Indexp. 439
Term Indexp. 453