Cover image for Avoiding static ignition hazards in chemical operations
Title:
Avoiding static ignition hazards in chemical operations
Personal Author:
Series:
A CCPS concept book
Publication Information:
New York : Center for Chemical Process Safety of the American Institute of Chemical Engineers, c1999
Physical Description:
xvi, 282 p. : ill. ; 24 cm.
ISBN:
9780816908004

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Material Type
Item Category 1
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30000010262139 TP155.5 B75 1999 Open Access Book Book
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Summary

Summary

Written by Laurence Britton, who has over 20 years' experience in the fields of static ignition and process fire and explosion hazards research, this resource addresses an area not extensively covered in process safety standards or literature: understanding and reducing potential hazards associated with static electricity. The book covers the nature of static electricity, characteristics and effective energies of different static resources, techniques for evaluating static electricity hazards, general bonding, grounding, and other techniques used to control static or prevent ignition, gases and liquids, powders and hybrid mixtures.


Author Notes

Laurence G. Britton is the author of Avoiding Static Ignition Hazards in Chemical Operations: A CCPS Concept Book, published by Wiley.


Table of Contents

Preface
Acknowledgments
Chapter 1 Introduction
1.1 Purpose
1.2 Exclusive
1.3 Units
1.4 Organization of the Book
Chapter 2 Fundamentals of Static Electricity
2.1 What is Static Electricity
2.1.1 Charge Separation
2.1.2 Magnitude of Current and Potential
2.1.3 Concentration of Charged Species
2.1.4 Importance of Trace Contaminants
2.1.5 Hazard Evaluation
2.1.6 Statistics
2.2 Charge Generation
2.2.1 Induction Charging
2.2.2 Ionic Charging
2.3 Charge Dissipation
2.3.1 Variability of Conductivity
2.4 Charge Accumulation
2.5 Ignition
2.5.1 Effective Energy
2.6 Static Discharges
2.6.1 Corona Discharge
2.6.2 Brush Discharge
2.6.3 Bulking Brush Discharge
2.6.4 Spark Discharge
2.6.5 Propagating Brush Discharge (PBD)
2.6.6 Surface Streamer
2.7 Personnel Spark and Shock Hazards
2.7.1 Body Capacitance and Resistance
2.7.2 Voltage (V) and Energy (W) Attained
2.7.3 Human Shock Response
Chapter 3 Evaluating the Hazard of Static Electricity
3.1 General
3.2 Hazard Identification Methods
3.2.1 Decision Trees
3.3 Charge Accumulation
3.3.1 Conductive Objects
3.3.2 Nonconductive Objects
3.4 Energy Estimates
3.4.1 Charge Sharing
3.5 Instrumentation
3.5.1 Charge
3.5.2 Electric Field
3.5.3 Potential
3.5.4 Ignition Energy
3.5.5 Conductivity of Liquids
3.5.6 Resistivity of Solids
3.5.7 Resistance
3.6 Direct Observation of Discharges
3.7 Radio Frequency Detection of Discharges
3.8 Measuring the Effective Energy of Nonspark Discharges
3.8.1 Gas Composition
Chapter 4 Controlling Electrostatic Hazards
4.1 Bonding and Grounding
4.1.1 Definitions
4.1.2 Purpose of Bonding and Grounding
4.1.3 Resistance to Ground
4.1.4 Bonding and Grounding Systems
4.1.5 Ground Rods
4.1.6 Grounding and Cathodic Protection
4.2 Control of Charge Relaxation
4.2.1 Increase of Conductivity
4.2.2 Charge Neutralizers
4.3 Control of Personnel Charging
4.3.1 Personnel Grounding
4.3.2 Clothing
4.3.3 Gloves
4.4 Control of Flammable Atmospheres
4.4.1 Liquid Nitrogen/Liquid Air Hazards
Chapter 5 Flammable Liquids, Vapors, and Gases
5.1 Ignition Hazards of Liquid Vapor and Mist
5.1.1 Flammable Liquid
5.1.2 Flammable Limits
5.1.3 Liquid Mist
5.1.4 Minimum Ignition Energy (MIE)
5.1.5 Explosion Prevention Systems
5.2 Generation and Relaxation (Loss) of Charge in Liquid Systems
5.2.1 Charge Generation
5.2.2 Charge Density
5.2.3 Factors Influencing Charge Generation
5.2.4 Charge Relaxation
5.2.5 Classification of Liquids based on Conductivity
5.2.6 Antistatic Additives
5.2.7 Bonding and Grounding
5.3 Flow in Pipe, Hose, and Tubing
5.3.1 Metallic Piping Systems
5.3.2 Nonconductive Pipe and Linings
5.3.3 Flexible Hoses
5.3.4 Dip Pipes
5.3.5 Filters and Relaxation Tanks
5.3.6 Suspended Material
5.3.7 Valves and Other Line Restrictions
5.4 Filling Criteria for Tank Operations
5.4.1 Storage Tanks
5.4.2 Road Tankers
5.4.3 Rail Cars
5.4.4 Liquid Phase Mixers, Blenders, and Reactors
5.4.5 Liquid-Solid Mixers, Blenders and Reactors
5.4.6 Vacuum Trucks
5.4.7 Plastic Tanks
5.5 Sampling, Gauging, and Analysis
5.5.1 Sample Container Cord
5.5.2 Sampling
5.5.3 Gauging
5.5.4 Portable Flammable Gas Analyzers
5.6 Tank Cleaning
5.6.1 Water Washing
5.6.2 Solvent Washing
5.6.3 Steam Cleaning
5.6.4 Acid Washing
5.6.5 Grit Blasting
5.7 Portable Tanks
5.7.1 Metal Portable Tanks
5.7.2 Plastic Portable Tanks
5.8 Portable Containers Le