Cover image for Materials for electrochemical energy storage and conversion II--batteries, capacitors, and fuel cells : symposium held December 1-5, 1997, Boston, Massachusetts, U.S.A.
Title:
Materials for electrochemical energy storage and conversion II--batteries, capacitors, and fuel cells : symposium held December 1-5, 1997, Boston, Massachusetts, U.S.A.
Series:
Materials Research Society symposium proceedings ; v. 496

Materials Research Society symposia proceedings ; v. 496
Publication Information:
New York : Cambridge Univ Pr., 1998
Physical Description:
xvii, 682 p. : ill. ; 24 cm.
ISBN:
9781558994010

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30000010323194 TK2896 M38 1998 Open Access Book Book
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Summary

Summary

Our energy-hungry world increasingly relies on new methods to store and convert energy for portable electronics, as well as environmentally friendly modes of transportation and electrical energy generation. The development of high-performance power sources are intimately linked to the availability of advanced materials. Designing batteries and capacitors with higher specific energy and power, longer cycle life and rapid charge/discharge rates requires a deeper understanding of the relationship between materials properties and performance. Fuel cells, which offer the potential for clean, efficient conversion of chemical energy to electrical energy, are hampered by high cost and performance problems which can be resolved by new materials and processing techniques. Advanced batteries such as lithium-ion and nickel-metal hydride offer the potential for improved performance if low-cost materials can be developed. This book shares research and highlights the importance of materials in energy conversion technologies. Topics include: rechargeable batteries; lithium-ion rechargeable batteries - modelling; fuel cells; lithium-ion rechargeable batteries - cathode materials; battery electrolytes, interfaces and passive films; lithium-ion rechargeable batteries - anode materials and supercapacitors.


Table of Contents

A.J. SalkindShizukuni Yata and Kazuyoshi Tanaka and Tokio YamabeD. Singh and T. Wu and M. Wendling and P. Bendale and J. Ware and D. Ritter and L. ZhangI.E. Anderson and V.K. Pecharsky and J. Ting and C. Witham and R.C. BowmanM. Neal Golovin and Irena Kuznetsov and Iyi Atijosan and Lawrence A. Tinker and Christopher S. PediciniS.B. BinerValentin N. Mitkin and Peter S. Galkin and Tatjana N. Denisova and Ol'ga V. Koreneva and Sergey V. Filatov and Eugene A. Shinelev and Alexander B. Alexandrov and Vladimir L. Afanasiev and Alexander A. Enin and Viktor V. Moukhin and Vladimir V. Rozhkov and Vladlen V. TelezhkinM.K. Aydinol and A. Van der Ven and G. CederC. Wolverton and Alex ZungerMarko Radosavljevic and Peter Papanek and John E. FischerG. Sandi and R. E. Gerald, II and L. G. Scanlon and K.A. Carrado and R.E. WinansJ.W. Halley and B. NielsenRandall T. Cygan and Henry R. Westrich and Daniel H. DoughtyR. Benedek and M.M. Thackeray and L.H. YangAnton Van der Ven and Mehmet K. Aydinol and Gerbrand CederN.J. Long and H.L. TullerD. Wheeler and F. Luczak and R. Fredley and N. CipolliniM. Greenblatt and W. Huang and P. ShukAlan F. Jankowski and Jeffrey D. MorseM.T. Nemeth and R.B. Ford and T.A. TaylorB. Ma and U. Balachandran and J.P. Hodges and J.D. Jorgensen and D.J. Miller and J.W. Richardson, JrJ.P. Hodges and J.D. Jorgensen and D.J. Miller and B. Ma and U. Balachandran and J.W. Richardson, JrCh. Gerk and M. Willert-PoradaReiichi Chiba and Fumikatsu Yoshimura and Junichi YamakiMasami Kanzaki and Akihiko Yamaji and Kazuya KawakamiC. Karmonik and T. Yildirim and T.J. Udovic and J.J. Rush and R. HempelmannY-T. Yamazaki and T. Namikawa and T. Ide and N. Oishi and O. SuzukiC. Shoji and T. Matsuo and A. Suzuki and Y. YamamasuM. Bhamidipati and E. Lazaro and F. Lyons and R.S. MorrisY. Wu and T.A. Zawodzinski and M.C. Smart and S.G. Greenbaum and G.K.S. Prakash and G.A. OlahKen-ichiro Ota and Katsuya Toda and Naobumi Motohira and Nobuyuki KamiyaA. Deptula and W. Lada and T. Olczak and B. Sartowska and A. Ciancia and L. Giorgi and A. Di BartolomeoT.M. Besmann and J.W. Klett and T.D. BurchellS. Kim and Y.L. Yang and R. Christoffersen and A.J. JacobsonToshimi Takada and Hirotoshi Enoki and Etsuo Akiba and Takenori Ishizu and Tatsuo HoribaN. Ravet and C. Michot and M. ArmandMark A. Rodriguez and David Ingersoll and Daniel H. DoughtyJunji Tabuchi and Tatsuji Numata and Yuichi Shimakawa and Masato ShirakataD.S. Ginley and J.D. Perkins and J.M. McGraw and P.A. Parilla and M.L. Fu and C.T. RogersH.S. Choe and K.M. AbrahamKatsuhiko Naoi and Ken-ichi Kawase and Mitsuhiro Mori and Michiko KomiyamaYair Ein-Eli and W.F. Howard, Jr. and Sharon H. Lu and Sanjeev Mukerjee and James McBreen and John T. Vaughey and Michael M. ThackerayH. Tsutsumi and S. Okada and K. Toda and K. Onimura and T. OishiJ.D. Perkins and M.L. Fu and D.M. Trickett and J.M. McGraw and T.F. Ciszek and P.A. Parilla and C.T. Rogers and D.S. GinleyT. Esaka and S. Takai and M. KamataK. Zhang and Y.L. Yang and A.J. Jacobson and K. SalamaA. Deptula and W. Lada and T. Olczak and F. Croce and F. Ronci and A. Ciancia and L. Giorgi and A. Brignocchi and A. Di BartolomeoF. Coustier and S. Passerini and J. Hill and W.H. SmyrlD. Peramunage and K.M. AbrahamFan Zhang and Peter Y. Zavalij and M. Stanley WhittinghamJ.M. McGraw and J.D. Perkins and J-G. Zhang and P.A. Parilla and T.F. Ciszek and M.L. Fu and D.M. Trickett and J.A. Turner and D.S. GinleyJi-Guang Zhang and Ping Liu and C. Edwin Tracy and David K. Benson and John A. TurnerM.J. Duncan and F. Leroux and L.F. NazarJ. Kawakita and Y. Katayama and T. Miura and T. KishiG.M. Ehrlich and R.L. GitzendannerY-I. Jang and B. Huang and H. Wang and Y-M. Chiang and D.R. SadowayT.D. Xiao and D.E. Reisner and P.R. StruttC. Julien and M. Massot and C. Perez-Vicente and E. Haro-Poniatowski and G.A. Nazri and A. RougierA. Manthiram and J. Kim and C. TsangS. Kostov and Y. Wang and M.L. denBoer and S. Greenbaum and C.C. Chang and Prashant N. KumtaD. Aurbach and M.D. Levi|cE. Levi and B. Markovsky and G. Salitra and H. Teller and U. Heider and L. HeiderM.N. Richard and J.R. DahnT. Sato and M. Deschamps and H. Suzuki and H. Ota and H. Asahina and S. MoriT. Fujieda and S. Koike and S. HiguchiRonald A. Guidotti and Gerald C. NelsonY.S. Sasaki and N. Yamazaki and M. HandaPaul Calvert and Zack Gardlund and Trey Huntoon and H.K. Hall and Anne PadiasM. Inaba and S. Nohmi and A. Funabiki and T. Abe and Z. OgumiT.A. Kerr and F. Leroux and L.F. NazarR.E. Dillon and D.F. ShriverG.B. Appetecchi and F. Croce and G. Dautzenberg and B. ScrosatiC-K. Huang and J.S. Sakamoto and M.C. Smart and S. Surampudi and J. WolfenstineM.J. Matthews and N. Kobayashi and M.S. Dresselhaus and M. Endo and T. Enoki and T. KarakiKevin R. Zavadil and Ronald A. Guidotti and William R. EvenS. Wang and H. Matsui and Y. Matsumura and T. YamabeY. Saito and K. Takano and K. Kanari and K. NozakiT. Takamura and K. Sumiya and Y. Nishijima and J. Suzuki and K. SekineA. Claye and P. Zhou and J.E. Fischer and F. Disma and J-M. TarasconToshio Tamaki and Toshifumi Kawamura and Yoshinori YamazakiDavid J. Derwin and Kim Kinoshita and Tri D. Tran and Peter ZaleskiT. Nakajima and M. Koh and K. DanD. Aurbach and A. Schechter and B. Markovsky and Y. Cohen and I. Weissman and M. MoshkovichF. Leroux and L.F. NazarT.D. Tran and D. Lenz and K. Kinoshita and M. DroegeJ. Flynn and C. MarshWilliam R. Even and Lawrence W. Peng and Nancy Yang and Ronald Guidotti and Thomas HeadleyT. Morimoto and M. Tsushima and M. Suhara and K. Hiratsuka and Y. Sanada and T. KawasatoP.M. Wilde and T.J. Guther and R. Oesten and J. GarcheM.R. Wixom and D.J. Tarnowski and J.M. Parker and J.Q. Lee and P-L. Chen and I. Song and L.T. ThompsonMasashi Ishikawa and Atsushi Sakamoto and Masayuki Morita and Yoshiharu Matsuda and Koichi IshidaR.B. Wright and T.C. Murphy and Susan A. Rogers and Raymond A. SutulaS.L. Roberson and D. Evans and D. Finello and R.F. Davis
Prefacep. xv
Acknowledgmentsp. xvii
Materials Research Society Symposium Proceedingsp. xviii
Part I General Section: Rechargeable Batteries
Advances in Battery Technologies and Markets - Materials Science Aspectsp. 3
Polyacene (PAS) Batteriesp. 15
Mechanisms Causing Capacity Loss on Long-Term Storage in NiMH Systemp. 25
Benefits of Rapid Solidification Processing of Modified LaNi[subscript 5] Alloys by High-Pressure Gas Atomization for Battery Applicationsp. 37
Influence of Carbon Structure and Physical Properties on the Corrosion Behavior in Carbon-Based Air Electrodes for Zinc Air Batteriesp. 43
Variation of Stresses Ahead of the Internal Cracks in ReNi[subscript 5] Powders During Hydrogen Charging and Discharging Cyclesp. 51
The Corrosion Phenomena in the Coin Cell BR2325 of the "Superstoichiometric Fluorocarbon-Lithium" Systemp. 57
Part II Lithium Ion Rechargeable Batteries - Modeling
Application of Ab Initio Methods to Secondary Lithium Batteriesp. 65
First-Principles Theory of Cation and Intercalation Ordering in Li[subscript x]CoO[subscript 2]p. 77
Reactions of Lithium With Small Graphene Fragments: Semiempirical Quantum-Chemical Calculationsp. 89
Computational, Electrochemical, and [superscript 7]Li NMR Studies of Lithiated Disordered Carbons Electrodes in Lithium lon Cellsp. 95
Simulation Studies of Polymer Electrolytes for Battery Applicationsp. 101
Molecular-Dynamics Study of Lithium Diffusion in Lithium-Manganese Spinel Cathode Materialsp. 109
Structure and Electrochemical Potential Simulation for the Cathode Material Li[subscript 1+x]V[subscript 3]O[subscript 8]p. 115
Ab Initio Calculation of the Li[subscript x]CoO[subscript 2] Phase Diagramp. 121
Part III Fuel Cells
Mixed lonic-Electronic Conduction in Ni-Doped Lanthanum Gallate Perovskitesp. 129
Carbon and Fluorinated Carbon Materials for Fuel Cellsp. 139
Hydrothermal Synthesis and Properties of Ceria Solid Electrolytesp. 149
Thin-Film Synthesis of Novel Electrode Materials for Solid-Oxide Fuel Cellsp. 155
Analysis of Mixtures of Gamma Lithium Aluminate, Lithium Aluminum Carbonate Hydroxide Hydrate, and Lithium Carbonatep. 159
Phase Stability of the Mixed-Conducting Sr-Fe-Co-O Systemp. 167
Crystal Structures of Mixed-Conducting Oxides Present in the Sr-Fe-Co-O Systemp. 173
Application of Eutectic Ceramic Mixtures for the Functional Components of High-Temperature SOFCsp. 179
A Composite Electrolyte for an SOFC Consisting of a Ceria Sheet and a Zirconia Film Deposited by the Sol-Gel Methodp. 185
Molecular-Dynamic Simulation and Electrical Properties of Ba[subscript 2]In[subscript 2]O[subscript 5]p. 193
Dynamics of the Perovskite-Based High-Temperature Proton-Conducting Oxides: Theory and Experimentp. 199
New Interconnections for Planar Alloy-Separator SOFC Stacksp. 205
Development of Electrolyte Plate for Molten Carbonate Fuel Cellp. 211
Novel Proton Exchange Membrane for High-Temperature Fuel Cellsp. 217
Pulsed Field Gradient NMR Investigation of Molecular Mobility of Trimethoxymethane in NAFION Membranesp. 223
Accelerated Corrosion of Stainless Steels in the Presence of Molten Carbonate Below 923 Kp. 231
Preparation of Pt/WO[subscript 3] Powders and Thin Coatings on Carbon Black and Metal Supports by the Complex Sol-Gel Process (CSGP)p. 237
Carbon Composite for a PEM Fuel Cell Bipolar Platep. 243
Determination of Oxygen Permeation Kinetics in a Ceramic Membrane With the Composition SrFeCo[subscript 0.5]O[subscript 3.25-[delta]]p. 249
Part IV Lithium Ion Rechargeable Batteries - Cathode Materials
Novel Synthesis Process and Characterization of Li-Mn-O Spinels for Rechargeable Lithium Batteriesp. 257
Novel Cathode Materials Based on Organic Couples for Lithium Batteriesp. 263
In Situ X-ray Characterization of LiMn[subscript 2]O[subscript 4]: A Comparison of Structural and Electrochemical Behaviorp. 275
Phase Transition of LiMn[subscript 2]O[subscript 4] Spinel and Its Application for Lithium Ion Secondary Batteryp. 287
LiCoO[subscript 2] Thin Films Grown by Pulsed Laser Deposition on Low-Cost Substratesp. 293
Synthesis and Characterization of LiNiO[subscript 2] as a Cathode Material for Pulse Power Batteriesp. 303
A New Polymer Cathode-Conducting Polymer Interconnected With Sulfur-Sulfur Bonds: Poly(2, 2'-Dithiodianiline)p. 309
LiMn[subscript 2-x]Cu[subscript x]O[subscript 4] Spinels - 5 V Cathode Materialsp. 315
Application of Potentially Biodegradable Polyamide and Polyester Containing Disulfide Bonds to Positive Active Materials for Lithium Secondary Batteriesp. 323
Raman Scattering in LiCoO[subscript 2] Single Crystals and Thin Filmsp. 329
NR Measurements to Study the Reversible Transfer of Lithium Ion in Lithium Titanium Oxidep. 335
Effects of Microstructure on Oxygen Permeation in Some Perovskite Oxidesp. 341
Synthesis and Preliminary Electrochemical Characterization of LiNi[subscript 0.5]Co[subscript 0.5]O[subscript 2] Powders Obtained by the Complex Sol-Gel Process (CSGP)p. 347
Silver-Doped Vanadium Oxides as Host Materials for Lithium Intercalationp. 353
Preparation and Battery Applications of Micron-Sized Li[subscript 4]Ti[subscript 5]O[subscript 12]p. 359
Hydrothermal Synthesis and Characterization of a Series of Novel Zinc Vanadium Oxides as Cathode Materialsp. 367
Structural Phase Transformations in V[subscript 2]O[subscript 5] Thin-Film Cathode Material for Li Rechargeable Batteriesp. 373
High Performance Vanadium Oxide Thin-Film Electrodes for Rechargeable Lithium Batteriesp. 379
Electrochemical Li Insertion in Lamellar (Birnessite) and Tunnel Manganese Oxides (Todorokite)p. 385
Lithium Insertion Behavior of Li[subscript 1+x]V[subscript 3]O[subscript 8] Prepared by Sol-Gel Method in Methanolp. 391
Demonstration of Mixed Metal Oxide Cathode Materials in Prismatic Li Ion Cellsp. 397
Effects of Aluminum Doping on the Phase Stability and Electrochemical Properties of LiCoO[subscript 2] and LiMnO[subscript 2]p. 403
High-Density Active-Site MnO[subscript 2] Nanofibers for Energy Storage and Conversion Applicationsp. 409
Vibrational Spectroscopic Studies of the Local Environment in 4-Volt Cathode Materialsp. 415
Amorphous and Nanocrystalline Oxide Electrodes for Rechargeable Lithium Batteriesp. 421
X-ray Absorption and NMR Studies of LiNiCoO[subscript 2] Cathodes Prepared by a Particulate Sol-Gel Processp. 427
On the Electroanalytical Characterization of Li[subscript x]CoO[subscript 2], Li[subscript x]NiO[subscript 2], and LiMn[subscript 2]O[subscript 4] (Spinel) Electrodes in Repeated Lithium Intercalation-Deintercalation Processesp. 435
Part V Battery Electrolytes, Interfaces, and Passive Films
Thermal Stability of Lithium lon Battery Electrode Materials in Organic Electrolytesp. 445
Effect of HF in LiPF[subscript 6]-Based Electrolytes on the Properties of Surface Passivation Films Formed on Graphite Electrodes in Li Secondary Batteriesp. 457
Influence of Water and Other Contaminants in Electrolyte Solutions on Lithium Electrodepositionp. 463
Passive-Film Formation on Methal Substrates in 1M LiPF[subscript 6]/EC-DMC Solutionsp. 469
Application to Lithium Batteries of Ternary Solvent Electrolytes With Ethylene Carbonate - 1,2-Dimethoxyethane Mixturep. 477
Pyrrole Copolymers With Enhanced lon Diffusion Rates for Lithium Batteriesp. 485
Lithium lon Diffusion Through Glassy Carbon Platep. 493
Polymer-Oxide Anode Materialsp. 499
Ionically Conducting Glasses With Subambient Glass Transition Temperaturesp. 505
Dry Composite Polymer Electrolytes for Lithium Batteriesp. 511
Part VI Lithium Ion Rechargeable Battery - Anode Materials
Comparison of Carbon and Metal Oxide Anode Materials for Rechargeable Li Ion Cellsp. 519
Magnetic and Transport Properties of Heat-Treated Polyparaphenylene-Based Carbonsp. 533
Electrochemical and Spectroscopic Evaluation of Lithium Intercalation in Tailored Polymethacrylonitrile Carbonsp. 539
New [superscript 7]Li-NMR Evidence for Lithium Insertion in Disordered Carbonp. 545
Voltage Hysteresis and Heat Generation Behavior in Lithium lon Batteriesp. 551
A Novel Method for Obtaining a High Performance Carbon Anode for Li Ion Secondary Batteriesp. 557
Local Structure of Ball-Milled Carbons for Lithium Ion Batteries: A Pair Distribution Function Analysisp. 563
Characteristics of Boron-Doped Mesophase Pitch-Based Carbon Fibers as Anode Materials for Lithium Secondary Cellsp. 569
Commercial Cokes and Graphites as Anode Materials for Lithium lon Cellsp. 575
Electrochemical Properties of Nitrogen-Substituted Carbon and Organofluorine Compoundsp. 581
Recent Studies of Interfacial Phenomena Which Determine the Electrochemical Behavior of Lithium and Lithiated Carbon Anodes With the Emphasis on In Situ Techniquesp. 587
Low Potential Li Insertion in Transition-Metal Oxidesp. 601
Effects of Processing Conditions on the Physical and Electrochemical Properties of Carbon Aerogel Compositesp. 607
Improved Carbon Anode Materials for Lithium Ion Cellsp. 613
The Effects of Near Surface and Bulk Microstructure on Lithium Intercalation of Disordered, "Hard" Carbonsp. 619
Part VII Supercapacitors
Electric Double-Layer Capacitor Using Organic Electrolytep. 627
Strontium Ruthenate Perovskites With High Specific Capacitance for Use in Electrochemical Capacitorsp. 637
High-Surface-Area Metal Carbide and Metal Nitride Electrodesp. 643
Modification of a Carbon Electrode Surface by Cold Plasma Treatment for Electric Double-Layer Capacitorsp. 655
Experimental Electrochemical Capacitor Test Resultsp. 661
Growth and Electrochemical Characterization of Single-Phase Mo[subscript x]N Films for the Fabrication of Hybrid Double-Layer Capacitorsp. 669
Author Indexp. 675
Subject Indexp. 679