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Cover image for Metal complexes and metals in macromolecules :  synthesis, structure and properties
Title:
Metal complexes and metals in macromolecules : synthesis, structure and properties
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Publication Information:
Weinheim : Wiley-VCH, 2003
ISBN:
9783527304998
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30000010063639 QD381.8 W63 2003 Open Access Book Book
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Summary

Summary

Metals and metal complexes can form compounds with organic macromolecules that show amazing properties. As is so often the case, nature leads by example. Synthetically produced model compounds, such as phthalocyanines, porphyrines or metalloproteins, as well as metallorganic polymers have aroused much interest in materials science. Their special magnetic, electrochemical and photochemical properties open up new perspectives in microelectronics and sensors.

This compact manual is aimed at all organic, inorganic, polymer and physical chemists as well as materials scientists looking for competent and detailed information on the current state of this interdisciplinary area of research. It covers all questions relating to the targeted design of metallic macromolecules, from proven synthesis methods right up to the latest strategies. It also treats major progress in the determination of their structures, the physical-chemical properties of promising compounds and their potential in microelectronics and sensors. Furthermore, the most important methods of synthesis and investigation are presented in detail in an experimental section, while a comprehensive collection of pertinent original literature rounds off this unique reference on all matters relating to macromolecular metal complexes.


Author Notes

Dieter Wöhrle and Anatolii D. Pomogailo are the authors of Metal Complexes and Metals in Macromolecules: Synthesis, Structure and Properties, published by Wiley.


Table of Contents

Part A Overview And Biological Systems
1 Definition, Classification, History, PropertiesD. W?hrle and A. Pomogailo
2 Macromolecular Metal Complexes in Biological SystemsD. W?hrle and M. Kaneko
Part B Syntheses And Structures
3 Kinetics and Thermodynamics of Formation of Macromolecular Metal Complexes and Their Structural OrganizationA.Pomogailo
4 Polymerisation of Metal-Containing Monomers (MCMs) as a Method for Incorporating Metals in MacromoleculesA.Pomogailo
5 Binding of Metal Ions and Metal Complexes to Macromolecules CarriersD. W?hrle
6 Metal Complexes as Part of a Linear or Cross-linked Macromolecule via the LigandD. W?hrle
7 Metals or Metal Complexes as Part of Linear or Crosslinked Macromolecule via MetalD. W?hrle
8 Metal Complexes or Clusters Physically Embedded in MacromoleculesA. Pomogailo and D. W?hrle
Part C Properties
9 Binding of Small MoleculesJ. Won, et al.
10 Physical and Optical SensorsI. Okura and Y. Amao
11 Catalysis by Soluble Macromolecular Metal ComplexesE. Karakhanov and A. Maximov
12 The State of the Art and Perspectives in Catalysis by Heterogenized Polymer-Bound Metal ComplexesA.Pomogailo
13 Photocatalytic PropertiesM. Kaneko and D. W?hrle
14 Electron- and Photon-Induced ProcessesM.Kaneko
15 OutlookD. W?hrle and A Pomogailo
Index
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