Cover image for MULTIFUNCTIONAL POLYMERIC NANOCOMPOSITES BASED ON CELLULOSIC REINFORCEMENTS
Title:
MULTIFUNCTIONAL POLYMERIC NANOCOMPOSITES BASED ON CELLULOSIC REINFORCEMENTS
Physical Description:
xiv, 394 pages : illustrations ; 24 cm.
ISBN:
9780323442480
Abstract:
Multifunctional Polymeric Nanocomposites Based on Cellulosic Reinforcements introduces the innovative applications of polymeric materials based on nanocellulose, and covers extraction methods, functionalization approaches, and assembly methods to enable these applications. The book presents the state-of-the-art of this novel nano-filler and how it enables new applications in many different sectors, beyond existing products. With a focus on application of nano-cellulose based polymers with multifunctional activity, the book explains the methodology of nano-cellulose extraction and production and shows the potential performance benefits of these particular nanostructured polymers, for applications across different sectors, including food active packaging, energy-photovoltaics, biomedical, and filtration. The book describes how the different methodologies, functionalization, and organization at the nano-scale level could contribute to the design of required properties at macro level. The book studies the interactions between the main nano-filler with other active systems and how this interaction enables multi-functionality in the produced materials. The book is an indispensable resource for the growing number of scientists and engineers interested in the preparation and novel applications of nano-cellulose, and for industrial scientists active in formulation and fabrication of polymer products based on renewable resources. - Provides insight into nanostructure formation science, and processing of polymeric materials and their characterization - Offers a strong analysis of real industry needs for designing the materials - Provides a well-balanced structure, including a light introduction of basic knowledge on extraction methods, functionalization approaches, and assembling focused to applications - Describes how different methodologies, functionalization, and organization at the nano-scale level could contribute to the design of required properties at macro level

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30000010342659 TA418.9.N35 M85 2016 Open Access Book Book
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Summary

Summary

Multifunctional Polymeric Nanocomposites Based on Cellulosic Reinforcements introduces the innovative applications of polymeric materials based on nanocellulose, and covers extraction methods, functionalization approaches, and assembly methods to enable these applications. The book presents the state-of-the-art of this novel nano-filler and how it enables new applications in many different sectors, beyond existing products.

With a focus on application of nano-cellulose based polymers with multifunctional activity, the book explains the methodology of nano-cellulose extraction and production and shows the potential performance benefits of these particular nanostructured polymers, for applications across different sectors, including food active packaging, energy-photovoltaics, biomedical, and filtration. The book describes how the different methodologies, functionalization, and organization at the nano-scale level could contribute to the design of required properties at macro level.

The book studies the interactions between the main nano-filler with other active systems and how this interaction enables multi-functionality in the produced materials. The book is an indispensable resource for the growing number of scientists and engineers interested in the preparation and novel applications of nano-cellulose, and for industrial scientists active in formulation and fabrication of polymer products based on renewable resources.


Author Notes

Debora Puglia, PhD, Researcher and Lecturer at the University of Perugia.
Elena Fortunati, PhD, Researcher in the Civil and Environmental Engineering Department at the University of Perugia.
Jos Maria Kenny, Professor of Materials Science and Technology at the University of Perugia and Director of the European Centre for Nanostructured Polymers.


Table of Contents

E. Fortunati and F. Luzi and D. Puglia and L. TorreV.F. Corujo and P. Cerrutti and M.L. Foresti and A. VázquezE. Lizundia and E. Meaurio and J.L. VilasF. Ansari and L.A. BerglundF. Khelifa and Y. Habibi and P. DuboisM. Ramos and A. Valdés and M.C. GarrigósM.P. Arrieta and E. Fortunati and N. Burgos and M.A. Peltzer and J. López and L. PeponiD.A. Gopakumar and S. Thomas and Y. GrohensA.S. Olalla and V. Sessini and E.G. Torres and L. PeponiS.G. Falkovich and S.V. Larin and N.V. Lukasheva and V.M. Nazarychev and D.A. Tolmachev and A.D. Glova and D.A. Mezhenskaia and J.M. Kenny and S.V. LyulinA. Kadimi and K. Benhamou and Y. Habibi and Z. Ounaies and H. Kaddami
List of Contributorsp. ix
Prefacep. xiii
1 Extraction of Lignocellulosic Materials From Waste Productsp. 1
1.1 Introductionp. 1
1.2 Cellulosic-Based Material Structure and Propertiesp. 7
1.3 Hemicellulose Structure, Properties, and Applicationsp. 15
1.4 Lignin Structure, Properties, and Applicationsp. 24
1.5 Conclusionsp. 30
Referencesp. 31
2 Production of Bacterial Nanocellulose From Non-Conventional Fermentation Mediap. 39
2.1 Introductionp. 39
2.2 Microbial Fermentationsp. 41
2.3 Bacterial Nanocellulosep. 43
2.4 Bacterial Nanocellulose Production: Why Look for Alternative Raw Materials?p. 46
2.5 Conclusionsp. 55
Referencesp. 56
3 Grafting of Cellulose Nanocrystalsp. 61
3.1 Introductionp. 61
3.2 Grafting of Cellulose Nanocrystalsp. 64
3.3 Polymer Nanocomposites Containing Grafted Cellulose Nanocrystalsp. 93
3.4 Conclusions, Perspectives, and Emerging Ideasp. 103
Referencesp. 104
4 Tensile Properties of Wood Cellulose Nanopaper and Nanocomposite Filmsp. 115
4.1 Introductionp. 115
4.2 Stress-Strain Behavior of Cellulose Nanopaper Filmsp. 117
4.3 Polymer Matrix Nanocompositesp. 122
4.4 Concluding Remarksp. 126
Referencesp. 129
5 Nanocellulose-Based Polymeric Blends for Coating Applicationsp. 131
5.1 Introduction to Coatingsp. 131
5.2 Generalities on Acrylics and Cellulose Nanocrystalsp. 137
5.3 Acrylic-Based Coatings and Nanocompositesp. 140
5.4 Conclusionsp. 172
Acknowledgmentsp. 173
Referencesp. 173
6 Multifunctional Applications of Nanocellulose-Based Nanocompositesp. 177
6.1 Introductionp. 177
6.2 Cellulose Nanofibrils, Nanocrystals, and Bacterial Cellulosep. 179
6.3 Nanocellulose-Based Nanocompositesp. 181
6.4 Applications of Nanocellulose-Based Compositesp. 184
6.5 Conclusionsp. 194
Referencesp. 195
7 Nanocellulose-Based Polymeric Blends for Food Packaging Applicationsp. 205
7.1 Introductionp. 206
7.2 Nanocellulose Structure and Extraction Proceduresp. 209
7.3 Nanocellulose Modifications to Improve Its Compatibility With Polymer Matricesp. 217
7.4 Processing Aspects of Nanocellulose-Based Polymer Blendsp. 220
7.5 Properties of Nanocellulose-Based Nanocomposite Blends and Their Merits for Food Packagingp. 223
7.6 Release Aspects From Nanocellulose-Based Polymer Blendsp. 237
7.7 Nanocellulose-Based Polymer Nanocomposite Blend Biodegradation Behaviorp. 242
7.8 Conclusionsp. 244
Acknowledgmentp. 245
Referencesp. 245
8 Nanocelluloses as Innovative Polymers for Membrane Applicationsp. 253
8.1 Introductionp. 253
8.2 Comparison of Cellulose Nancocrystals and Cellulose Nanofibersp. 254
8.3 Nanocellulose-Based Membranes for Fuel Cell Applicationsp. 256
8.4 Nanocellulose-Based Membranes for Wound Healing Applicationsp. 259
8.5 Nanocellulose-Based Membranes for Gas Barrier Applicationsp. 261
8.6 Nanocellulose-Based Membranes for Water Purificationp. 265
8.7 Conclusionsp. 271
Referencesp. 272
9 Smart Nanocellulose Composites With Shape-Memory Behaviorp. 277
9.1 General Concept on Shape-Memory Polymersp. 277
9.2 General Concept on Nanocellulosep. 278
9.3 Mechanisms of Thermally Activated Shape-Memory Polymersp. 281
9.4 Biodegradable Shape-Memory Polymersp. 287
9.5 Shape-Memory Polymer Compositesp. 294
9.6 Cellulose Nanocrystals as Potential Filler for Shape-Memory Polymersp. 296
9.7 Conclusionsp. 302
Acknowledgmentsp. 302
Referencesp. 303
10 Computational Modeling of Polylactide and Its Cellulose-Reinforced Nanocompositesp. 313
10.1 Introductionp. 313
10.2 Simulation of Cellulosep. 318
10.3 Simulation of Polylactide and Polylactide-Based Compositesp. 320
10.4 Generation of the Initial Configuration and Equilibration of Cellulose-Reinforced Polylactide Nanocompositesp. 323
10.5 Simulation of Structural, Thermal, and Mechanical Properties of Nanocomposites by Atomistic Molecular Dynamicsp. 325
10.6 Development of the Method for Simulation of Nanoceltulose-Modified With Polylactide Chains Using Classical and Quantum Mechanical Approachesp. 330
10.7 Conclusionsp. 335
Acknowledgmentp. 336
Referencesp. 336
11 Nanocellulose Alignment and Electrical Properties Improvementp. 343
11.1 General Introductionp. 343
11.2 Cellulose: Chemical and Physical Proprietiesp. 344
11.3 Preparation of Nanocellulosesp. 346
11.4 Miciostructure of Nanocellulosep. 350
11.5 Alignment Techniquesp. 351
11.6 Orientation of Nanocellulose and Electrical Propertiesp. 357
11.7 Electric Field Manipulation of Nanofiber Cellulosesp. 361
11.8 Conclusionp. 370
Acknowledgmentp. 370
Referencesp. 371
Indexp. 377