Cover image for Nanotechnology : the whole story
Title:
Nanotechnology : the whole story
Personal Author:
Publication Information:
Boca Raton : CRC Press, 2013
Physical Description:
xvii, 377 p. : ill. ; 25 cm.
ISBN:
9781439897805

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35000000000154 T174.7 R634 2013 Open Access Book Book
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30000010327941 T174.7 R634 2013 Open Access Book Book
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Summary

Summary

Winner of an Outstanding Academic Title Award from CHOICE Magazine

Transistors using one electron at a time. Seemingly transparent sunscreens made with titanium dioxide particles that block harmful UV rays. Nanometer-sized specks of gold that change color to red and melt at 750°C instead of 1,064°C. Nanotechnology finds the unique properties of things at the nanometer scale and then puts them to use!

Although nanotechnology is a hot topic with a wide range of fascinating applications, the search for a true introductory popular resource usually comes up cold. Closer to a popular science book than a high-level treatise, Nanotechnology: The Whole Story works from the ground up to provide a detailed yet accessible introduction to one of the world's fastest growing fields.

Dive headlong into nanotechnology! Tackling the eight main disciplines--nanomaterials, nanomechanics, nanoelectronics, nanoscale heat transfer, nanophotonics, nanoscale fluid mechanics, nanobiotechnology, and nanomedicine--this book explains what's different at the nanoscale, and how we exploit those differences to make useful things. You're holding the key to an exciting and rapidly evolving field.

So get The Whole Story ...


Author Notes

Ben Rogers is a writer and an engineer (BS 2001; MS 2002, University of Nevada, Reno). He has done research at Nanogen, the Oak Ridge National Laboratory, and NASA's Jet Propulsion Laboratory, and published many technical papers, as well as fictional works and essays (which can be found at http://www.readrogers.com). He is currently the principal engineer at NevadaNano.

Jesse Adams (BS 1996, University of Nevada; MS 1997 and PhD 2001, Stanford University) is the vice president and CTO of NevadaNano. He is working to bring multifunctional microsensor technology to the chemical sensing market space.

Sumita Pennathur is currently an associate professor of mechanical engineering at the University of California, Santa Barbara (BS 2000, MS 2001, Massachusetts Institute of Technology; PhD 2005, Stanford University). She has been actively contributing to the fields of nanofluidics and nanoelectromechanical systems (NEMS), and was awarded both a Presidential Early Career Award for Science and Engineering (PECASE) in 2011, and well as a DARPA Young Faculty Award in 2008.


Reviews 1

Choice Review

This book by Rogers and Adams (both, NevadaNano) and Pennathur (Univ. of California, Santa Barbara) is an excellent resource for anyone interested in nanotechnology. The text is well structured and easy to read. Each chapter starts with a brief "Background" section, which introduces a specific topic. Related historical facts are frequently included. Individual subchapters are hardly longer than a page or two. Mixed within those sections are paragraphs titled "A Little More," which provide (calculation) examples for specific concepts. The chapters do not deal with highly futuristic subjects like nanorobots as do other books on nanotechnology, but instead emphasize explaining scientific concepts that are already being applied in nanotechnology in areas such as biotechnology, medicine, electronics, and physics. The examples provided throughout the text will help readers get a realistic feeling for when and how these "nano effects" are to be expected. A list of reading suggestions follows each chapter. Very simple pictures illustrate the concepts, so even undergraduate students will be able to understand them. Graduate students will find enough detail to provide them with ideas for further investigation and a deeper understanding of the field. Summing Up: Highly recommended. Students of all levels, researchers/faculty, and professionals. H. Giesche Alfred University


Table of Contents

Prefacep. xiii
Acknowledgmentsp. xv
An Invitationp. xvi
Authorsp. xvii
1 Big Picture of the Small Worldp. 1
1.1 Understanding the Atom: Ex Nihilo Nihil Fitp. 3
1.2 Nanotechnology Starts with a Dare: Feynman's Big Little Challengesp. 11
1.3 Why One-Billionth of a Meter Is a Big Dealp. 15
1.4 Thinking It Through: The Broad Implications of Nanotechnologyp. 18
1.4.1 Gray Goop. 21
1.4.2 Environmental Impactp. 21
1.4.3 The Written Wordp. 23
1.5 The Business of Nanotech: Plenty of Room at the Bottom Line, Toop. 25
1.5.1 Productsp. 27
Recommendations for Further Readingp. 27
2 Introduction to Miniaturizationp. 29
2.1 Background: The Smaller, the Betterp. 29
2.2 Scaling Lawsp. 30
2.2.1 The Elephant and the Fleap. 30
2.2.2 Scaling in Mechanicsp. 34
2.2.3 Scaling in Electricity and Electromagnetismp. 37
2.2.4 Scaling in Opticsp. 38
2.2.5 Scaling in Heat Transferp. 41
2.2.6 Scaling in Fluidsp. 42
2.2.7 Scaling in Biologyp. 43
2.3 Accuracy of the Scaling Lawsp. 44
Recommendations for Further Readingp. 46
3 Introduction to Nanoscale Physicsp. 47
3.1 Background: Newton Never Saw a Nanotubep. 47
3.2 One Hundred Hours and Eight Minutes of Nanoscale Physicsp. 47
3.3 The Basics of Quantum Mechanicsp. 48
3.3.1 Atomic Orbitals (Not Orbits)p. 49
3.3.2 Electromagnetic Wavesp. 52
3.3.2.1 How Electromagnetic Waves Are Madep. 56
3.3.3 The Quantization of Energyp. 57
3.3.4 Atomic Spectra and Discretenessp. 61
3.3.5 The Photoelectric Effectp. 61
3.3.6 Wave-Particle Duality: The Double-Slit Experimentp. 66
3.3.6.1 Bulletsp. 67
3.3.6.2 Water Wavesp. 68
3.3.6.3 Electronsp. 69
3.3.7 The Uncertainty Principlep. 71
3.3.8 Particle in a Wellp. 73
3.4 Summaryp. 76
Recommendations for Further Readingp. 77
4 Nanomaterialsp. 79
4.1 Background: Matter Mattersp. 79
4.2 Bonding Atoms to Make Molecules and Solidsp. 79
4.2.1 Ionic Bondingp. 81
4.2.2 Covalent Bondingp. 83
4.2.3 Metallic Bondingp. 84
4.2.4 Walking through Waals: van der Waals Forcesp. 84
4.2.4.1 The Dispersion Forcep. 86
4.2.4.2 Repulsive Forcesp. 87
4.2.4.3 van der Waals Force versus Gravityp. 88
4.3 Crystal Structuresp. 90
4.4 Structures Small Enough to Be Different (and Useful)p. 92
4.4.1 Particlesp. 93
4.4.1.1 Colloidal Particlesp. 98
4.4.2 Wiresp. 98
4.4.3 Films, Layers, and Coatingsp. 100
4.4.4 Porous Materialsp. 103
4.4.5 Small-Grained Materialsp. 105
4.4.6 Moleculesp. 108
4.4.6.1 Carbon Fullerenes and Nanotubesp. 109
4.4.6.2 Dendrimersp. 115
4.4.6.3 Micellesp. 115
4.5 Summaryp. 118
Recommendations for Further Readingp. 119
5 Nanomechanicsp. 121
5.1 Background: The Universe Mechanismp. 121
5.1.1 Nanomechanics: Which Motions and Forces Make the Cut?p. 122
5.2 A High-Speed Review of Motion: Displacement, Velocity, Acceleration, and Forcep. 123
5.3 Nanomechanical Oscillators: A Tale of Beams and Atomsp. 125
5.3.1 Beamsp. 126
5.3.1.1 Free Oscillationp. 126
5.3.1.2 Free Oscillation from the Perspective of Energy (and Probability)p. 129
5.3.1.3 Forced Oscillationp. 132
5.3.2 Atomsp. 134
5.3.2.1 The Lennard-Jones Interaction: How an Atomic Bond Is Like a Springp. 135
5.3.2.2 The Quantum Mechanics of Oscillating Atomsp. 139
5.3.2.3 The Schrödinger Equation and the Correspondence Principlep. 141
5.3.2.4 Phononsp. 146
5.3.3 Nanomechanical Oscillator Applicationsp. 150
5.3.3.1 Nanomechanical Memory Elementsp. 150
5.3.3.2 Nanomechanical Mass Sensors: Detecting Low Concentrationsp. 153
5.4 Feeling Faint Forcesp. 157
5.4.1 Scanning Probe Microscopesp. 158
5.4.1.1 Pushing Atoms Around with the Scanning Tunneling Microscopep. 158
5.4.1.2 Skimming across Atoms with the Atomic Force Microscopep. 159
5.4.1.3 Pulling Atoms Apart with the AFMp. 164
5.4.1.4 Rubbing and Mashing Atoms with the AFMp. 168
5.4.2 Mechanical Chemistry: Detecting Molecules with Bending Beamsp. 170
5.5 Summaryp. 172
Recommendations for Further Readingp. 173
6 Nanoelectronicsp. 175
6.1 Background: The Problem (Opportunity)p. 175
6.2 Electron Energy Bandsp. 175
6.3 Electrons in Solids: Conductors, Insulators, and Semiconductorsp. 179
6.4 Fermi Energyp. 182
6.5 Density of States for Solids 185 6.5.1 Electron Density in a Conductorp. 186
6.6 Turn Down the Volume! (How to Make a Solid Act More Like an Atom)p. 186
6.7 Quantum Confinementp. 187
6.7.1 Quantum Structuresp. 189
6.7.1.1 Uses for Quantum Structuresp. 191
6.7.2 How Small Is Small Enough for Confinement?p. 192
6.7.2.1 Conductors: The Metal-to-Insulator Transitionp. 193
6.7.2.2 Semiconductors: Confining Excitonsp. 194
6.7.3 The Band Gap of Nanomaterialsp. 196
6.8 Tunnelingp. 198
6.9 Single-Electron Phenomenap. 202
6.9.1 Two Rules for Keeping the Quantum in Quantum Dotp. 205
6.9.1.1 Rule 1: The Coulomb Blockadep. 206
6.9.1.2 Rule 2: Overcoming Uncertaintyp. 207
6.9.2 Single-Electron Transistor (SET)p. 208
6.10 Molecular Electronicsp. 211
6.10.1 Molecular Switches and Memory Storagep. 215
6.11 Summaryp. 216
Recommendations for Further Readingp. 216
7 Nanoscale Heat Transferp. 219
7.1 Background: Hot Topicp. 219
7.2 All Heat Is Nanoscale Heatp. 219
7.2.1 Boltzmann's Constantp. 220
7.3 Conductionp. 221
7.3.1 Thermal Conductivity of Nanoscale Structuresp. 224
7.3.1.1 Mean Free Path and Scattering of Heat Carriersp. 224
7.3.1.2 Thermoelectrics: Better Energy Conversion with Nanostructuresp. 227
7.3.1.3 Quantum of Thermal Conductionp. 229
7.4 Convectionp. 230
7.5 Radiationp. 232
7.5.1 Increased Radiation Heat Transfer: Mind the Gap!p. 232
7.6 Summaryp. 235
Recommendations for Further Readingp. 236
8 Nanophotonicsp. 237
8.1 Background: The Lycurgus Cup and the Birth of the Photonp. 237
8.2 Photonic Properties of Nanomaterialsp. 238
8.2.1 Photon Absorptionp. 238
8.2.2 Photon Emissionp. 240
8.2.3 Photon Scatteringp. 240
8.2.4 Metalsp. 241
8.2.4.1 Permittivity and the Free Electron Plasmap. 243
8.2.4.2 Extinction Coefficient of Metal Particlesp. 244
8.2.4.3 Colors and Uses of Gold and Silver Particlesp. 247
8.2.5 Semiconductorsp. 249
8.2.5.1 Tuning the Band Gap of Nanoscale Semiconductorsp. 249
8.2.5.2 Colors and Uses of Quantum Dotsp. 251
8.2.5.3 Lasers Based on Quantum Confinementp. 254
8.3 Near-Field Lightp. 256
8.3.1 Limits of Light: Conventional Opticsp. 257
8.3.2 Near-Field Optical Microscopesp. 259
8.4 Optical Tweezersp. 262
8.5 Photonic Crystals: A Band Gap for Photonsp. 263
8.6 Summaryp. 264
Recommendations for Further Readingp. 265
9 Nanoscale Fluid Mechanicsp. 267
9.1 Background: Becoming Fluent in Fluidsp. 267
9.1.1 Treating a Fluid the Way It Should Be Treated: The Concept of a Continuump. 267
9.1.1.1 Fluid Motion, Continuum Style: The Navier-Stokes Equationsp. 269
9.1.1.2 Fluid Motion: Molecular Dynamics Stylep. 270
9.2 Fluids at the Nanoscale: Major Conceptsp. 272
9.2.1 Swimming in Molasses: Life at Low Reynolds Numbersp. 272
9.2.1.1 Reynolds Numberp. 273
9.2.2 Surface Charges and the Electrical Double Layerp. 275
9.2.2.1 Surface Charges at Interfacesp. 276
9.2.2.2 Gouy-Chapman-Stern Model and Electrical Double Layerp. 276
9.2.2.3 Electrokinetic Phenomenap. 279
9.2.3 Small Particles in Small Flows: Molecular Diffusionp. 279
9.3 How Fluids Flow at the Nanoscalep. 282
9.3.1 Electroosmosisp. 282
9.3.2 Ions and Macromolecales Moving through a Channelp. 283
9.3.2.1 The Convection-Diffusion-Electromigration Equation: Nanochannel Electrophoresisp. 286
9.3.2.2 Macromolecules in a Nanofluidic Channelp. 290
9.4 Applications of Nanofluidicsp. 290
9.4.1 Analysis of Biomolecules: An End to Painful Doctor Visits?p. 291
9.4.2 EO Pumps: Cooling Off Computer Chipsp. 293
9.4.3 Other Applicationsp. 293
9.5 Summaryp. 293
Recommendations for Further Readingp. 295
10 Nanobiotechnologyp. 297
10.1 Background: Our World in a Cellp. 297
10.2 Introduction: How Biology Feels at the Nanometer Scalep. 299
10.2.1 Biological Shapes at the Nanoscale: Carbon and Water Are the Essential Toolsp. 299
10.2.2 Inertia and Gravity Are Insignificant: The Swimming Bacteriump. 301
10.2.3 Random Thermal Motionp. 302
10.3 The Machinery of the Cellp. 305
10.3.1 Sugars Are Used for Energy (but Also Structure)p. 306
10.3.1.1 Glucosep. 307
10.3.2 Fatty Acids Are Used for Structure (but Also Energy)p. 310
10.3.2.1 Phospholipidsp. 312
10.3.3 Nucleotides Are Used to Store Information and Carry Chemical Energyp. 315
10.3.3.1 Deoxyribonucleic Acidp. 315
10.3.3.2 Adenosine Triphosphatep. 320
10.3.4 Amino Acids Are Used to Make Proteinsp. 323
10.3.4.1 ATP Synthasep. 324
10.4 Applications of Nanobiotechnologyp. 327
10.4.1 Biomimetic Nanostructuresp. 328
10.4.2 Molecular Motorsp. 328
10.5 Summaryp. 329
Recommendations for Further Readingp. 330
11 Nanomedicinep. 331
11.1 What Is Nanomedicine?p. 331
11.2 Medical Nanoparticlesp. 332
11.2.1 Nanoshellsp. 332
11.2.2 Lipid-Based Nanoparticlesp. 335
11.2.3 Polymer-Based Nanoparticlesp. 337
11.2.4 Drug Delivery Using Nanoparticlesp. 337
11.3 Nanomedicine and Cancerp. 338
11.4 Biomimicry in Nanomedicinep. 340
11.5 Potential Toxicityp. 344
11.6 Environmental Concernsp. 345
11.7 Ethical Implicationsp. 346
11.8 Commercial Explorationp. 346
11.9 Summaryp. 347
Recommendations for Further Readingp. 347
Glossaryp. 349
Indexp. 365