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Library | Item Barcode | Call Number | Material Type | Item Category 1 | Status |
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Searching... | 30000010163027 | QC718.5.P55 I84 2007 | Open Access Book | Book | Searching... |
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Summary
Summary
A variety of plasmas include molecules rather than only ions or atoms. Examples are ionospheres of the Earth and other planets, stellar atmospheres, gaseous discharges for use in various devices and processes, and fusion plasmas in the edge region. This book describes the role of molecules in those plasmas by showing elementary collision processes involving those molecules. All possible processes are presented both for electron and ion collisions with the molecules. On the basis of the accumulated knowledge in atomic and molecular physics, a compact but informative description is given for each process. Specific emphasis is placed on the feature which application people often tend to overlook.
Author Notes
The author graduated from the Physics Department, University of Tokyo. As a PhD thesis, he studied the theoretical plasma physics. He has been working at the Institute of Space and Astronautical Science (before the organizational change in 1982, the Institute of Space and Aeronautical Science, University of Tokyo) for more than thirty years. He is now the professor emeritus at the Institute. His main interest is in the theoretical atomic and molecular physics, particularly on the electron or photon collisions with molecules. He is also interested in the application of the atomic and molecular physics to other fields (space science, plasma physics, radiation interaction with matter, etc.). He has personally organized an activity of compilation of cross section data. He published, with his colleagues, data reviews on electron collisions with molecules such as N2, O2, CO2, and H2O. He served as the editor of the volume of the Landolt Börnstein series on electron/photon collisions with atoms, molecules, and ions.
Table of Contents
1 Introduction | p. 1 |
2 Plasmas Involving Molecules | p. 5 |
2.1 Ionosphere | p. 5 |
2.1.1 Energy Degradation of Photoelectrons | p. 7 |
2.1.2 Optical Emission | p. 7 |
2.1.3 Energy Balance and Transport Phenomena in Thermal Electrons | p. 10 |
2.2 Interstellar Cloud | p. 10 |
2.3 Gaseous Discharges | p. 13 |
2.3.1 Production and Maintenance of Plasmas | p. 13 |
2.3.2 Determination of Electron Energy Distribution Function | p. 14 |
2.3.3 Production of Active Species | p. 6 |
2.4 Fusion Plasma | p. 17 |
3 Collision Cross-Sections and Related Quantities | p. 21 |
3.1 Definitions and Fundamental Relations | p. 21 |
3.2 Cross-Section in the Quantum Theory | p. 25 |
3.3 Scattering from a Spherical Potential | p. 26 |
3.4 One-Body vs. Two-Body Problems | p. 28 |
3.5 Experimental Methods to Obtain Cross-Sections | p. 33 |
3.5.1 Measurement of Energy Loss of Electrons | p. 33 |
3.5.2 Detection of Collision Products | p. 34 |
3.5.3 Beam Attenuation Method | p. 35 |
3.5.4 Merged Beam Method | p. 36 |
3.5.5 Swarm Experiment | p. 37 |
4 Molecule as a Collision Partner | p. 39 |
4.1 Molecular Structure and Energy Levels | p. 39 |
4.2 Interaction of Charged Particles with Molecules | p. 45 |
4.3 Electron Collision with a Diatomic Molecule | p. 48 |
4.4 Remarks on the Collision with Polyatomic Molecules | p. 53 |
4.5 The Born Approximation | p. 54 |
5 Electron Collisions with Molecules | p. 57 |
5.1 Collision Processes | p. 57 |
5.2 Elastic Scattering | p. 59 |
5.3 Momentum-Transfer | p. 64 |
5.4 Rotational Transition | p. 69 |
5.5 Vibrational Transition | p. 77 |
5.6 Excitation of Electronic State | p. 85 |
5.7 Ionization | p. 91 |
5.8 Electron Attachment | p. 99 |
5.8.1 Dissociative Attachment | p. 100 |
5.8.2 Three-Body Attachment | p. 103 |
5.8.3 Metastable Negative Ion | p. 103 |
5.9 Emission | p. 104 |
5.10 Dissociation | p. 109 |
5.11 Total Scattering Cross-Section | p. 115 |
5.12 Stopping Cross-Section | p. 118 |
5.13 Collisions with Excited Molecules | p. 121 |
6 Ion Collisions with Molecules | p. 127 |
6.1 Characteristics of Ion Collisions Compared with Electron Collisions | p. 127 |
6.2 Momentum-Transfer | p. 130 |
6.3 Inelastic Scattering | p. 136 |
6.4 Reaction | p. 139 |
7 Electron Collisions with Molecular Ions | p. 145 |
7.1 General Remarks | p. 145 |
7.2 Electron-Ion Recombination | p. 148 |
7.2.1 Three-Body Recombination | p. 148 |
7.2.2 Dissociative Recombination | p. 150 |
8 Summary of the Roles of the Molecular Processes in Plasmas | p. 155 |
A Order of Magnitude of Macroscopic Quantities | p. 157 |
B Molecular Properties | p. 161 |
C Atomic Units and Evaluation of the Born Cross-Section | p. 167 |
C.l Definition of Atomic Units | p. 167 |
C.2 Example of the Calculation of the Born Cross-Section for Rotational Transitions | p. 168 |
C.3 Example of the Calculation of the Born Cross-Section for Vibrational Transitions | p. 169 |
D Cross-Section Sets for H 2 , N 2 , H 2 O, and CO 2 | p. 171 |
E How to Find Cross-Section Data | p. 175 |
E.l Data Compilations in Printed Form | p. 175 |
E.2 Journals Exclusively Focused on Atomic and Molecular Data | p. 177 |
E.3 Online Database | p. 177 |
E.4 Review Papers | p. 177 |
E.5 Conference | p. 178 |
F Data Compilations for Electron Molecule Collisions | p. 181 |
G Data Compilations for Ion Molecule Reactions and Related Processes | p. 185 |
References | p. 187 |
Index | p. 193 |