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Cover image for Air quality in urban environments
Title:
Air quality in urban environments
Series:
Issues in environmental science and technology ; 28
Publication Information:
Cambridge, UK : RSC Publishing, 2009
Physical Description:
xii, 148 p. : ill. ; 24 cm.
ISBN:
9781847559074

Available:*

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30000010210687 TD883 A37 2009 Open Access Book Book
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33000000000656 TD883 A37 2009 Open Access Book Book
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Summary

Summary

Urban air quality is a topic which remains high on the scientific and political agenda. Concentrations of most air pollutants are higher in urban areas than in the surrounding rural regions, and given the high population densities, it is within urban areas that the majority of the population receive their air pollutant exposure. Despite the continued implementation of abatement measures, concentrations of air pollutants within urban areas frequently exceed health-based guidelines and stricter measures to restrict emissions are required. This comprehensive volume, written by authoritative authors, deals with the basic science of urban air pollution in relation to the sources and concentrations, and the atmospheric chemical and physical processes which determine those concentrations and lead to the formation of secondary pollutants by chemical reactions in the atmosphere. The health effects of urban air pollution are described as is the policy response designed to mitigate the problems. Some of the highest air pollutant exposures occur within underground railway systems and this topic is considered explicitly in its own chapter. With comprehensive coverage from sources through atmospheric processes, to human exposure and effects on health and the policy response, this topical work will be of interest to scientists and policy makers within this field as well advanced students.


Author Notes

The series has been edited by Professors Hester and Harrison since it began in 1994.

Professor Roy Harrison OBE is listed by ISI Thomson Scientific (on ISI Web of Knowledge) as a Highly Cited Researcher in the Environmental Science/Ecology category. He has an h-index of 54 (i.e. 54 of his papers have received 54 or more citations in the literature). In 2004 he was appointed OBE for services to environmental science in the New Year Honours List. He was profiled by the Journal of Environmental Monitoring (Vol 5, pp 39N-41N, 2003). Professor Harrison's research interests lie in the field of environment and human health. His main specialism is in air pollution, from emissions through atmospheric chemical and physical transformations to exposure and effects on human health. Much of this work is designed to inform the development of policy.

Now an emeritus professor, Professor Ron Hester's current activities in chemistry are mainly as an editor and as an external examiner and assessor. He also retains appointments as external examiner and assessor / adviser on courses, individual promotions, and departmental / subject area evaluations both in the UK and abroad.


Reviews 1

Choice Review

This edited book is designed to provide a "comprehensive overview" of urban air quality. One cannot be really comprehensive in only 145 pages, considering the range of topics covered, but chapters are well supplied with current references, and the book appears well indexed. Can students or professionals really understand the chemistry when supplied with the relevant chemical reactions but essentially none of the algebra? The book presents the simplest version of the photostationary state equation, which relates the concentrations of ozone, nitrogen dioxide, and nitric oxide. It does not present the fact that this useful equation is a balance of kinetic terms, nor does it indicate that it can be derived from the chemical reaction scheme already provided, but not elaborated upon. This is the level of generality at which all topics are treated, except perhaps the chapter focusing on health issues, which includes more graphical material. One drawback of an edited multi-author book is repetition; for example, the discussion of street canyon meteorology, an important subject, must have occurred at least three times. This book is useful to a general environmental science audience, but more substantial information is needed for it to serve as a textbook. Summing Up: Recommended. Lower- and upper-division undergraduates, two-year technical program students, and professionals. D. H. Stedman University of Denver


Table of Contents

Ole Hertel and Michael Evan GoodsiteSalmond and McKendryBlossJenny A. Salmond and I.G. McKendryWilliam BlossImre SalmaSotiris VardoulakisRobert L. MaynardMartin Williams
Urban Air Pollution Climates throughout the Worldp. 1
1 Introductionp. 1
1.1 Emission and Formation of Urban Air Pollutionp. 2
1.2 Urban Pollution Levels and Indicatorsp. 3
2 Sources in the Vicinity of the Cityp. 4
3 Impact of the Geography, Topography and Meteorologyp. 5
3.1 Geographyp. 5
3.2 Topographyp. 6
3.3 Meteorologyp. 6
4 Pollutant Dispersion in Urban Streetsp. 7
5 Nitrogen Dioxide Pollution in Urban Areasp. 8
6 Particle Pollution in Urban Areasp. 9
6.1 Particle Mass Concentrationsp. 9
6.2 Particle Number Concentrationsp. 11
6.3 Importance of Measurement Locationp. 13
6.4 Contribution from Natural Processesp. 13
7 Polycyclic Aromatic Hydrocarbons (PAH) in Urban Areasp. 13
7.1 Sources and Emissionsp. 13
7.2 Sampling Artefactsp. 15
7.3 Long Range Transportp. 16
7.4 Future Requirementsp. 16
8 Trace Elements, including Heavy Metals in Urban Areasp. 16
8.1 Heavy Metalsp. 17
8.2 Trace Elementsp. 17
8.3 Recommendations for Modellingp. 18
9 Conclusionsp. 18
Referencesp. 19
Influences of Meteorology on Air Pollution Concentrations and Processes in Urban Areasp. 23
1 Introductionp. 24
2 The Polluted Urban Atmospherep. 26
3 The Urban Canopy Layerp. 29
3.1 Emissions, Intra-Urban Variability and Data Sourcesp. 29
3.2 Flow Patterns within the Urban Canopy Layerp. 30
3.3 Street Canyonsp. 30
3.4 Vertical Exchange Processes: Coupling the UCL to the UBLp. 32
4 Larger Scale Processes Affecting Urban Air Pollutionp. 33
4.1 Mesoscale Flowsp. 34
4.2 Regional Transportp. 35
4.3 Synoptic Scalesp. 36
4.4 Global Scales and "Chemical Weather"p. 37
5 Conclusionsp. 37
Acknowledgementsp. 38
Referencesp. 38
Atmospheric Chemical Processes of Importance in Citiesp. 42
1 Introductionp. 43
2 Emissions in the City Environmentp. 43
3 Dynamic Considerationsp. 45
4 Gas-phase Chemical Processingp. 46
4.1 NO x -Ozone Interactionsp. 46
4.2 Oxidant Radicals and Ozone Productionp. 48
4.3 Night-Time Processesp. 50
4.4 Timescales of Ozone Productionp. 51
4.5 Analysis of Ozone Sourcesp. 52
4.6 Limits on Ozone Production: NO x -Limited and VOC-Limitedp. 52
5 Modifications Particular to the Urban Environmentp. 54
5.1 Radical Sourcesp. 54
5.2 VOC Speciation and Abundancep. 56
5.3 Primary Emissions of NO 2p. 57
6 Particulate Phase Chemistryp. 58
6.1 Chemical Compositionp. 59
6.2 Secondary Particle Formationp. 59
6.3 Other Impacts of Aerosolp. 61
7 Modelling Urban Atmospheric Chemistryp. 61
8 Conclusionsp. 62
Referencesp. 62
Air Pollution in Underground Railway Systemsp. 65
1 Introductionp. 65
2 Physical and Chemical Propertiesp. 67
2.1 Particle Mass and Number Concentrationsp. 67
2.2 Time Variationp. 69
2.3 Chemical Compositionp. 71
2.4 Size Distributionsp. 75
2.5 Morphology and Speciationp. 76
3 Emission Sourcesp. 78
4 Consequences for Human Healthp. 80
5 Conclusionsp. 82
Acknowledgementsp. 83
Referencesp. 83
Human Exposure: Indoor and Outdoorp. 85
1 Introductionp. 86
2 Characteristics of Outdoor and Indoor Exposurep. 87
2.1 Outdoor Exposurep. 87
2.2 Indoor Exposurep. 88
2.3 Time-Activity Patternsp. 89
2.4 Indoor-Outdoor Relationshipsp. 89
3 Exposure Assessmentp. 90
3.1 Exposure Monitoringp. 90
3.1.1 Monitoring Networksp. 90
3.1.2 Personal Monitoringp. 92
3.1.3 Biomonitoringp. 93
3.2 Exposure Modellingp. 94
3.2.1 Proximity and Buffer Zone Modelsp. 95
3.2.2 Dispersion and Photochemical Air Quality Modelsp. 96
3.2.3 Geostatistical Interpolation and Land-Use Regression Modelsp. 98
3.2.4 Receptor-Oriented Modelsp. 99
3.2.5 Time-Activity (or Micro-Environmental) Modellingp. 99
3.3 Modelling Uncertaintyp. 100
4 Evidence from Personal Exposure Surveys in Urban Areasp. 101
4.1 North American Studiesp. 101
4.2 European Studiesp. 102
5 Role of Exposure Assessment in Regulatory Control of Air Pollutionp. 103
6 Conclusionsp. 104
Referencesp. 104
Health Effects of Urban Pollutionp. 108
1 Introductionp. 109
2 Exposure to Air Pollutantsp. 109
3 Epidemiological Approachesp. 110
3.1 Time-Series Studiesp. 110
3.2 Intervention Studiesp. 113
3.3 Cohort Studiesp. 113
4 Particulate Matterp. 114
5 Nitrogen Dioxidep. 116
6 Sulfur Dioxidep. 118
7 Ozonep. 120
8 Carbon Monoxidep. 122
9 Carcinogenic Air Pollutants found in Urban Areasp. 123
Referencesp. 124
The Policy Response to Improving Urban Air Qualityp. 129
1 Introductionp. 130
2 Policy and the Evidence Base after the Smog Episodes of 1952 and 1962p. 130
3 The Development of Strategies in the UK and Europep. 134
4 Policy Instruments which Reduce Emissionsp. 137
5 Future Developments in Air Quality Management Policiesp. 139
5.1 Exposure Reductionp. 139
5.2 Links and Co-benefits with Climate Change Policiesp. 142
Disclaimerp. 145
Referencesp. 145
Subject Indexp. 146
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