Cover image for Energy materials
Title:
Energy materials
Series:
Inorganic materials series ; 4
Publication Information:
Hoboken, NJ : Wiley, 2011
Physical Description:
viii, 291 p. : ill. ; 24 cm.
ISBN:
9780470997529
Abstract:
"Following the success of Inorganic Materials, the concept of the original book will be updated and extended to reflect the recent expansion of research and applications in inorganic material chemistry, and its interfaces with physics, biology and materials science. Inorganic materials will be separated into five areas based on their physical properties: porous, functional oxides, molecular, low-dimensional and electronic materials. Each area will be presented in one volume and each chapter will cover recent research areas within the contributors' field of knowledge, providing a clear and useable introduction to that field. The chapters of the book will be self-contained and relate to a different area of the volume's general subject matter. This volume looks at inorganic materials with special electronic properties and is proposed as follows: polymer electrolytes, photonic crystals, low molar mass OLEDs, and polymer LEDs"-- Provided by publisher.

"This volume looks at inorganic materials with special electronic properties and is proposed as follows: polymer electrolytes, photonic crystals, low molar mass OLEDs, and polymer LEDs"-- Provided by publisher.

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30000010237048 TK2896 E524 2011 Open Access Book Book
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Summary

Summary

In an age of global industrialisation and population growth, the area of energy is one that is very much in the public consciousness. Fundamental scientific research is recognised as being crucial to delivering solutions to these issues, particularly to yield novel means of providing efficient, ideally recyclable, ways of converting, transporting and delivering energy.

This volume considers a selection of the state-of-the-art materials that are being designed to meet some of the energy challenges we face today. Topics are carefully chosen that show how the skill of the synthetic chemist can be applied to allow the targeted preparation of inorganic materials with properties optimised for a specific application.

Four chapters explore the key areas of:

Polymer Electrolytes Advanced Inorganic Materials for Solid Oxide Fuel Cells Solar Energy Materials Hydrogen Adsorption on Metal Organic Framework Materials for Storage Applications

Energy Materials provides both a summary of the current status of research, and an eye to how future research may develop materials properties further.

Additional volumes in the Inorganic Materials Series :
Molecular Materials
Functional Oxides
Porous Materials
Low-Dimensional Solids


Author Notes

Professor Duncan Bruce graduated from the University of Liverpool (UK), where he also gained his PhD. In 1984, he took up a Temporary Lectureship in Inorganic Chemistry at the University of Sheffield and was awarded a Royal Society Warren Research Fellowship. He was then appointed Lecturer in Chemistry and was promoted Senior Lecturer in 1994, in which year he became co-director of the Sheffield Centre for Molecular Materials. In 1995, he was appointed Professor of Inorganic Chemistry at the University of Exeter. Following the closure of Exeter's chemistry department in 2005, Professor Bruce took up his present position as Professor of Materials Chemistry in York. He is currently Chair of the Royal Society of Chemistry Materials Chemistry Forum. His current research interests include liquid crystals and nanoparticle-doped, nanostructured, mesoporous silicates. His work has been recognized by various awards including the British Liquid Crystal Society's first Young Scientist prize and the RSC's Sir Edward Frankland Fellowship and Corday-Morgan Medal and Prize. He has held visiting positions in Australia, France, Japan and Italy.

Dr. Richard Walton , who was also formerly based in the Department of Chemistry at the University of Exeter, now works in the Department of Chemistry at the University of Warwick. His research group works in the area of solid-state materials chemistry and has a number of projects focusing upon the synthesis, structural characterization and properties of inorganic materials.

Dermot O'Hare is Professor in the Chemistry Research Laboratory at the University of Oxford. His research group has a wide range of research interests. They all involve synthetic chemistry ranging from organometallic chemistry to the synthesis of new microporous solids.
Duncan Bruce and Dermot O'Hare have edited several editions of "Inorganic Materials" published by John Wiley & Sons Ltd.


Table of Contents

Michel B. Armand and Peter G. Bruce and Maria Forsyth and Bruno Scrosati and Wladyslaw WieczorekStephen J. Skinner and Miguel A. Laguna-BerceroElizabeth A. Gibson and Anders HagfeldtK. Mark Thomas
Inorganic Materials Series Prefacep. vii
Prefacep. ix
List of Contributorsp. xi
1 Polymer Electrolytesp. 1
1.1 Introductionp. 1
1.1.1 Contextp. 1
1.1.2 Polymer Electrolytes - The Early Yearsp. 2
1.2 Nanocomposite Polymer Electrolytesp. 8
1.3 Ionic Liquid Based Polymer Electrolytesp. 13
1.3.1 Ionic Liquid Propertiesp. 13
1.3.2 Ion Gelsp. 16
1.3.3 Polymer Electrolytes Based on Polymerisable Ionic Liquidsp. 18
1.4 Crystalline Polymer Electrolytesp. 21
1.4.1 Crystalline Polymer: Salt Complexesp. 22
Referencesp. 27
2 Advanced Inorganic Materials for Solid Oxide Fuel Cellsp. 33
2.1 Introductionp. 33
2.1.1 Conventional SOFC Electrolytesp. 35
2.1.2 Conventional Anodesp. 39
2.1.3 Conventional Cathodesp. 40
2.1.4 Summaryp. 41
2.2 Next Generation SOFC Materialsp. 42
2.2.1 Novel Electrolyte Materialsp. 42
2.2.2 Novel Cathodesp. 58
2.2.3 Ceramic and Sulfur Tolerant Anodesp. 71
2.3 Materials Developments through Processingp. 79
2.4 Proton Conducting Ceramic Fuel Cellsp. 81
2.4.1 Materials for Proton Conducting Solid Oxide Fuel Cells (PC-SOFCs)p. 81
2.5 Summaryp. 83
Referencesp. 83
3 Solar Energy Materialsp. 95
3.1 Introductionp. 95
3.1.1 The Solar Spectrump. 95
3.1.2 The Photovoltaics Industryp. 98
3.1.3 Terminologyp. 99
3.2 Development of PV Technologyp. 103
3.2.1 First Generation: Crystalline Silicon (c-Si)p. 103
3.2.2 Second Generation: Thin-Film Technologiesp. 106
3.2.3 Third Generation: Nanotechnology/Electrochemical PVsp. 118
3.3 Summaryp. 228
Acknowledgementsp. 230
Referencesp. 230
4 Hydrogen Adsorption on Metal Organic Framework Materials for Storage Applicationsp. 245
4.1 Introductionp. 245
4.2 Hydrogen Adsorption Experimental Methodsp. 248
4.3 Activation of MOFsp. 249
4.4 Hydrogen Adsorption on MOFsp. 251
4.4.1 Hydrogen Adsorption Capacity Studiesp. 257
4.4.2 Temperature Dependence of Hydrogen Physisorptionp. 260
4.4.3 Hydrogen Surface Interactions in Poresp. 261
4.4.4 Framework Flexibility and Hysteretic Adsorptionp. 267
4.4.5 Comparison of Hydrogen and Deuterium Adsorptionp. 269
4.5 Conclusionsp. 271
Acknowledgementsp. 272
Referencesp. 272
Indexp. 283