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Summary
Summary
Most modern surfactants are readily biodegradable and exhibit low toxicity in the aquatic environment, the two criteria for green surfactants. However the majority are synthesised from petroleum, so over the past decade the detergent industry has turned its attention to developing greener routes to create these surfactants via renewable building blocks.
Surfactants from Renewable Resources presents the latest research and commercial applications in the emerging field of sustainable surfactant chemistry, with emphasis on production technology, surface chemical properties, biodegradability, ecotoxicity, market trends, economic viability and life-cycle analysis.
Reviewing traditional sources for renewable surfactants as well as recent advances, this text focuses on techniques with potential for large scale application.
Topics covered include:
Renewable hydrophobes from natural fatty acids and forest industry by-products Renewable hydrophiles from carbohydrates, amino acids and lactic acid New ways of making renewable building blocks; ethylene from renewable resources and complex mixtures from waste biomass Biosurfactants Surface active polymers This book is a valuable resource for industrial researchers in companies that produce and use surfactants, as well as academic researchers in surface and polymer chemistry, sustainable chemistry and chemical engineering.Author Notes
Dr Mikael Kjellin is based at the Institute for Surface Chemistry, Stockholm, Sweden, which works with many industrial branches including pharmaceuticals, personal care products, biotech, food, industrial chemicals, household products, engineering and materials industries, pulp and paper, coatings, adhesives, paints, and printing.
In addition, Dr Kjellin is the coordinator of the research centre SNAP, which aims to build from an industrial need, long-term knowledge and experience relating to new environmentally safe surfactants derived entirely or partly from natural products.
Ingegard.Johansson is a research scientists based at Akzo Nobel Surfactants Europe in Sweden.
Table of Contents
Series Preface |
Preface |
Acknowledgements |
List of Contributors |
Part 1 Renewable Hydrophobes |
1 Surfactants based on natural fatty acids, Martin Svensson |
1.1 Introduction and History |
1.2 Fats and Oils as Raw Materials |
1.3 Fatty Acid Soaps |
1.4 Polyethyleneglycol Fatty Acid Esters |
1.5 Polyglycerol fatty acid esters |
1.6 Conclusions |
References |
2 Nitrogen Derivatives of Natural Fats and Oils Ralph Franklin |
2.1 Introduction |
2.2 Manufacture of Fatty Nitrogen Derivatives |
2.3 Production Data |
2.4 Ecological Aspects |
2.5 Biodegradation |
2.6 Properties of Nitrogen-based Surfactants |
2.7 Applications |
2.8 Conclusions |
References |
3 Surface-Active Compounds as Forest-Industry By-Products Bjarne Holmbom, Anna Sundberg and Anders Strand |
3.1 Introduction |
3.2 Resin and Fatty Acids |
3.3 Sterols and Sterol Ethoxylates |
3.4 Hemicelluloses |
Acknowledgement |
References |
Part 2 Renewable Hydrophiles |
4 Surfactants based on Carbohydrates and Proteins for Consumer Products and Technical Applications Karlheinz Hill |
4.1 Introduction |
4.2 Raw materials |
4.3 Products and Applications |
4.4 Conclusion |
5 Amino acids, lactic acid and ascorbic acid as raw materials for biocompatible surfactants |
Carmen Moran, Lourdes Perez, Ramon Pons, Aurora Pinazo and Mª Rosa Infante |
5.1 Introduction |
5.2 Production of raw materials |
5.3 Lysine based surfactants |
5.4 Lactic acid based surfactants |
5.5 Ascorbic acid based surfactants |
References |
Part 3 New ways of making renewable building blocks |
6 Synthesis of ethylene, propylene from ethanol or methanol |
Anna Lundgren and Thomas Hjertberg |
6.1 Introduction |
6.2 Why Produce Ethylene from Renewable Resources? |
6.3 Production of Ethylene from Renewable Feed Stock |
6.4 Commercialization of Bioethylene |
6.5 Environmental Impact of Bioethylene |
6.6 Certificate of Green Carbon Content |
6.7 Concluding Remarks |
References 7. Fermentation based building blocks for renewable resource based surfactants KrisArvid Berglund, Ulrika Rova, David B. Hodge |
7.1 Introduction |
7.2 Existing and Potential Classes of Surfactants from Biologically-Derived Metabolites |
7.3 Fermentation-Based Building Blocks with Large Existing Markets |
7.4 New Fermentation-Based Building Blocks |
Conclusion |
References |
Part 4 Biosurfactants |
8 Enzymatic synthesis of biosurfactants, Patrick Adlercreutzand Rajni Hatti-Kaul |
8.1 Introduction |
8.2 Enzymes as catalysts for synthesis of surfactants |
8.3 Enzymatic synthesis of polar lipids useful as surfactants |
8.4 Carbohydrate esters |
8.5 Fatty amide surfactants |
8.6 Amino acid-based surfactants |
8.7 Alkyl glycosides |
8.8 Future prospects |
Acknowledgement |
References |
9 Surfactants from waste biomass Flor Yunuen Garcia-Becerra, David Grant Allen, and Edgar Joel Acosta |
9.1 Introduction |
9.2 Surfactants obtained from biological transformation of waste biomass |
9.3 Surfactants obtained from chemical transformation of waste biomass |
9.4 Summary and outlook |
9.5 References |
10 Lecithin and Phospholipids Willem van Nieuwenhuyzen |
10.1 Introduction |
10.2 Sources and production |
10.3 Composition |
10.4 Quality and analysis of lecithins |
10.5 Modification |
10.6 Emulsifying properties |
10.7 Applications |
10.8 Legislation and reach |
10.9 Conclusion |
References 11. Sophorolipid and rhamnolipid synthesis and their application in cleaning products Dirk Develter and Steve Fleurackers |
11.1 Sophorolipids |
11.2 Derivatives of native sophorolipids |
11.3 Biosynthesis of novel sophorolipids |
11.4 Rhamnolipids |
11.5 Cleaning applications using sophorolipids and rhamnolipids |
References |
12 Saponin based surfactants Wieslaw Oleszek and Arafa Hamed |
12.1 Introduction |
12.2 Molecular properties |
12.3 Sources of saponins |
12.4 Saponins as emulsifiers and surfactants |
12.5 Application of saponins as surfactants and emulsifiers |
References |
Part 5 Polymeric surfactants/Surface active polymers |
13 Surface active polymers from cellulose Leif Karlson |
13.1 Introduction |
13.2 Structure and synthesis of cellulose ether |
13.3 Cellulose ethers in aqueous solution |
13.4 Interaction with surfactants |
13.5 Clouding |
References |
14 New developments in the commercial utilisation of lignosulfonates Rolf Andreas Lauten, Bernt O. Myrvold and Stig Are Gundersen |
14.1 Introduction |
14.2 Lignosulfonates |
14.3 Lignosulfonate production |
14.4 Environmental issues |
14.5 Lignosulfonates as stabilisers for emulsions and suspoemulsions |
14.6 Superplasticizers for concrete |
14.7 Summary |
Acknowledgements |
References |
15 Dispersion stabilizers based on inulin Tharwat F. Tadrosand Bart Levecke |
15.1 Introduction |
15.2 Solution Properties of long-chain inulin and hydrophobically modified inulin (HMI) |
15.3 Interfacial Aspects of HMI at Various Interfaces |
15.4 Emulsions Stabilized Using HMI |
15.5 Emulsion Polymerization Using Hydrophobically Modified Inulin (HMI) |
15.6 Use of HMI for Preparation and Stabilisation of Nano-Emulsions |
References |