Cover image for The kinetics of environmental aquatic photochemistry : theory and practice
Title:
The kinetics of environmental aquatic photochemistry : theory and practice
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Publication Information:
Washington, DC : American Chemical Society, 1988
ISBN:
9780841214644

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30000000550446 TD193.L44 1988 Open Access Book Book
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Summary

Summary

Now in one source---the theory and practice for determining environmentally relevant rates of photoreaction in aquatic media. Works out all mathematic derivations, step by step. Shows how to select experimental procedures for measuring rates of aqueous photoreaction. Details how to measure rates at very low concentrations. Also describes theory and practice of chemical actinometry. Shows how to measure rates of direct and indirect aqueous photoreaction by outdoor experiments in sunlight and laboratory experiments using monochromatic light. Describes detailed experimental procedures for obtaining requisite kinetic data. Gives comprehensive tables of solar irradiance as a function of latitude and season of the year in the northern hemisphere. Illustrates how to use data from kinetic experiments to estimate rates of direct and indirect photoreaction in aquatic media in the environment.


Table of Contents

Some Fundamental Principles of Photochemistry
Absorption and Transmission of Solar Radiation in the Atmosphere
Absorption and Transmission of Solar Radiation in a Natural Water Body
Direct Photoreaction Rates and Half-Lives in Natural Water Bodies in the
Environment
Theory of the Kinetics of Photochemical Reactions in Aquatic Media in the
Environment
Theory and Development of the Screening Test Methods
Experimental Procedures
Illustrative Examples
Theory and Development of the Tests
Experimental Procedures
Illustrative Example: Determination of the Reaction Quantum Yield by the
Low-Optical-Density Test Chemical and Actinometer Method and Sunlight
Photoreaction Rates
A Review of the Published Literature
Theory and Development of the Screening Test Method
Experimental Procedures
Illustrative Examples